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111.
We analyze the Mercury perihelion precession, the bending of starlight, and the radar echo delay in the Schwarzschild field modified by the presence of a solid angle deficit. By using the experimental data we obtain that the parameter characterizing the solid angle deficit is less than 10–9, 10–8 and 10–9, respectively, on the length scales associated with such phenomena. In particular, if the solid angle deficit is generated by a global monopole, it is shown that within the length scales associated with such phenomena, the observational data available constrain the monopole energy scale to lower bounds which are in considerable agreement with the limits derived from grand unified theory and cosmology. 相似文献
112.
113.
The electrochemical reduction of the antidepressant drug fluoxetine was investigated by cyclic, linear sweep, differential pulse and square wave voltammetry using a hanging mercury drop electrode in alkaline buffer solution in water and in a water/acetonitrile mixed solvent. Cyclic voltammograms in aqueous solution showed very strong adsorption of fluoxetine on the electrode with formation of a compact film. The effect of addition of different percentages of acetonitrile on the voltammetric response was evaluated. It is shown that acetonitrile protects the electrode surface, thus preventing the adsorption of fluoxetine as a compact film, although reduction occurs at more negative potentials. Adsorption was used to accumulate the drug onto the electrode surface. The adsorbed species were measured voltammetrically by reduction at -1.3 V in an aqueous 0.05 M Ringer buffer, pH 12, 20% acetonitrile v/v. Linear calibration graphs were obtained in the range 0.52-5.2 M. The quantification of fluoxetine in pharmacological formulations existing in the market was performed using adsorptive square wave cathodic stripping voltammetry. and compared with data from UV spectrophotometry. The method is simple and not time-consuming. A comparative high performance liquid chromatography assay with UV detection was performed. Recovery data for both methods are reported. 相似文献
114.
A. L. F. Porto G. M. Campos-Takaki J. L. Lima Filho 《Applied biochemistry and biotechnology》1996,60(2):115-122
The influence of nitrogen and phosphate sources on the production of extracellular protease activity byStreptomyces clavuligerus has been investigated. The experiments were carried out in batch fermentation using soy-bean flour as nitrogen source and
potassium phosphate dibasic as phosphate source. High protease yield was obtained after 24 h of fermentation with an initial
pH of 7.0. The maximal protease activity (112.68 and 88.72 U/mg) was obtained the phosphate concentration of the 21 and 29
mM for strains 3585 and 644, respectively. With regard to the nitrogen concentration in both strains, the maximal protease
activity was achieved with 0.5% (154.89 U/mg and 228.36 U/mg for 3585 and 644 strains, respectively). Enzyme production appeared
to be modulated by an inducer system where ammonia, complex nitrogen, and phosphate sources might have been involved. 相似文献
115.
The synthesis of samples by the sol-gel method with aluminum tri-sec-butoxide as cation precursor, 2-propanol as solvent, and sulfuric acid as hydrolysis catalyst gave rise to nanocapsules with an average diameter of 20 nm and a shell thickness of 3.5 nm. The analysis of the X-ray diffraction patterns and the 27Al MAS NMR spectra showed that the shell of the nanocapsules was made up of Al13 tridecamers ordered in a noncrystalline symmetry. The interaction between the capsule's shells opened the capsule structure, producing curved fibers, but maintaining the atomic local order. This opening of the capsules favored the reordering of the atomic local order of Al13 tridecamers into the one of crystalline boehmite, when the sample was aged at room temperature for several days; it also increased the pore volume and the specific surface area of the sample. The crystallization transformed the curved fibers into rods made of small crystalline boehmite bars. The capsule morphology was preserved after calcining the nonaged sample at 700 degrees C, indicating that the transformation of the phase made up of ordered Al13 tridecamers into a noncrystalline alumina was pseudomorphic. We describe and partially explain one of the possible atomic ordering evolutions from the one of an isolated Al13 tridecamer, to the phase forming the nanocapsules shell, until eventually coming to the ordering corresponding to boehmite crystalline rods. 相似文献
116.
