全文获取类型
收费全文 | 1141篇 |
免费 | 42篇 |
专业分类
化学 | 827篇 |
晶体学 | 8篇 |
力学 | 34篇 |
数学 | 85篇 |
物理学 | 229篇 |
出版年
2023年 | 8篇 |
2022年 | 24篇 |
2021年 | 23篇 |
2020年 | 16篇 |
2019年 | 23篇 |
2018年 | 5篇 |
2017年 | 7篇 |
2016年 | 20篇 |
2015年 | 26篇 |
2014年 | 47篇 |
2013年 | 43篇 |
2012年 | 73篇 |
2011年 | 90篇 |
2010年 | 53篇 |
2009年 | 72篇 |
2008年 | 89篇 |
2007年 | 71篇 |
2006年 | 69篇 |
2005年 | 57篇 |
2004年 | 36篇 |
2003年 | 27篇 |
2002年 | 28篇 |
2001年 | 19篇 |
2000年 | 15篇 |
1999年 | 16篇 |
1998年 | 12篇 |
1997年 | 21篇 |
1996年 | 14篇 |
1995年 | 10篇 |
1994年 | 17篇 |
1993年 | 11篇 |
1992年 | 14篇 |
1991年 | 8篇 |
1990年 | 9篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 4篇 |
1986年 | 8篇 |
1985年 | 8篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 8篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 8篇 |
1975年 | 5篇 |
1974年 | 12篇 |
1973年 | 12篇 |
1968年 | 3篇 |
排序方式: 共有1183条查询结果,搜索用时 15 毫秒
61.
Hsieh HT Psaltis D Beyer O Maxein D von Korff Schmising C Buse K Sturman B 《Optics letters》2005,30(17):2233-2235
Spatial gratings are recorded holographically by two femtosecond pump pulses at 388 nm in lithium niobate (LiNbO3) crystals and read out by a Bragg-matched, temporally delayed probe pulse at 776 nm. We claim, to our knowledge, the first holographic pump-probe experiments with subpicosecond temporal resolution for LiNbO3. An instantaneous grating that is due mostly to the Kerr effect as well as a long-lasting grating that results mainly from the absorption caused by photoexcited carriers was observed. The Kerr coefficient of LiNbO3 for our experimental conditions, i.e., pumped and probed at different wavelengths, was approximately 1.0 x 10(-5) cm2/GW. 相似文献
62.
A simple spectrophotometric method is proposed for determining deacetylation degrees (DD) of chitinous materials using phosphoric acid as the UV-transparent solvent system. Calibrating by the extinction coefficients (A(210)) of D-glucosamine and N-acetyl-D-glucosamine, DD values (24-88%) were computed numerically. The results correlated well (R(2) = 0.9805, n = 50) with those obtained by solid-state (13)C NMR. Comparison of the results obtained by the proposed UV method and solid-state (13)C NMR. 相似文献
63.
Electrophoresis of biological cells: charge-regulation and multivalent counterions association model
The electrophoresis of a biological cell is analyzed theoretically. An entity, which is of amphoteric nature, is used to simulate its electrophoretic behavior. To reflect conditions of practical interest, we assume that the liquid phase contains mixed (a:b)+(c:b) electrolytes, where a and c are the valences of cations, and b is the valence of anions. We consider the case where the surface of a cell contains both bivalent acidic and monovalent basic functional groups, the dissociation/association of them yields fixed surface charge, and the multivalent cations in the liquid phase are allowed to combine with dissociated acidic functional groups, which has the effect of lowering the charge density on cell surface. The electrophoretic behaviors of a cell under various conditions are illustrated. The results obtained can be used to identify the types of functional groups that may be present on cell surface. On the other hand, if the surface functional groups involved in cell electrophoresis are known, then their density and the associated dissociation/association constants can be estimated from experimental data. 相似文献
64.
C.?T.?Hsieh J.?T.?LueEmail author 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,35(3):357-364
The electron spin resonance (ESR) spectrometer, a very sensitive instrument with fast detecting window to explore quantum phase transitions for magnetic nanoparticles, was exploited to study the fascinating interplay between thermal and quantum fluctuations in the vicinity of a quantum critical point. We have measured ESR in ferrofluid samples containing nanosize particles of Fe2O3. The evolution of the ESR spectrum with temperature suggests that quantum tunneling of spins occurs in single domain magnetic particles in the low temperature regime. The effects of various microwave fields, particle sizes, and temperatures on the magnetic states of single domain spinel ferrite nanoparticles are investigated. We can consistently explain experimental data assuming that, as the temperature decreases, the spectrum changes from superparamagnetic (SPR) to blocked SPR and finally evolves quantum superparamagnetic behaviour as the temperature lowers down further. A nanoparticle system of a highly anisotropic magnetic material can be qualitatively specified by a simple quantum spin model, or by the Heisenberg model with strong easy-plane anisotropy.Received: 29 August 2003, Published online: 15 October 2003PACS:
76.30.-v Electron paramagnetic resonance and relaxation - 75.40.Cx Static properties (order parameter, static susceptibility, heat capacities, critical exponents, etc.) - 05.30.-d Quantum statistical mechanics - 75.50.Dd Nonmetallic ferromagnetic materials 相似文献
65.
