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Antoine Franche Claire Imbs Antoine Fayeulle Franck Merlier Muriel Billamboz Estelle Léonard 《中国化学快报》2020,31(3):706-710
Botrytis cinerea is a necrotrophic fungusth at a ffects various plant species.Chemical control is an ecessity and as much as possible,eco-friendly conditions and bioresources to obtain these chemicals should be used.In this context,a series of products w as obtained from salicylaldehyde using zinc as a powerful reagent and tested for antifungal activity against Botrytis cinerea. 相似文献
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Stéphane Sengmany Claire Ceballos Romain Belhadj Christine Cachet‐Vivier Erwan Le Gall Blandine Brissault Jacques Penelle Eric Léonel 《Journal of polymer science. Part A, Polymer chemistry》2012,50(5):900-911
Thiophene monomers displaying a dimethylenecarboxylate (CH2CH2COOR) substituent on the 3‐position of the aromatic ring can be easily obtained and in one step from the electrochemically induced reaction of 3‐bromothiophene with the corresponding acrylate (CH2?CHCOOR). The synthesis of the ethyl ester monomer, of related 2,5‐dihalogenothiophenes, and their polymerization are reported. Despite the surprisingly low solubilities displayed by the polymers, a full spectroscopic characterization could be performed and the data fully analyzed. Oxidative polymerizations (FeCl3 or electropolymerization) yield a regioirregular polythiophene, with 60–70% of head‐to‐tail diads. Both experimental and theoretical results suggest that the nonconjugated ester plays a very minor role—if any—in the polymerizations under oxidative conditions, but has a significant influence on the polymer properties. Preliminary attempts to polymerize the dihalogenothiophenes under reductive conditions were hampered by the even lower solubilities exhibited by the regioregular oligomers. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
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Jens Linnek Anne‐Claire Mitaine‐Offer Thomas Paululat Marie‐Aleth Lacaille‐Dubois 《Magnetic resonance in chemistry : MRC》2012,50(12):798-802
From the branches of Pittosporum senacia Putterlick (Pittosporaceae), two new triterpenoid saponins, senaciapittosides A and B (1, 2), were isolated. Their structures were elucidated by extensive analysis of one‐ and two‐dimensional nuclear magnetic resonance spectroscopy, high‐resolution electrospray ionization mass spectrometry (HR‐ESIMS) and chemical evidence as 3‐O‐[β‐d ‐glucopyranosyl‐(1 → 2)]‐[α‐l ‐arabinopyranosyl‐(1 → 3)]‐[α‐l ‐arabinofuranosyl‐(1 → 4)]‐β‐d ‐glucuronopyranosyl oleanolic acid 28‐O‐β‐d ‐glucopyranosyl ester (1) and 3‐O‐[β‐d ‐glucopyranosyl‐(1 → 2)]‐[α‐l ‐arabinopyranosyl‐(1 → 3)]‐[α‐l ‐arabinofuranosyl‐(1 → 4)]‐β‐d ‐glucuronopyranosyl‐22‐O‐α‐l ‐arabinopyranosyl‐21‐acetoxy R1‐barrigenol (2). Compound 2 presents an unusual glycosylation at C‐22 of its aglycone. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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Development of laser ablation multi‐collector inductively coupled plasma mass spectrometry for boron isotopic measurement in marine biocarbonates: new improvements and application to a modern Porites coral
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Maria Betzabeth Espina-Benitez Jérôme Randon Claire Demesmay 《Separation & Purification Reviews》2018,47(3):214-228
Boronate affinity chromatography (BAC) is commonly used in sample preparation techniques for its specific selectivity for cis-diol-containing compounds. Various chromatographic materials based on phenyl-boronic acid (PBA) functionalization have been designed. This review aims to present the versatility of the underlying BAC mechanisms. The PBA moiety presents secondary/complementary/interfering interactions, i.e., hydrophobic, electrostatic and/or hydrogen-bonding interactions. The comprehensive understandings of these mechanisms are very helpful to manipulate separation selectivity, which is a key feature in biomolecular sample treatment. Each BAC interaction is reviewed and illustrated by specific examples. Special attention is given to the underlying role of PBA supports for sugars, glycans and glycoconjugates recognition. 相似文献
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Keteniminium salts are powerful electrophilic heterocumulene reagents well‐known for their selectivity and stereocontrol in [2+2] cycloadditions to olefins and carbonyl derivatives. Furthermore, they are readily accessible from stable and simple precursors under a variety of different conditions. Herein, we present the chemistry of keteniminium salts with the hindsight of time, describe preparation methods, recent [2+2] chemistry, mechanistic studies, and assorted applications that significantly extend the scope of utility of these unique electrophilic heterocumulenes. 相似文献