Vegard Lima 《Journal of Functional Analysis》2004,210(1):148-170
We prove that a Banach space X has the metric approximation property if and only if , the space of all finite rank operators, is an ideal in , the space of all bounded operators, for every Banach space Y. Moreover, X has the shrinking metric approximation property if and only if is an ideal in for every Banach space Y.Similar results are obtained for u-ideals and the corresponding unconditional metric approximation properties. 相似文献
117.
R. S. Castro S. Prasad R. M. Gomes I. C. E. S. G Lima A. G. Souza T. A. A Melo S. J. G. Lima 《Journal of Thermal Analysis and Calorimetry》2004,75(2):649-654
Co80Nb14B6, Co80Nb12B8 and Co80Nb10B10 amorphous alloys were obtained through the melt-spinning process. The ribbons structure was investigated by X-ray diffractometry
and the crystallization process and the thermal stability were studied by means of differential thermal analysis and thermomechanical
technique. It was observed that the crystallization temperature depends on the alloy composition and occurs in a temperature
range between 420 and 730°C. The coercive field of all alloys was determined by magnetic susceptibility measurements, the
values of which range from 2.78 to 5.95 A m-1.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
118.
Pacheco Santos V Del Colle V Batista de Lima R Tremiliosi-Filho G 《Langmuir : the ACS journal of surfaces and colloids》2004,20(25):11064-11072
In the present work, ethanol electrooxidation on a Pt(100) electrode modified by different coverage degrees of osmium nanoislands obtained by spontaneous depositions, was extensively studied employing in situ FTIR spectroscopy. A collection of spectra of the ethanol adsorption and oxidation processes was acquired during the first series of a positive potential step, to determine the intermediate species, as well as the main products formed. The spectroscopic results obtained were correlated with conventional electrochemical results obtained by cyclic voltammetry. It was shown that the catalytic activity of Pt(100) for ethanol oxidation increases significantly after osmium deposition and that the mechanistic pathway for this reaction depends directly on the osmium coverage degree. Thus, for low osmium coverage (theta;( Os) up to 0.15) the formation of CO as an intermediate was favored and hence the full oxidation of adsorbed ethanol to CO(2) was increased. For higher osmium coverages (theta;(Os) up to 0.33), the higher the coverage is, the more the direct ethanol oxidation to acetaldehyde and acetic acid is favored. For osmium coverage degree of 0.40, the catalytic activity of the electrode for ethanol oxidation decreased. On an almost complete osmium layer (theta;(Os) = 0.92) obtained by electrodeposition at 50 mV vs reversible hydrogen electrode, the catalytic activity for ethanol oxidation shows a much lower value. 相似文献
119.
We establish monotonicity inequalities for the r-area of a complete oriented properly immersed r-minimal hypersurface in Euclidean
space under appropriate quasi-positivity assumptions on certain invariants of the immersion. The proofs are based on the corresponding
first variational formula. As an application, we derive a degeneracy theorem for an entire r-minimal graph whose defining
function ƒ has first and second derivatives decaying fast enough at infinity: Its Hessian operator D2 ƒ has at least n − r null eigenvalues everywhere. 相似文献
120.
Sauaia MG de Lima RG Tedesco AC da Silva RS 《Journal of the American Chemical Society》2003,125(48):14718-14719
The binuclear complex [RuII(NH3)5(pz)RuII(bpy)2(NO)](PF6)5 was prepared and characterized by elemental analysis, UV-vis, and IR spectroscopy. The complex UV-vis spectrum has presented bands at 242, 286, and 530 nm in acetate buffer solution at pH 4.5. The photochemical study by laser flash-photolysis at 532 nm showed the NO release account from the NO measured by a NO sensor. The quantum yield for NO release (0.025 +/- 0.004 mol einsten-1) was determined with a laser flash-photolysis apparatus (Continuum Q-switched Nd:YAG laser). The major irradiation product of the [RuII(NH3)5(pz)RuII(bpy)2(NO)]5+ complex besides nitric oxide is [RuIII(NH3)5(pz)RuII(bpy)2(H2O)]5+. 相似文献