全文获取类型
收费全文 | 2716篇 |
免费 | 102篇 |
国内免费 | 7篇 |
专业分类
化学 | 2125篇 |
晶体学 | 7篇 |
力学 | 41篇 |
数学 | 384篇 |
物理学 | 268篇 |
出版年
2024年 | 2篇 |
2023年 | 25篇 |
2022年 | 78篇 |
2021年 | 94篇 |
2020年 | 71篇 |
2019年 | 76篇 |
2018年 | 37篇 |
2017年 | 42篇 |
2016年 | 109篇 |
2015年 | 96篇 |
2014年 | 102篇 |
2013年 | 166篇 |
2012年 | 195篇 |
2011年 | 201篇 |
2010年 | 153篇 |
2009年 | 113篇 |
2008年 | 169篇 |
2007年 | 150篇 |
2006年 | 136篇 |
2005年 | 136篇 |
2004年 | 130篇 |
2003年 | 102篇 |
2002年 | 98篇 |
2001年 | 34篇 |
2000年 | 40篇 |
1999年 | 31篇 |
1998年 | 25篇 |
1997年 | 25篇 |
1996年 | 30篇 |
1995年 | 21篇 |
1994年 | 22篇 |
1993年 | 18篇 |
1992年 | 21篇 |
1991年 | 7篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 7篇 |
1987年 | 10篇 |
1986年 | 8篇 |
1985年 | 7篇 |
1984年 | 2篇 |
1983年 | 5篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1970年 | 2篇 |
排序方式: 共有2825条查询结果,搜索用时 0 毫秒
991.
Albrecht M Wessel C de Groot M Rissanen K Lüchow A 《Journal of the American Chemical Society》2008,130(14):4600-4601
A series of pentafluorophenyl substituted ammonium, iminium, amidinium, and phosphonium halides are presented which show extensive anion-pi interactions. Hereby, the well-known anion-donor-pi-acceptor as well as "eta6" anion-pi-complex type interactions are observed. The latter is supported by fixation of the anion on top of the aromatic system through hydrogen bonding. This arrangement was investigated by theoretical methods showing a highly attractive anion-pi interaction. In addition an eta2-type coordination of the anions to only two C-atoms of the electron-deficient ring system is described. 相似文献
992.
Swanson CH Shaikh HA Rogow DL Oliver AG Campana CF Oliver SR 《Journal of the American Chemical Society》2008,130(35):11737-11741
We have discovered a rare example of a cationically charged inorganic material. The layered structure is an example outside the extensively studied isostructural set of anionic clays/layered double hydroxides and our previously reported lead fluoride nitrate. For the present compound, the antimony oxide hydroxide layers are positively charged and are templated by anionic alkylenedisulfonate. The organic molecules are only bonded electrostatically to the layers with sulfonate oxygen to antimony distances beyond the covalent range. The material catalyzes a ketal formation reaction as a Lewis acid without the need for drying the solvent before the reaction or a nonaqueous medium such as toluene. The catalyst is heterogeneous and is completely recovered after the catalysis for reapplication. 相似文献
993.
994.
Botek E Giribet C Ruiz de Azúa M Martín Negri R Bernik D 《The journal of physical chemistry. A》2008,112(30):6992-6998
The IPPP-CLOPPA-INDO/S method is introduced to investigate the static molecular polarizability in macromolecules. As an example of application, the polarizability of phospholipidic compounds, with and without the presence of water molecules has been estimated. The IPPP technique was employed to calculate the polarizability of the polar head and the hydrocarbon chains separately to analyze the feasibility of evaluating the total polarizability of the molecule by addition of these two projected results. INDO/S dipole moments of different fragments of the complex molecule were obtained by means of localized molecular orbitals in order to evaluate the charge transfer in the system. 相似文献
995.
Caltagirone C Gale PA Hiscock JR Brooks SJ Hursthouse MB Light ME 《Chemical communications (Cambridge, England)》2008,(26):3007-3009
Neutral 1,3-di(1H-indol-7-yl)ureas are selective dihydrogen phosphate receptors in polar solvent mixtures (DMSO-d(6)-25% water). 相似文献
996.
Mariano Asteasuain Matheus Soares Marcelo K. Lenzi Robin A. Hutchinson Michael Cunningham Adriana Brandolin José Carlos Pinto Claudia Sarmoria 《大分子反应工程》2008,2(5):414-421
“Living” radical polymerization is a relatively new polymerization process that can be used to prepare resins with controlled structures. In this work, a mathematical model developed previously to describe nitroxide‐mediated “living” radical polymerizations performed in tubular reactors is used for the optimization of the process and obtainment of tailor‐made MWDs. Operating conditions and design variables are determined with the help of optimization procedures in order to produce polymers with specified MWDs. It is shown that bimodal and trimodal MWDs, with given peak locations, can be obtained through proper manipulation of the operating conditions. This indicates that the technique discussed in this work is suitable for detailed design of the MWD of the final polymer.
997.
998.
999.
A mild and efficient methodology for the rearrangement of protected asparagine and protected glutamine is reported; good results are obtained with a wide selection of protecting groups. 相似文献
1000.
Prof. Guowei Li Dr. Qun Yang Prof. Kaustuv Manna Dr. Yudi Zhang Dr. Patrick Merz Chandra Shekhar Yang Zhang Dr. Hua Lv Dr. Anastasios Markou Dr. Yan Sun Prof. Claudia Felser 《Angewandte Chemie (International ed. in English)》2023,62(27):e202303296
The study of heterogeneous reactions for enantiomeric processes based on inorganic crystals has been resurgent in recent years. However, the question remains how homochirality develops in nature and chemical reactions. Here, the successful growth of B20 group PdGa single crystals with different chiral lattices enabled us to achieve enantioselective recognition of 3,4-dihydroxyphenylalanine (DOPA) based on a new mechanism, namely orbital angular momentum (OAM) polarization. The orbital textures of PdGa crystals indicate large OAM polarization near the Fermi level and carrying opposite signs. A positive or negative magnetization in the [111] direction is expected depending on the chiral lattice of PdGa crystals. Due to this, the adsorption energies of PdGa crystals and DOPA molecules differ depending on how well the O-2p orbital of DOPA pairs with the Pd-4d orbital of PdGa. The results provide one possible explanation for how chirality arises in nature by providing an enantioselective route with pure inorganic crystals. 相似文献