丁苯橡胶的阳离子环化

应用一氯二乙基铝和苄基氯催化剂体系进行了丁苯橡胶的阳离子环化反应。研究了反应温度、苄基氯／一氯二乙基铝比例、溶剂、原胶浓度对环化的影响。发现通过控制苄基氯／一氯二乙基铝比,可在高温（１２０℃）、高原胶浓度（２～４％ｗ／ｖ）下进行丁苯橡胶的环化,制得特性粘度较原胶有大幅度降低,可溶性无凝胶的环化丁苯胶。通过对红外光谱、＾１Ｈ－ＮＭＲ谱初步解析,证实了环化反应的发生。     

Studies on the Polarographic Catalytic Wave of Cinnamic Acid-Bu4NBr-H2O2 System

A new-type of polarographic catalytic wave of organic compound,the polarographic catalytic wave of cinnamic acid (CA) in the presence of tetra-butylammonium bromide (Bu₄NBr) and H₂O₂, is reported based on the combination of the reduction current of adsorbed CA induced by Bu₄NBr with the catalytic current of CA caused by H₂O₂. The dual enhancement of both Bu₄NBr and the oxidizing agent H₂O₂ on the polarographic current of CA produces excellent sensitivity.     

Study on the Determination of Vitamin K4 by Chemical Deoxygenation Micelle-Stabilized Room Temperature Phosphorimetry

Vitamin K₄(acetomenaphthone) is widely used as a haemoglutinin. Numerous studies focus on its determination, including UV, electrochemical and HPLC etc. HPLC has superseded other methods, but it requires lengthy and complex sample preparation.     

The Linear Optical Polarizability Spectra of Five C78 Isomers

Effects of anisotropy, symmetry, atom arrangement and Coulomb interaction on the linear optical polarizability spectra of five C₇₈ isomers are theoretically studied by using the extended Su-Schrieffer-Heeger model with and without Coulomb interaction. The main results are as follows. 1) The spectra become anisotropic with respect to the direction of the electric field of light. The property is common in the niorlel with and without Coulomb interaction. 2) The symmetry and atom arrangement have grcat effects on the peak positions, strengths, and number. 3) The Coulomb interaction tends to shift peaks to higher energies and enhances the oscillator strengths at higher energies.     

用CCD相机观测HL—1M弹丸消融过程

利用高速ＣＣＤ相机拍摄了ＨＬ－１Ｍ等离子体中注入氢弹丸时的Ｈａ辐射照片。得到的弹丸不同形状消融云照片表明：弹丸轨迹发生弯曲和出现条纹。通过对照片的处理获得了辐射光强的空间分布、弹丸的速度与轨迹,分析了弹丸与等离子体相互作用的物理机制,为进一步在弹丸注入条件下用ＣＣＤ测量等离子体局部磁场和电流分布打下了基础。     

化学修饰电极的研究——Ⅰ.等离子体聚合法制备聚乙烯二茂铁膜电极

化学修饰电极是当前电化学领域中十分活跃的崭新研究方向^[1~4].它的出现扩展了电化学的研究和应用范围,有广阔的发展前途,已在电子转移、光电转换、催化、立体选择性有机合成以及选择富集测定等方面显出其优越性.最近,在多种化学修饰电极类型中,令人特别感兴趣的是具有电活性的聚合物膜电极.制备聚合物膜电极的方法很多^[5~10],用等离子体聚合法可得高度交联的超薄膜,且化学和热稳定性均好^[10,11].     

单电子转移反应 I.单电子转移反应引发的碳一氟键异裂——顺-1,2二苯基六氟环丁烷的烷氧基化脱氟取代反应

A novel reaction involving electron transfer and the breakage of a C-F bond has been investigated. In this reactio, 1, 2-diphenylhexafluorocyclobutane(1)reacts with i-PrONa to yield a substitution product 9. The reaction has to be photostimulated, and O2 and p-dinitrobenzene inhibit the reaction. Interestingly and unexpectedly, other alkoxides, viz. MeO-, EtO-, n-PrO- and t-BuO-, do not react with 1. Thus the reaction does not look like a SRN 1. However, the most amazing fact is: only the cis isomer of 1 reacts, whereas the trans isomer does not. Possibly, simultaneous breakage of α-C-H bond (in the i-PrO-) and formation of a (temporary) H-F bond is involved in a very tight transition state of the (caged?) reaction between the radical anion of 1 and the i-PrO.     

THE MOMENTUM SELECTOR OF BIG CLOUD CHAMBER SET

Using a“preselection-register-operation for reselection”program,a selection systemof the Yunan big cloud chamber set used for cosmic ray reseach is projected andconstructed.A small on-line digital computation technigue is applied to the momentumselector of the system,and a special computation element is designed.According tothe deflection angle and momentum of a charged particle passing through the magniticfield,computation and logieal judgment can be done immediately for the track signal registered before.     

载有微量贵金属的n-TiO2电极的光电化学研究

利用在富氧和乏氧溶液中光照下与不光照下测得的极化曲线,研究了载有铂和银的TiO₂电极的光电化学行为及反应机理.在富氧溶液中,光照载有贵金属的TiO₂电极时,贵金属上发生氧的还原反应,其速度与光照与否无关;而在未被贵金属覆盖的电极表面上进行水或其它组份的光氧化;二者组成一对共轭反应,相当于短路的光电化学电池.共轭反应速度一般由氧的还原反应速度控制.增加贵金属的载量能使共轭反应速度增大,外电路中通过的电流等于这一对反应所引起的电流的代数和.根据对极化曲线的分析和界面阻抗的测量结果,可以确定载在TiO₂表面上的铂、银与基底之间的接触基本上是欧姆型的.光照下贵金属中的电子具有与半导体整体相同的费米能级.在含载有贵金属的TiO₂粉末的悬浮液中实现了CN^-和二乙胺的光氧化,其速度随贵金属载量变化的规律可用上述反应机理加以解释.     

COMPOSITE MODEL OF QUARKS AND LEPTONS WITH ELEMENTARY SCALARS

The model in Ref.[5] is modified to include three doublets of quarks and Leptons so as to recover quark-Lepton symmetry. The second model is constructed from two elementary scalars and a fermion and is therefore more economical.