Synthesis of (+)-polyoxamic acid and D-sorbitol from simple achiral allylic halides employing (S,S)-hydrobenzoin as a chiral source

Coupling of cis-1-bromo-2-pentene and (S,S)-hydrobenzoin stannylene acetal followed by regio- and stereoselective transformations of the resulting allylic ether gave (+)-polyoxamic acid and a similar procedure was applied to the synthesis of D-sorbitol from trans-1-iodo-2-hexene.     

The role of hydrogenases in the anaerobic microbiologically influenced corrosion of steels

The direct electron transfer between 316 L stainless steel and the NAD-dependent hydrogenase from Ralstonia eutropha was studied by spectroelectrochemistry. The presence of hydrogenase and NAD+ clearly increased the quantity of electricity, which was consumed during the electrolysis performed at potential lower than -0.70 V/SCE. The involvement of hydrogenase in the cathodic depolarisation theory was discussed in the light of these results.     

LD泵浦Nd:YAG 946 nm/1 064 nm双波长运转及腔内和频

用国产半导体激光二极管(LD)端面泵浦NdYAG晶体, 通过优化激光谐振腔反射膜系,调节1 064 nm谱线的线性损耗以达到与弱谱线946 nm的增益匹配,在室温下实现1 064 nm和946 nm双波长连续运转,并通过I类临界相位匹配LBO晶体腔内和频在国内首次实现500.8 nm青色激光连续输出.当泵浦注入功率为1.4W时和频青色激光最大输出达20 mW,光-光转换效率为1.4%,功率稳定性24 h内优于±3%.     

Design and synthesis of novel [60]fullerene derivatives as potential HIV aspartic protease inhibitors

[structure] Two water-soluble fullerene derivatives have been computer-designed and synthesized. They may exhibit interesting anti-HIV activity owing to the presence of two ammonium groups strategically located on the spheroid surface.     

Recent advances on thermoelectric materials

By converting waste heat into electricity through the thermoelectric power of solids without producing greenhouse gas emissions, thermoelectric generators could be an important part of the solution to today’s energy challenge. There has been a resurgence in the search for new materials for advanced thermoelectric energy conversion applications. In this paper, we will review recent efforts on improving thermoelectric efficiency. Particularly, several novel proof-of-principle approaches such as phonon disorder in phonon-glass-electron crystals, low dimensionality in nanostructured materials and charge-spin-orbital degeneracy in strongly correlated systems on thermoelectric performance will be discussed.      

Inclusion of Enantiomeric Carvones in β-Cyclodextrin: a Variable Temperature 1H NMR Study in Aqueous Solution

In aqueous solution, the apparent association constant at room temperature for the 1 : 1 inclusion of S-(+)-carvone in - cyclodextrin is double of that for R-(-)-carvone, whereas, at 45 °C, both enantiomers have association constants two orders of magnitude smaller, with the S-(+) inclusion being then slightly weaker than the R-(-) encapsulation. Calculations carried out at the molecular mechanics, AM1 and STO-3G levels confirm the preferential inclusion of the S-enantiomer and provide important clues for understanding chiral discrimination by -cyclodextrin.     

广义对角占优阵的一个等价条件

给出了实方阵为广义对角占优阵的充要条件,同时给出了判断广义对角占优阵可靠,可行,较简单方法。     

电解沉积的分形维数与ZnSO_4溶液浓度的关系

用电沉积方法得到了不同浓度硫酸锌电解液的分形凝聚图像;进行图像处理,得到了其分形维数与浓度的关系曲线;用粒子扩散限制凝聚模型解释了此关系     

赋值格为非线性序的Kleene-Dienes四值逻辑系统K24

研究赋值格为非线性序,非运算不同于Ｂｏｏｌｅ的补运算,而蕴含算子→取Ｋｌｅｅｎｅ－Ｄｉｅｎｅｓ的ＲＫ的一种新的四值逻辑系统Ｋ＾２４,得到若干结果。特别是,Ｋ＾２４中没有重言式,其准重言式恰与Ｃ２中的重言式一致,即ＱＴ（Ｋ＾２４）＝Ｔ（Ｃ２）。     

离心式冷水空调机组中CFC11替代工质的研究

对几种 HFCs、HFEs 类新工质和混合工质M1、M2进行了以在离心式冷水空调机组中替代 CFC11为目标的理论循环性能分析。结果表明,M1具有作为 CFC11 灌注式替代物的潜力;HFC143 循环性能优良,更适合应用于新设计的系统中。