Viscosity effect in Landau's hydrodynamical model

The Bose-Einstein distribution is used to investigate Landau's hydrohynamical model with viscosity. In case the viscosity dependence on the temperature isT ³, the correction to the multiplicity behaves like 1/E and is found to be negligible for thepp data. A discussion is presented on a possibility of reconcilingE ^1/2 and logE dependence of the multiplicity law.     

58Co核拉长态性质的实验研究

利用△E-E望远镜及北京Q3D磁谱仪系统.在HI-13串列加速器提供的35MeVα离子轰击下,测量了⁵⁶Fe(аd)⁵⁸Co核反应的精细能谱和微分截面角分布.借助全微观DEBA理论分析,相应于核反应俘获的p-n核子对具有(lg_9/2)²组态,观测到迄今所能看到的最高拉长态(lg_9/2,lg_9/2)_9.还对6.4 MeV高激发能级核反应截面的反常增强,而p-n核子对耦合成最小角动量的实验证据进行了讨论,并且确认了6.4MeV能级为非自然宇称态,自旋字称值J^л=1⁺.     

温度对应变式位移传感系统灵敏系数的影响

应变式位移传感系统的工作原理是基于电阻应变效应,该系统具有精度高﹑稳定性好等优点,但温度尤其是极端低温环境将影响该系统的灵敏系数,进而影响其测量精度.本文介绍了一种可用于低温环境的应变式位移传感系统,理论分析和实验研究了温度对该系统灵敏系数的影响,研究结果为其在低温环境中的应用提供了一定基础。     

相干平行板电容器对外场的动态响应

基于介观体系动态响应的自洽理论,讨论了介观相干平行板电容器的电容.结果表明相干电容器的电容对外场频率有很强的依赖关系,并且是随频率变化的复变函数.该电容随频率的变化关系呈现出一个非常有意义的特性,即电容虚部曲线有一个较尖锐的峰,它正好与电容实部的极小位置相对应,而进一步研究发现它们与该电容体系中的类等离子体激发相联系.另外,也讨论了介观电容的尺寸效应,发现当极板间距很大时,电容值和宏观的几何电容结果趋于一致.     

Theoretical Studies of O(1D)+HD (v=0, j=0, 1, 2, 3)→OD(H)+H(D) Reaction

利用准经典轨线计算方法在DK势能面上对O+HD进行了计算,获得了产物的反应截面和分支比OD/OH. 计算结果表明,当碰撞能由4.6 kJ/mol增加到46.0 kJ/mol时,产物的反应截面随着碰撞能的增加明显减小;产物的平均分支比随着转动量子数的增加逐渐减小.     

A new effect of ultrasonication on the formation of BaTiO3 nanoparticles

A new effect of ultrasonic irradiation on the formation of BaTiO₃ particles was identified. Ultrasonication caused the aggregation of the original 5–10 nm BaTiO₃ particles in the same crystal axis and accelerated the formation of BaTiO₃ particles significantly. Furthermore, narrow size distribution was obtained for the aggregated particles under ultrasonic irradiation.     

Stoichiometry of BaTiO3 nanoparticles

Barium titanate nanoparticles with various nominal Ba/Ti ratios were prepared through direct synthesis from solution (DSS) and further annealed at different temperatures. Their deviation from stoichiometry was studied through XRD analysis, and a large deviation from stoichiometry has been observed. The grain size we studied ranges from 50 nm to 1 μm. For the as-prepared particles, the grain size is about 50 nm, and the maximum excess of Ti is over 15%. For the samples annealed at 800 °C, the grain size is increased to 100 nm, and the maximum excesses of Ba and Ti are 8 and 9%, respectively. The defects formed during synthesis and surface effect of nanoparticles are both estimated for their contributions to the deviation from stoichiometry, and the defects have been found to be mainly responsible for the large deviation observed.     

Unsymmetrically N,N'-substituted saturated carbenes: synthesis, reactivity and preparation of a rhodium(I) carbene complex

A versatile synthesis of unsymmetrically N,N'-substituted saturated carbenes is described. The novel racemic imidazolidin-2-ylidenes rac-5 have been synthesized by reductive desulfurization of the corresponding imidazolidin-2-thiones rac-4. The thiones were prepared in two reaction steps from aldimines and secondary amines. Three different substituents at N1, N3 and C4 of the five-membered N-heterocyclic ring can be introduced by choice of suitable aldimines and secondary amines. The dimerization behaviour (diaminocarbene/enetetramine equilibrium) for the unsymmetrically N,N'-substituted imidazolidin-2-ylidenes has been investigated by NMR spectroscopy. Unsymmetrically N-iPr and N-iBu substituted N-heterocyclic carbenes undergo a slow dimerization, whereas N-tBu substituted derivatives are stable as monomeric carbenes indefinitely. The carbene ligand rac-5d has been coordinated to rhodium(I) to give the square-planar rhodium carbene complex [Cl(cod)Rh(rac-5d)]rac-6d which has been characterized by an X-ray diffraction analysis.     

Solution structures by NMR of a novel antifungal drug: Petriellin A

Petriellin A is a novel cyclic depsipeptide antifungal compound consisting of nine l-configured residues, one d-phenyllactic acid (PhLac) and three unknown chiral centres: two N-methyl-threonines (MeThr1 & MeThr2) and one N-methyl-isoleucine (MeIle). NMR experiments including 2D ROESY, NOESY along with structural and energy calculations predicted that the unknown chiral centres were all l-configured, which was later verified chemically. Simulated annealing, dynamics calculations and minimisation processes showed Petriellin A to have a folded "C-shaped" structure.