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91.
92.
Agustin Campos Rafael Gavara Roberto Tejero Clara Gomez Bernardo Celda 《Journal of Polymer Science.Polymer Physics》1989,27(8):1559-1597
The Flory–Huggins theory as modified by Pouchlý has been applied to calculate preferential (λ) and total (Y) sorption coefficients for a ternary polymer system. The ternary interaction function (?1?2?3GT(u1, ?3)) is described as the product of three independent binary functions. This expression allows prediction of λ and Y from binary interaction parameters χ, χ, g, g, and g12(?10). Three ternary polymer systems are used to check the validity of the expression. Moreover for polymer systems in which the parameters g and/or g are unknown, a procedure to evaluate them has been developed and verified on systems for which sufficient experimental information is available. 相似文献
93.
Le Naour C Trubert D Di Giandomenico MV Fillaux C Den Auwer C Moisy P Hennig C 《Inorganic chemistry》2005,44(25):9542-9546
The present work describes the first structural studies of protactinium(V) in sulfuric and hydrofluoric acid media using X-ray absorption spectroscopy. The results show unambiguously the absence of the trans-dioxo bond that characterizes the other early actinide elements such as U and Np. In concentrated sulfuric acid (13 M), Pa(V) is proved to exhibit a single oxo bond as postulated in the literature for species in more dilute media. In a 0.5 M HF medium, XANES and EXAFS spectra indicate the absence of any oxo bond: Pa(V) exists in the form of a pure fluoro complex. 相似文献
94.
Fraile JM García JI Herrerías CI Mayoral JA 《Chemical communications (Cambridge, England)》2005,(37):4669-4671
Condensation of tetraethoxysilane with silane-functionalized bis(oxazolines) in the presence of dodecylamine leads to hybrid materials whose textural and catalytic properties depend on both the ligand and the spacer structure. 相似文献
95.
Tortosa-Estorach C Ruiz N Masdeu-Bultó AM 《Chemical communications (Cambridge, England)》2006,(26):2789-2791
High selectivity in acids is obtained in the first example of hydrocarboxylation of 1-octene in supercritical carbon dioxide using a Pd/P(4-C6H4-CF3)3 catalyst system and a perfluorinated surfactant. 相似文献
96.
97.
Remco van der Hofstad Johan S.H. van Leeuwaarden Clara Stegehuis 《Stochastic Processes and their Applications》2018,128(12):4246-4276
To understand mesoscopic scaling in networks, we study the hierarchical configuration model (HCM), a random graph model with community structure. Connections between communities are formed as in a configuration model. We study the component sizes of HCM at criticality, and we study critical bond percolation. We find the conditions on the community sizes such that the critical component sizes of HCM behave similarly as in the configuration model. We show that the ordered components of a critical HCM on vertices are . More specifically, the rescaled component sizes converge to the excursions of a Brownian motion with parabolic drift. 相似文献
98.
We study a generalization of the Turán problem in random graphs. Given graphs T and H, let ex(G(n,p),T,H) be the largest number of copies of T in an H‐free subgraph of G(n,p). We study the threshold phenomena arising in the evolution of the typical value of this random variable, for every H and every 2‐balanced T. Our results in the case when m2(H) > m2(T) are a natural generalization of the Erd?s‐Stone theorem for G(n,p), proved several years ago by Conlon‐Gowers and Schacht; the case T = Km was previously resolved by Alon, Kostochka, and Shikhelman. The case when m2(H) ≤ m2(T) exhibits a more complex behavior. Here, the location(s) of the (possibly multiple) threshold(s) are determined by densities of various coverings of H with copies of T and the typical value(s) of ex(G(n,p),T,H) are given by solutions to deterministic hypergraph Turán‐type problems that we are unable to solve in full generality. 相似文献
99.
Clara Carlota Sílvia Chá António Ornelas 《NoDEA : Nonlinear Differential Equations and Applications》2013,20(2):273-293
Given any AC solution ${\overline{x} : [a,b] \rightarrow \mathbb{R}^{n}}$ to the convex ordinary differential inclusion $$x^{\prime} ( t) \in co\{v^{1} ( t), \ldots, v^{m} ( t)\} \qquad a.e. on [ a,b], \qquad \qquad (^{*})$$ we aim at solving the associated nonconvex inclusion $$x^{\prime} ( t) \in \{v^{1} ( t), \ldots, v^{m} ( t)\} \qquad a.e.,x( a) = \overline{x} ( a), x( b) = \overline{x} ( b), \qquad \qquad (^{**})$$ under an extra pointwise constraint (e.g. on the first coordinate): $$x_{1} ( t) \leq \overline{x}_{1} ( t) \qquad \forall t \in [ a,b]. \qquad \qquad \qquad (^{***})$$ While the unconstrained inclusion (**) had been solved already in 1940 by Liapunov, its constrained version, with (***), was solved in 1994 by Amar and Cellina in the scalar n = 1 case. In this paper we add an extra geometrical hypothesis which is necessary and sufficient, in the vector n > 1 case, for it existence of solution to the constrained inclusion (**) and (***). We also present many examples and counterexamples to the 2 × 2 case. 相似文献
100.
Clara L. Aldana 《Annals of Global Analysis and Geometry》2013,44(2):169-216
The goal of this article is to prove that on surfaces with asymptotically cusp ends the relative determinant of pairs of Laplace operators is well defined. We consider a surface with cusps $(M,g)$ and a metric $h$ on the surface that is a conformal transformation of the initial metric $g$ . We prove the existence of the relative determinant of the pair $(\Delta _{h},\Delta _{g})$ under suitable conditions on the conformal factor. The core of the paper is the proof of the existence of an asymptotic expansion of the relative heat trace for small times. We find the decay of the conformal factor at infinity for which this asymptotic expansion exists and the relative determinant is defined. Following the paper by B. Osgood, R. Phillips, and P. Sarnak about extremal of determinants on compact surfaces, we prove Polyakov’s formula for the relative determinant and discuss the extremal problem inside a conformal class. We discuss necessary conditions for the existence of a maximizer. 相似文献