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61.
Identification and separation of saxitoxins using hydrophilic interaction liquid chromatography coupled to traveling wave ion mobility‐mass spectrometry 下载免费PDF全文
Salomé Poyer Corinne Loutelier‐Bourhis Gaël Coadou Florence Mondeguer Julien Enche Anne Bossée Philipp Hess Carlos Afonso 《Journal of mass spectrometry : JMS》2015,50(1):175-181
The aim of this work was to develop a reliable and efficient analytical method to characterise and differentiate saxitoxin analogues (STX), including sulphated (gonyautoxins, GTX) and non‐sulphated analogues. For this purpose, hydrophilic interaction liquid chromatography (HILIC) was used to separate sulphated analogues. We also resorted to ion mobility spectrometry to differentiate the STX analogues because this technique adds a new dimension of separation based on ion gas phase conformation. Positive and negative ionisation modes were used for gonyautoxins while positive ionisation mode was used for non‐sulphated analogues. Subsequently, the coupling of these three complementary techniques, HILIC‐IM‐MS, permitted the separation and identification of STX analogues; isomer differentiation was achieved in HILIC dimension while non‐sulphated analogues were separated in the IM‐MS dimension. Additional structural characteristics concerning the conformation of STXs could be obtained using IM‐MS measurements. Thus, the collision cross sections (CCS) of STXs are reported for the first time in the positive ionisation mode. These experimental CCSs correlated well with the calculated CCS values using the trajectory method. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
62.
On the occasion of the celebration of Prof. Rosa Caballol's 65's birthday, a symposium was organized by the Quantum Chemistry Group of the Universitat Rovira i Virgili (Tarragona, Spain) under the title “Theoretical Chemistry in Spain told by women.” The symposium gave a representative illustration of the research in theoretical chemistry in Spain, which is not only very diverse, but also in many areas at the forefront of the field. In this article, we summarize the contributions made by Rosa Caballol and coworkers. Emphasis lies on the developments of wave function based methods to accurately describe electron correlation effects in systems with unpaired electrons. Besides discussing some illustrative applications, we will also explore the limits of the existing methods and outline the perspectives of how one can possibly overcome them. © 2014 Wiley Periodicals, Inc. 相似文献
63.
The copper(I) catalyzed reaction of an enamide with an iminoiodane, in the presence of an alcohol, triggers the direct alkoxyamination of the double bond. This transformation represents a straightforward access to α-amino aminals in a completely regio- and diastereoselective manner. Use of a chiral Box ligand allows this reaction to be carried out in an enantioselective fashion. 相似文献
64.
A postsynthetic modification (PSM) scheme for metal-organic frameworks (MOFs) has been developed using a tetrazine-based "Click" reaction. It was found that the efficacy of this modification procedure was dependent on the MOF topology and, in the case of an isoreticular MOF (IRMOF) system, required the formation of a mixed-ligand IRMOF with a suitable ratio of 1,4-benzenedicarboxylate (BDC) and an olefin-tagged BDC derivative. On the basis of the versatile use of tetrazine "Click" chemistry in bioconjugate chemistry, we expect that this scheme will prove to be a useful reaction for preparing functionalized materials, including MOFs. 相似文献
65.
Carmen J. Calzado Celestino Angeli Coen de Graaf Rosa Caballol 《Theoretical chemistry accounts》2011,128(4-6):505-519
The magnetic coupling in organic biradicals has been analyzed by means of ab initio wave function-based methods. Attention is focused on the coupling between the spin moments localized on the NO-groups in meta and para phenylene-bridged nitroxides, and bis(nitronyl) nitroxide and bis(imino) nitroxide biradicals. The leading mechanisms governing the coupling have been isolated by means of class-partitioned CI calculations. It was found that the mechanisms of the coupling in the para and meta phenylene-bridged nitroxides are similar to that found in transition metal complexes, while for the other biradicals the dominance of other mechanisms (like the spin polarization) imposes restrictions on the computational strategy to be followed to best estimate the coupling. 相似文献
66.
67.
Ekaterina A. Shilova Valery P. Perevalov Corinne Moustrou 《Tetrahedron letters》2007,48(23):4127-4130
A convenient new synthetic route to p-aminophenylaminobenzo- and naphthopyrans was developed via palladium-catalyzed C-N coupling. It was demonstrated that novel targeted aminoderivatives reveal photochromic properties. The structure of intermediate p-nitrophenylaminochromenes was confirmed by X-ray crystallographic analysis. 相似文献
68.
Corinne Coudun Franois Grillon Jean-Franois Hochepied 《Colloids and surfaces. A, Physicochemical and engineering aspects》2006,280(1-3):23-31
The aim of the present work is to determine at 60 °C, the influence of the specific nature of nickel salt and pH on nickel hydroxide features such as crystallographic structure and morphology. Within the range 8 ≤ pH ≤ 11.5, a home-made nickel functionalized surfactant, nickel di-dodecylsulfate Ni(C12H25SO4)2 is compared to usual salts (nickel nitrate Ni(NO3)2 and nickel sulfate NiSO4). In both cases, a sharp transition appears for pH about 10. In the classic salt case, the transition mainly affects morphology, that could be evidenced by the crosschecking of complementary techniques as SEM and nitrogen gas adsorption. For pH < 10, β-Ni(OH)2 platelets are yielded, whereas more basic conditions lead to randomly aggregated nano-grains of badly crystallized β hydroxide. Inversely, by employing the functionalized surfactant, 2D morphology is maintained in the whole pH-range, but the crystal structure is pH-controlled ( phase with interlamellar dodecylsulfate for pH ≤ 9.5, and β phase for pH ≥ 10.5). 相似文献
69.
Functionalization of the diaminodibenzocrown ethers with 2H-[1]benzopyrane and 3H-naphtho[2,1-b]pyrane units by Buchwald-Hartwig C-N coupling was developed. It is demonstrated that the novel molecule possesses photochromic properties that can be modified by the complex formation process. 相似文献
70.
Numerical simulations are used to study the effect of the frequency dependence of the effective mode area in photonic crystal fiber on supercontinuum generation. We quantify how the frequency dependence of the effective area influences the propagation characteristics through a modified optical shock term and identify the major consequence as a reduction in the extreme long-wavelength edge of the supercontinuum spectrum. Our results show that, for the parameter regimes used in many previous supercontinuum generation experiments using near-infrared femtosecond pump sources around 800 nm, this effect would be expected to be negligible. However, for pumps in the 1000–1500 nm range, the inclusion of this effect would be expected to be crucial for accurate comparison of simulations with experiment. 相似文献