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41.
Using Wagner's polarization technique and EMF method the joinic and silver ionic transport number measurements of various
compositions of the mixed system CdI2-Ag2O-CrO3 have been made. The presence of AgI in these materials has been inferred from the typical β → α phase transition of AgI,
which is characterized by an endothermic peak at around 420 K in the DSC traces of these specimens. While the structural analysis
performed by means of powder X-ray diffraction has revealed the formation of ionic phases involving polycrystalline compounds,
the Fourier transform infrared (FTIR) spectroscopic results have indicated the presence of ionic species thus confirming the
ionic nature of the products. The complex impedance studies carried out in the frequency range 20 Hz - 1 MHz and over the
temperature range 294 – 442 K have revealed that the best conducting composition, namely 55%(CdI2) – 45%(Ag2O·CrO3), would exhibit a silver ionic conductivity of 1.3×10−5Scm−1 at 294 K. 相似文献
42.
43.
44.
The present paper analyzes the properties of structural phase transitions under the extremal conditions of high pressures. In the context of the theory of density functional (TDF), the pressures of the B1–B2 transitions are calculated for small alkali-halide crystals as functions of the crystal size. The size effect of the B1–B2 transition – an increase in the transition pressure with the decreasing crystal grain radius – has been established for all investigated halides except lithium fluoride for which the dependence is reverse. 相似文献
45.
Sanzharov N. A. Yarovoi A. T. Bekhtereva E. S. Ulenikov O. N. 《Russian Physics Journal》2002,45(10):1024-1031
Analytical formulas are derived that describe the dependences of the transition probabilities in vibrational-rotational spectra of XY3-type molecules with C
3v
symmetry on the rotational quantum numbers. 相似文献
46.
A. D. Smirnov 《Journal of Applied Spectroscopy》1991,54(1):33-38
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 54, No. 1, pp. 46–50, January, 1991. 相似文献
47.
In intonation research, prominence-lending pitch movements have either been described on a linear or on a logarithmic frequency scale. An experiment has been carried out to check whether pitch movements in speech intonation are perceived on one of these two scales or on a psychoacoustic scale representing the frequency selectivity of the auditory system. This last scale is intermediary between the other two scales. Subjects matched the excursion size of prominence-lending pitch movements in utterances resynthesized in different pitch registers. Their task was to adjust the excursion size in a comparison stimulus in such a way that it lent equal prominence to the corresponding syllable in a fixed test stimulus. The comparison stimulus and the test stimulus had pitches running parallel on either the logarithmic frequency scale, the psychoacoustic scale, or the linear frequency scale. In one-half of the experimental sessions, the test stimulus was presented in the low register, while the comparison stimulus was presented in the high register, and, conversely, for the other half of the sessions. The result is that, in all cases, stimuli are matched in such a way that the average excursion sizes in different registers are equal on the psychoacoustic scale. 相似文献
48.
49.
50.
N. S. Simonović 《Few-Body Systems》2006,38(2-4):139-145
In agreement with the Kohn theorem the relative motion (rel) of three electrons in a two-dimensional parabolic trap separates
from the centre-of-mass (CM) motion. By introducing new coordinates the Hamiltonian for relative motion in the approximation
of non-interacting electrons can be taken to the normal form. The eigenstates of the normalized Hamiltonian are products of
the Fock-Darwin states for normal modes. The energy levels for relative motion are obtained by diagonalizing the exact Hamiltonian
in the eigenbasis for the non-interacting case. In this basis the interaction matrix elements can be obtained in the analytical
form. Since the rank of the Hamiltonian matrix is significantly reduced, the calculations are faster and more accurate than
those for the full (CM + rel) motion. This advantage is especially important for the calculations of excited states and the
analysis of energy spectra. 相似文献