Observation of inverse Meyer–Neldel rule in thermally activated crystallization of a hybrid composite of phenol formaldehyde

We report the inverse Meyer–Neldel (MN) rule in the thermally activated crystallization of a hybrid composite of phenol formaldehyde using two experimental approaches. In the first experiment, the annealing time dependence of the pre-exponential factor K ₀ and the activation energy of crystallization E _c were studied. In the second experiment, the annealing temperature dependence of the same parameters was investigated. We observed the inverse Meyer–Neldel rule between the pre-exponential factor K ₀ and the activation energy of crystallization E _c in both cases.     

A de novo Diels-Alder strategy toward the novel pentacyclic natural product fluostatin C: a concise synthesis of 6-deoxyfluostatin C

A conceptually new Diels-Alder approach, involving a diene moiety grafted on a preformed epoxyquinone platform and a 4-hydroxy-indenone as the dienophile, delivers the pentacyclic framework of fluostatin C in one key step.     

Temperature dependent small-angle neutron scattering of CTABr—magnetic fluid emulsion

Small-angle neutron scattering studies have been carried out to check the structural integrity of citryltrimethylammonium bromide (CTABr) micelles in a magnetic fluid for different magnetic fluid concentrations at two different temperatures 303 and 333 K. It is found that the CTABr micelles grow with increasing magnetic fluid concentration and there is a decrease in the micellar size with increase in temperature.     

Thermal analysis for transient radiative cooling of a conducting semitransparent layer of ceramic in high-temperature applications

A method is developed for obtaining transient temperature distribution in a cooling semitransparent layer of ceramic. The layer is emitting, absorbing, isotropically scattering and heat conducting with a refractive index ranging from 1 to 2. The solution involves solving simultaneously the energy equation and the integral equation for the radiative flux gradient. The energy equation is solved using an implicit finite volume scheme and the integral equation of radiative heat transfer is solved using the singularity technique and Gaussian integration. The effects of scattering are investigated. It is shown that scattering has a significant effect on the transient temperature distribution and the transient mean temperature of the layer.     

High spin states in120Xe

High spin states in ¹²⁰Xe, populated via¹⁰⁷Ag(¹⁶O, p2n) and¹⁰⁸Pd(¹⁶O, 4n)reactions have been studied using γ-ray spectroscopic techniques. 21 new transitions have been added to extend the level scheme. Two S-bands are extended upto 26⁺ and 22⁺;these bands are found to cross the g. s band at hΩ=0. 39 and 0. 47 MeV. The band structures have been discussed within the framework of CSM.     

Weakly analytic sets for function spaces

We define and study weakly analytic sets for function spaces. This concept generalizes the concept of weak analyticity for function algebras. We also define weak analyticity for the space of affine functions using the ideas of convexity. We show that it coincides with the same concept regarding it as a function space. We give several examples to illustrate the concepts.     

Numerical analysis of pressure oscillations over axisymmetric spiked blunt bodies at Mach 6.80

The pressure oscillations over a forward facing spike attached to an axisymmetric blunt body are simulated by solving time-dependent compressible Navier–Stokes equations. The governing fluid flow equations are discretized in spatial coordinates employing a finite volume approach which reduces the equations to semidiscretized ordinary differential equations. Temporal integration is performed using the two-stage Runge–Kutta time stepping scheme. A global time step is used to obtain a time-accurate numerical solution. The numerical computation is carried out for a freestream Mach number of 6.80 and for spike length to hemispherical diameter ratios of 0.5, 1.0 and 2.0. The flow features around the spiked blunt body are characterized by a conical shock wave emanating from the spike tip, a region of separated flow in front of the hemispherical cap, and the resulting reattachment shock wave. Comparisons of the numerical results are made with the available experimental results, such as schlieren pictures and the surface pressure distribution along the spiked blunt body. They are found to be in good agreement. Spectral analysis of the computed pressure oscillations are performed employing fast Fourier transforms. The surface pressure oscillations over the spike and phase plots exhibit a behaviour analogous to that of the Van der Pol equation for a self-sustained oscillatory flow. Received 28 February 2001 / Accepted 17 January 2002