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91.
Mechanical, thermal, and electrical properties of graphite/PMMA composites have been evaluated as functions of particle size and dispersion of the graphitic nanofiller components via the use of three different graphitic nanofillers: “as received graphite” (ARG), “expanded graphite,” (EG) and “graphite nanoplatelets” (GNPs) EG, a graphitic materials with much lower density than ARG, was prepared from ARG flakes via an acid intercalation and thermal expansion. Subsequent sonication of EG in a liquid yielded GNPs as thin stacks of graphitic platelets with thicknesses of ~10 nm. Solution‐based processing was used to prepare PMMA composites with these three fillers. Dynamic mechanical analysis, thermal analysis, and electrical impedance measurements were carried out on the resulting composites, demonstrating that reduced particle size, high surface area, and increased surface roughness can significantly alter the graphite/polymer interface and enhance the mechanical, thermal, and electrical properties of the polymer matrix. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2097–2112, 2007  相似文献   
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A palladium‐TPPTS catalyst heterogenized on KF/alumina has been shown to be effective and recyclable for the selective formation of monooctadienylxylopyranosides via the telomerization of butadiene with D ‐xylose. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
94.
Summary A non-destructive method is described for the determination of major and minor constituents in archeological specimens by energy-dispersive X-ray fluorescence. Homogeneity tests are made by measuring at various sites of the specimen. In the same way, mean values are obtained for inhomogeneous specimen without taking samples. For calibration, powder standards are used. In case of the determination of elements with numbers up to 14 (Si) a vacuum chamber is used and the dimensions of the specimens are limited by the dimensions of that vacuum chamber, whereas for the determination of elements from K up to U specimens of any size, form or weight are suitable.
Zerstörungsfreie Analyse von archäologischen Proben mit Hilfe der Energie-dispersiven Röntgenfluorescenzanalyse
Zusammenfassung Eine zerstörungsfreie Methode für die Bestimmung von Haupt- und Nebenbestandteilen in archäologischen Proben mit Hilfe der Energie-dispersiven Röntgenfluorescenzanalyse wird beschrieben. Für Homogenitätstests wird an mehreren Stellen der Probe gemessen. In der gleichen Weise werden für inhomogene Proben Mittelwerte erhalten ohne Probenahme. Für die Eichung werden Pulverstandards verwendet. Im Falle der Bestimmung von Elementen mit Ordnungszahlen bis 14 (Si) wird eine Vakuumkammer eingesetzt, und die Dimensionen der Proben sind durch die Dimensionen dieser Vakuumkammer begrenzt, während für die Bestimmung der Elemente K bis U Proben jeder Größe, jeder Form oder jeden Gewichts verwendbar sind.
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Ohne Zusammenfassung
Structural aspects for grain boundary segregation studies
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97.
Poly(γ-benzyl-L-glutamate) (PBLG), was utilized as a surface coating agent in order to obtain parallel molecular orientation in thin layers of PBLG liquid-crystalline solutions confined between coated surfaces. It was found that in a thickness range much larger than the cholesteric pitch value, the texture was predominantly planar cholesteric. At film thickness comparable or smaller than the pitch, isotropic spherulites developed from a homeotropic nematic phase. Because of the coupling between the solution concentration and nematic director, as well as large differences in the elastic moduli of PBLG liquid-crystalline solutions, the long-range intermolecular interaction was unfavorable. Competition between parallel orientation induced by the surface coating of PBLG and inherent perpendicular orientation induced by PBLG molecules in the bulk would favor a short-range helix-coil transition mechanism, which results into a reentrant isotropic phase.  相似文献   
98.
The effect of crack tip sharpness on crack propagation in vulcanized rubbers has been studied. For very sharp cracks, tearing is found to occur on a small scale at very low energies not far above the threshold required for the onset of mechanical crack growth. The “small-scale” tearing energies show relatively little variation for rubbers that differ widely in tear strength as normally measured. Thus the latter property appears to be strongly influenced by variations in the ability of rubbers to promote tip blunting. The small-scale tear behavior is of relevance to other fracture phenomena, including cutting by sharp objects and tensile failure. Natural variations in tip sharpness occur during cyclic or time-dependent mechanical crack growth and influence the form of the crack growth characteristics.  相似文献   
99.
The QQ mass spectrometer is shown to be applicable to ion structure determination via collision-induced dissociations of mass-selected ions. The instrument can be scanned so as to record the products of dissociation as well as those of ion—molecule association reactions. The dissociations correspond to those observed at high kinetic energy in mass-analyzed ion kinetic energy spectrometers and the association reactions show parallels with reactions seen in ion cyclotron resonance spectroscopy and in high-pressure mass spectrometry  相似文献   
100.
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