Po-Hsun Hsieh 《Geometriae Dedicata》2003,97(1):99-113
We study a nonidentity transvection (i.e. (strictly) hyperbolic isometry) or nonidentity Heisenberg translation f of complex hyperbolic space H
n and a Dirichlet polyhedron P of the cyclic group f. We have four main results: (a) If z & in H
n and the axis of a nonidentity transvection are not complex collinear, then, roughly speaking, any two distinct 'naturally arising' geodesics passing through z are not complex collinear. (b) If g is also a transvection or Heisenberg translation of H
n and z & in H
n such that f(z)=g(z) and f
–1(z)=g
–1(z), then f=g. (c) We classify all this kind of polyhedra up to congruence in H
n. (d) We obtain an equivalent condition for P to be cospinal (which means that the complex spines of the two sides of P coincide) in terms of the distance of the spines of the two sides of P. 相似文献
66.
Rohit Deo Mengchen Hsieh Clifford M. Hurvich Philippe Soulier 《Statistical Inference for Stochastic Processes》2000,3(3):291-292
Volume Contents
Volume contents 相似文献67.
Analysis of the geometric properties of a mean-field HP model on a square lattice for protein structure shows that structures with a large number of switchbacks between surface and core sites are chosen favorably by peptides as unique ground states. Global comparison of model (binary) peptide sequences with concatenated (binary) protein sequences listed in the Protein Data Bank and the Dali Domain Dictionary indicates that the highest correlation occurs between model peptides choosing the favored structures and those portions of protein sequences containing alpha helices. 相似文献
68.
Jaw-Yen Yang Tse-Yang Hsieh Yu-Hsin Shi Kun Xu 《Journal of computational physics》2007,227(2):967-982
A class of high-order kinetic flux vector splitting schemes are presented for solving ideal quantum gas dynamics based on quantum statistical mechanics. The collisionless quantum Boltzmann equation approach is adopted and both Bose–Einstein and Fermi–Dirac gases are considered. The formulas for the split flux vectors are derived based on the general three-dimensional distribution function in velocity space and formulas for lower dimensions can be directly deduced. General curvilinear coordinates are introduced to treat practical problems with general geometry. High-order accurate schemes using weighted essentially non-oscillatory methods are implemented. The resulting high resolution kinetic flux splitting schemes are tested for 1D shock tube flows and shock wave diffraction by a 2D wedge and by a circular cylinder in ideal quantum gases. Excellent results have been obtained for all examples computed. 相似文献
69.
Darius H. Torchinsky David Hsieh J.L. Luo Nuh Gedik 《Journal of Physics and Chemistry of Solids》2011,72(5):519-522
We report on band-dependent quasiparticle dynamics in the hole-doped Ba-122 pnictides measured by ultrafast pump-probe spectroscopy. In the superconducting state of the optimal and over hole-doped samples, we observe two distinct relaxation processes: a fast component whose decay rate increases linearly with excitation density and a slow component whose relaxation is independent of excitation strength. We argue that these two components reflect the recombination of quasiparticles in the two hole bands through intraband and interband processes. We also find that the thermal recombination rate of quasiparticles increases quadratically with temperature in all samples. The temperature and excitation density dependence of the decays indicates fully gapped hole bands and nodal or very anisotropic electron bands. 相似文献
70.
Numerical experiments with several variants of the original weighted essentially non‐oscillatory (WENO) schemes (J. Comput. Phys. 1996; 126 :202–228) including anti‐diffusive flux corrections, the mapped WENO scheme, and modified smoothness indicator are tested for the Euler equations. The TVD Runge–Kutta explicit time‐integrating scheme is adopted for unsteady flow computations and lower–upper symmetric‐Gauss–Seidel (LU‐SGS) implicit method is employed for the computation of steady‐state solutions. A numerical flux of the variant WENO scheme in flux limiter form is presented, which consists of first‐order and high‐order fluxes and allows for a more flexible choice of low‐order schemes. Computations of unsteady oblique shock wave diffraction over a wedge and steady transonic flows over NACA 0012 and RAE 2822 airfoils are presented to test and compare the methods. Various aspects of the variant WENO methods including contact discontinuity sharpening and steady‐state convergence rate are examined. By using the WENO scheme with anti‐diffusive flux corrections, the present solutions indicate that good convergence rate can be achieved and high‐order accuracy is maintained and contact discontinuities are sharpened markedly as compared with the original WENO schemes on the same meshes. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献