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991.
I. I. Murav'ev E. V. Chernikova A. D. Shatova A. M. Yancharina 《Russian Physics Journal》1992,35(11):1008-1011
An experimental study has been made of the characteristics of radiation from a dispersing helium plasma. From measurements of the space-time dependence of the line intensities of the helium 23P — n3D series we obtained the distribution of the populations of the n3D levels for n=3–10. The study has shown that over a wide range of conditions the high-lying levels (n=5–10) are in equilibrium with electrons while a substantial deviation from equilibrium is observed for levels n=3, 4. From the energy distribution of the populations of the upper levels we determined the space-time dependence of the electron temperature, which reflects the process of effective electron cooling during dispersal of the plasma. The gas temperature was estimated from the populations of helium singlet and triplet levels with n=5. The time distribution of the electron density in the plasma was found from the Stark broadening of the spectral lines.Deceased.V. D. Kuznetsov Siberian Physicotechnical Institute, Tomsk State University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 15–19, November, 1992. 相似文献
992.
In this article, the question is considered whether there exist finite translation planes with arbitrarily small kernels admitting nonsolvable collineation groups. For any integerN, it is shown that there exist translation planes of dimension >N and orderq
3 admittingGL(2,q) as a collineation group. 相似文献
993.
Translated from Matematicheskie Zametki, Vol. 49, No. 6, pp. 92–97, June, 1991. 相似文献
994.
P E S?rensen R A McClelland R D Gandour 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1991,45(6):558-566
The ring-chain tautomerism in aqueous solution of some aryl-substituted morpholinium salts (bromides), has been studied and equilibrium constants are reported. In the crystals the substrates exist entirely in their cyclic forms as hemiacetals, but in aqueous solution NMR measurements reveal that an equilibrium is established between the cyclic (hemiacetal) and the noncyclic (ketone) form, the degree of ring-opening being more pronounced with electron-donating aryl substituents at the carbonyl carbon. The kinetics of the ring-chain interconversion in water has been investigated spectrophotometrically by a 'pH jump' stopped-flow technique. General base catalysis is observed with a Br?nsted beta value apparently independent of substituent and equal to 0.60. The Hammett rho values for various base catalysts are close to those for very similar intermolecular reactions involving hemiacetal breakdown, leading to the suggestion of a 'normal' class n mechanism for base catalysis. For acid catalysis, however, a quite different situation is encountered, since no general acid but only (weak) catalysis by the hydronium ion can be detected. We believe this deviation from 'normal' general acid catalysis is caused by an electrostatic interaction, and we suggest that it might result from a change in the usual class e mechanism for general acid catalysis by a situation in which rate-limiting concerted proton transfer is replaced by rate-limiting preprotonation. This is supported by the observed drastic change in Hammett rho value for catalysis by the hydronium ion, compared with the 'normal' case. An interesting case is encountered for the 4-aminophenyl-substituted substrate, in which the amino group becomes protonated in acid solution, thus representing a new substituent. Despite this complication, the various equilibrium and rate constants may also be evaluated experimentally for this substrate. 相似文献
995.
996.
We report on the integration of the kinematic dynamo problem in a spherical domain forced by velocity fields that are convective
fluid flows resulting from a bifurcation analysis of the spherical Bénard problem. We derive a code based on generalized spherical
harmonics that ensures a divergence-free magnetic field. We determine the growth or decay of a magnetic field in the kinematic
dynamo equation for various physically relevant velocity fields which are stationary as well as time-periodic and chaotic.
Velocity signals that are produced by heteroclinic cycles are used as an input to an energy-saturated kinematic dynamo equation
that limits the growth of the linearly unstable modes. Preliminary calculations indicate the possibility of reversals of the
magnetic field for this case of forcing.
Received 8 October 1996 and accepted 28 April 1997 相似文献
997.
A new microscopic model of anomalous muonium for the elemental semiconductors is proposed. The relevant configuration consisting
of both a diamagrentic molecule Si−Mu and an unpaired orbital e− is contained into a semivacancy of the real lattice. By using the unrestricted Hartree-Fock computational method the principal
properties of the system are established. A dynamical version of the model together with a question on the formation of such
system are discussed. 相似文献
998.
An explicit expression is obtained for the Green's functions of a massive scalar field for nonnull temperatures and density in the form of a series in powers of m/T. The equivalence of the spectral-geometric approach and the temperature technique of Matsubara and Bernard is demonstrated. Corrections to the Stefan-Boltzmann law are obtained on the basis of the calculated Green's functions. The energy density is calculated in regions of high and low temperatures. The formulas obtained can prove to be useful in the discussion of the phase transition hadrons-quark-gluon plasma.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 32–40, July, 1991. 相似文献
999.
1000.
A random-medium model which is a correlated distribution of points (particles) randomly positioned in the 3-dimensional space
is considered. The construction of the medium starts from a noncorrelated (Poisson) distribution of parent particles, each
of them initiates a finite Markov chain of its descendants. The complete collection of correlation functions of all orders
within the scope of the model have been obtained. The use of the 3-dimensional stable law (Lévy law) as a transition probability
allows us to present the correlation function in an explicit form.
Proceedings of the XVII Seminar on Stability Problems for Stochastic Models, Kazan, Russian, 1995, Part II. 相似文献