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Hajer Bahouri Clotilde Fermanian-Kammerer Isabelle Gallagher 《Comptes Rendus Mathematique》2009,347(17-18):1021-1024
We establish pseudo-differential calculus on the Heisenberg group by defining an algebra of operators acting continuously on Sobolev spaces and containing the class of differential operators. Our approach puts into light microlocal directions and completes, with the Littlewood–Paley theory developed by Bahouri et al., a microlocal analysis of the Heisenberg group. To cite this article: H. Bahouri et al., C. R. Acad. Sci. Paris, Ser. I 347 (2009). 相似文献
85.
Extraction of lanthanides from aqueous solution by using room-temperature ionic liquid and supercritical carbon dioxide in conjunction 总被引:2,自引:0,他引:2
Mekki S Wai CM Billard I Moutiers G Burt J Yoon B Wang JS Gaillard C Ouadi A Hesemann P 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(6):1760-1766
For the first time, the study of a three-step extraction system of water/ionic liquid/supercritical CO2 has been performed. Extraction of trivalent lanthanum and europium from an aqueous nitric acid solution to a supercritical CO2 phase via an imidazolium-based ionic liquid phase is demonstrated, and extraction efficiencies higher than 87 % were achieved. The quantitative extraction is obtained by using different fluorinated beta-diketones with and without the addition of tri(n-butyl)phosphate. The complexation phenomenon occurring in the room-temperature ionic-liquid (RTIL) phase was evidenced by using luminescence spectroscopy. 相似文献
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87.
Clotilde Fermanian Kammerer 《Monatshefte für Mathematik》2004,142(4):281-313
We study adiabatic decoupling for Dirac equation with some scaling which yields that the mass appears with a coefficient where is the semi-classical parameter and > 0. Therefore, the system presents an avoided crossing. The scale = 1/2 is critical: adiabatic decoupling holds for (0,1/2) while for 1/2, there is energy transfer at leading order between the two modes. We describe this transfer in terms of two-scale Wigner measures by means of Landau-Zener formula which takes into account the change of polarization of the measures after the crossing. 相似文献
88.
Improved mutasynthetic approaches for the production of modified aminocoumarin antibiotics 总被引:1,自引:0,他引:1
Anderle C Hennig S Kammerer B Li SM Wessjohann L Gust B Heide L 《Chemistry & biology》2007,14(8):955-967
This study reports improved mutasynthetic approaches for the production of aminocoumarin antibiotics. Previously, the mutasynthetic production of aminocoumarins with differently substituted benzoyl moieties was limited by the substrate specificity of the amide synthetase CloL. We expressed two amide synthetases with different substrate specificity, CouL and SimL, in appropriately engineered producer strains. After feeding of precursor analogs that were not accepted by CloL, but by SimL or CouL, a range of aminocoumarins, unattainable in our previous experiments, was produced and isolated in preparative amounts. Further, we developed a two-stage mutasynthesis procedure for the production of hybrid antibiotics that showed the substitution pattern of novobiocin in the aminocoumarin moiety and that of clorobiocin in the deoxysugar moiety. The substitution pattern of the benzoyl moiety was determined by external addition of an appropriate precursor. Twenty-five aminocoumarin compounds were prepared by these methods, and their structures were elucidated with mass and 1H-NMR spectroscopy. 相似文献
89.
Reactivity of MnII with superoxide. Evidence for a [MnIIIOO]+ unit by low-temperature spectroscopies
Groni S Blain G Guillot R Policar C Anxolabéhère-Mallart E 《Inorganic chemistry》2007,46(6):1951-1953
Manganese superoxide dismutase cycles between the MnIII and MnII states to produce oxygen and hydrogen peroxide from superoxide. The formation of an adduct has been suggested, but its nature remains questionable because both [MnIIOO-] and [MnIIIOO2-] redox states have been proposed. Study of the reactivity of superoxide with manganese complexes is of current interest. The reaction of [(L)MnII]2+ [L = N-methyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine] with potassium superoxide has been investigated at low temperature in an anhydrous solvent using various techniques. Upon the addition of ca. 2 equiv of potassium superoxide, the [(L)MnII]2+ colorless solution turned blue and the UV-vis spectrum displayed a band at 590 nm (165 M(-1) cm(-1)) and a shoulder at 430 nm (100 M(-1) cm(-1)). Electrospray ionization mass spectrometry showed a peak (m/z = 434.1) assigned to [(L)MnO2]+. The X-band electron paramagnetic resonance spectrum parallel mode displayed a six-line signal separated by 6.6 mT and centered at 86 mT (g = 8.1). These results support the formation of an [MnIIIOO]+ adduct. 相似文献
90.
Yohan Gisbert Dr. Seifallah Abid Dr. Claire Kammerer Prof. Dr. Gwénaël Rapenne 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(47):12019-12031
This review highlights the major efforts devoted to the development of molecular gears over the past 40 years, from pioneering covalent bis-triptycyl systems undergoing intramolecular correlated rotation in solution, to the most recent examples of gearing systems anchored on a surface, which allow intermolecular transmission of mechanical power. Emphasis is laid on the different strategies devised progressively to control the architectures of molecular bevel and spur gears, as intramolecular systems in solution or intermolecular systems on surfaces, while aiming at increased efficiency, complexity and functionality. 相似文献