Half-width temperature dependence of nitrogen broadened lines in the ν2 band of H2O

Forty-seven N₂ broadened water vapor line-widths have been measured in the 1845-2140 cm⁻¹ spectral range with a Fourier Transform spectrometer in the 258-330 K temperature range at a spectral resolution of 0.005 cm⁻¹ for the lines with upper state rotational quantum number up to 16. The measured exponents of the temperature dependence of the width exhibit a large range of values from 1.60 to −0.86. Theoretical calculations were made using a semi-empirical technique based on the Anderson theory. The calculated broadening coefficients as well as the temperature exponents for the half-width agree satisfactory with measured values.     

A finite element-spherical harmonics radiation transport model for photon migration in turbid media

In this paper, we solve the steady-state form of the Boltzmann transport equation in homogeneous and heterogeneous tissue-like media with a finite element-spherical harmonics (FE-P_N) radiation transport method. We compare FE-transport and diffusion solutions in terms of the ratio of absorption to reduced scattering coefficient, (μ_a/μ_s′) and the anisotropy factor g. Two different scattering phase function formulas are employed to model anisotropic scattering in the slab media with high g-value. Influence of void-like heterogeneities, and of their boundaries with the surrounding medium on the transport of photons are also examined.     

Plasmon resonance in a nanosphere

The phenomenon of plasmon resonance in a nanosphere and a nanospheroid is considered. As is known, this phenomenon does not depend explicitly on the size of these nanoparticles. However, it is shown that, actually, the resonance conditions are determined by the diameter of the nanosphere and by the length of the major axis of the nanospheroid.     

Dependence of Doubly Charged Ion Formation by the Two-Electron Mechanism on the intensity of Laser Radiation

Experimental dependences of the doubly charged ion yield N ²⁺ on the laser radiation intensity F are analyzed for the case of ion formation by the two-electron mechanism. It is shown that the region where the dependence N ²⁺(F) is characterized by the degree of nonlinearity K≈2.5 corresponds to the saturation of the process of doubly charged ion formation. This region is described well by theoretical calculations performed for Gaussian laser beams.     

Mathematical modeling of the Magnus effect in the geometrical optics approximation

The Magnus effect in multimode fibers with triangular and parabolic refractive index profiles (RIPs) is simulated in the geometrical optics approximation. The calculations confirm the linear relation between the angle of rotation Δ? and the fiber length z. The results of calculations for a spiral path with constant radius are compared with the analytical solution obtained. For a fiber with a parabolic RIP, the value of Δ? obtained in this work is one-half the result obtained in the wave approach.     

Polarized Fluorescence of Jet-Cooled indole and Carbazole and Their Complexes with Water

The spectra of the fluorescence excitation within the rotational contours of the bands of the pure electronic long-wavelength S ₀-S ₁ transitions of jet-cooled indole and carbazole molecules and their complexes with water are measured. For the carbazole-water complex, a contour with three maxima is registered, which is possibly related to the occurrence of two isomers, differing in a slight displacement of hydrogen between the nitrogen atom of the imine group of carbazole and the oxygen atom of the water molecule. The degrees of polarization of integral fluorescence upon excitation within the rotational contours of the S ₀-S ₁ electronic transition bands of the above molecules and their complexes with water are determined for the first time. The coincidence of the calculated (7.7%) and measured (7.3%) values of the degree of polarization upon excitation in the rotational Q branch of the ^b L ₁-A electronic transition of indole confirms the accepted intramolecular orientation of the transition dipole moment at an angle of 38.3° with respect to the principal axis of inertia A. Upon excitation of indole, its complex with water, and carbazole into the P and R branches, the measured and calculated degrees of polarization are also close to each other and amount to 2–3%. This confirms the occurrence of contributions to the fluorescence polarization due to the rotations of the indole molecules around the principal axes of inertia A and C.     

Hysteresis and Eddy-current Relaxation in SiFe Materials

The rate-dependent effects in metallic ferromagnetic materials with magnetization processes attributed to domain-walls motion were studied. The experimental method for eddy-current relaxation time determination was proposed. Some discrepancies between the data and theoretical predictions were observed and discussed. The origin of these discrepancies is accounted for by the decrease of viscous-type relaxation process as the rate of change of averaged magnetization is approaching zero.     

Optical third-harmonic generation in coupled microcavities based on porous silicon

The resonance features of the third-harmonic generation have been observed in 1D coupled microcavities consisting of three Bragg reflectors and two identical half-wave layers of mesoporous silicon. The third-harmonic intensity increases by a factor of about 10³ in the resonance of fundamental radiation with each of the modes of coupled microcavities. It has been shown that the resonance positions in the angular spectra of the third-harmonic intensity depend on the coupling between microcavities that is determined by the transmission of the intermediate Bragg reflector. In the framework of the transfer-matrix method with nonlinear sources, it has been shown that the basic mechanism of the enhancement of the third-harmonic generation in coupled microcavities based on porous silicon is the constructive interference of the partial third-harmonic waves that are generated by near-surface layers.     

Branes,Quantum Nambu Brackets and the Hydrogen Atom

The Nambu-bracket quantization of the hydrogen atom is worked out as an illustration of the general method. The dynamics of topological open branes is controlled classically by Nambu brackets. Such branes then may be quantized through the consistent quantization of the underlying Nambu brackets: properly defined, the quantum Nambu-brackets comprise an associative structure, although the naive derivation property is mooted through operator entwinement. For superintegrable systems, such as the hydrogen atom, the results coincide with those furnished by Hamiltonian quantization - but the method is not limited to Hamiltonian systems.