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排序方式: 共有76条查询结果,搜索用时 15 毫秒
41.
Research on Chemical Intermediates - We have reported trifluoroethanol (TFE) as an efficient and recyclable medium in promoting one-pot, four-component synthesis of biologically and... 相似文献
42.
In this communication,we report four component condensations of acetophenone,arylaldehydes,arylthiol,and malononitrile in the presence of Triton X-100(5 mol%) aqueous micelles.This reaction led to the formation of 4,6-diaryl-2-(arylthio)nicotinonitrile new derivatives in good yields.The FT-IR,19F NMR,1H NMR,13C NMR spectra and elemental analysis confirm the structure of compounds. 相似文献
43.
Reece JS Miller MJ Arnold MA Waterhouse C Delaplaine T Cohn L Cannon T 《Applied biochemistry and biotechnology》2003,104(1):1-11
A compact, flow-through oxygen sensor device based on luminescence quenching was used to monitor dissolved oxygen levels during
mammalian cell growth on the STS-93 mission of the Columbia space shuttle. Excitation of an oxygen-sensitive ruthenium complex
was provided by a radiolumin escent light source (0.9 mm in diameter, 2.5 mm long), and the intensity of the resulting luminescence
was measured by a simple photodiode detector. The use of radiolum inescence for the excitation light source is a unique approach
that provides many features important for long-term and remote monitoring applications. For the spaceflight experiment, human
lung fibroblast cells (WI-38) were grown in hollow-fiber bioreactors. Oxygen concentration was measured in the flow path both
before and after the bioreactor cartridge in order to gain information about the metabolism of the cells. The sensor was found
to be nonperturbing to cell growth and withstood the challenging physical conditions of shuttle launch and landing while maintaining
a stable calibration function. In addition, the sensor provided physically meaningful oxygen predictions. 相似文献
44.
Wireless Network Optimization for Federated Learning with Model Compression in Hybrid VLC/RF Systems
Wuwei Huang Yang Yang Mingzhe Chen Chuanhong Liu Chunyan Feng H. Vincent Poor 《Entropy (Basel, Switzerland)》2021,23(11)
In this paper, the optimization of network performance to support the deployment of federated learning (FL) is investigated. In particular, in the considered model, each user owns a machine learning (ML) model by training through its own dataset, and then transmits its ML parameters to a base station (BS) which aggregates the ML parameters to obtain a global ML model and transmits it to each user. Due to limited radio frequency (RF) resources, the number of users that participate in FL is restricted. Meanwhile, each user uploading and downloading the FL parameters may increase communication costs thus reducing the number of participating users. To this end, we propose to introduce visible light communication (VLC) as a supplement to RF and use compression methods to reduce the resources needed to transmit FL parameters over wireless links so as to further improve the communication efficiency and simultaneously optimize wireless network through user selection and resource allocation. This user selection and bandwidth allocation problem is formulated as an optimization problem whose goal is to minimize the training loss of FL. We first use a model compression method to reduce the size of FL model parameters that are transmitted over wireless links. Then, the optimization problem is separated into two subproblems. The first subproblem is a user selection problem with a given bandwidth allocation, which is solved by a traversal algorithm. The second subproblem is a bandwidth allocation problem with a given user selection, which is solved by a numerical method. The ultimate user selection and bandwidth allocation are obtained by iteratively compressing the model and solving these two subproblems. Simulation results show that the proposed FL algorithm can improve the accuracy of object recognition by up to 16.7% and improve the number of selected users by up to 68.7%, compared to a conventional FL algorithm using only RF. 相似文献
45.
Theorems are given which describe when high enough vanishing at the cusps implies that a Siegel modular cusp form is zero.
Formerly impractical computations become practical and examples are given in degree four. Vanishing order is described by
kernels, a type of polyhedral convex hull.
Received: November 19, 1998 / Revised: July 5, 1999 / Published online: September 5, 2000 相似文献
46.
Mohammad Reza Poor Heravi 《中国化学快报》2010,21(12):1399-1402
<正>The fluorination reaction involving aβ-ketosulfones by Selectfluor~(TM) was efficiently promoted by the ionic liquid,[Hbim]BF_4 (EL) as a reaction medium with methanol as co-solvent at room temperature under ultrasonic irradiation to afford the corresponding mono and difluoro-β-ketosulfones in excellent yields.The advantages of this method include among others the use of a recyclable, non-volatile ionic liquid,which promotes this protocol under room temperature without the requirement of any added catalyst under ultrasonic irradiation. 相似文献
47.
Mohammad Reza Poor Heravi 《Ultrasonics sonochemistry》2009,16(3):361-366
The condensation reaction involving an o-aminoaryl ketones with α-methylene ketones via the tandem addition/annulation reaction by the ionic liquid of [Hbim][BF4] (IL) as a solvent with methanol as co-solvent at room temperature under ultrasound irradiation afforded the corresponding quinolines derivatives in excellent yields. The use of ionic liquid and ultrasound, which promoted this protocol under room temperature without the requirement of any added catalyst. Quinoline derivatives are important and have a potential use as special biological drug in medicine. 相似文献
48.
Pinacho Crisóstomo FR Carrillo R León LG Martín T Padrón JM Martín VS 《The Journal of organic chemistry》2006,71(6):2339-2345
The concept of molecular simplification as a drug design strategy to shorten synthetic routes, while keeping or enhancing the biological activity of the lead drug, has been applied to (+)-muconin, an acetogenin with remarkable cytotoxicity. A novel approach that enables the stereoselective synthesis of such a natural compound or its enantiomer from a common precursor is described. An additional advantage of the method is complete stereochemical control and the decrease in the number of chemical steps required, thus providing an enhancement of the overall yield. Antiproliferative studies against the human solid tumor cell lines showed that the aliphatic chain-THF/THP fragment of (+)-muconin has modest cytotoxic activity. The strategy opens the way to preparing novel bioactive acetogenin analogues by shorter synthetic routes. 相似文献
49.
E. Vessally M. Abbasian A. Ramazani A. R. Poor Heravi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):705-708
Thermal energy gaps, ΔEs–t; enthalpy gaps, ΔHs–t; and Gibbs free energy gaps, ΔGs–t between the singlet (s) and triplet (t) states of X2C2H2C, 1X (X = CH, N, P, As, and Sb) were calculated and compared with those analogues, XC2H3C, 1′X (X = N, P, As, and Sb) at the B3LYP/6-311++G** level of theory. Density functional theory (DFT) calculations indicated that the ΔGs-t, for 1X (X = N and P) should be lower with respect to their monosubstituted 1′X . In contrast, the ΔGs-t for 1X (X = As and Sb) should be larger with respect to 1′X . The ΔGs-t for 1X and 1′X were increased in the following order: 1Sb > 1As > 1C > 1P > 1N ; 1′Sb > 1′As > 1′P > 1C > 1′N , respectively. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. 相似文献
50.
M. R. Poor Heravi 《Journal of the Iranian Chemical Society》2009,6(3):483-488
A novel and efficient procedure for the synthesis of 1,8-dioxo-octahydro-xanthenes through one-pot condensation of 5,5- dimethyl-1,3-cyclohexadione with aryl aldehydes in the presence of selectfluor? [1-(chloromethyl)-4-fluoro-1,4- diazoniabicyclo[2,2,2]octane bis(tetrafluoroborate) as catalyst under solvent free conditions was applied. It demonstrated several advantages such as good yields of products, simple operation, convenient separation, and inexpensive catalyst. 相似文献