A new simulation method is proposed coupling deterministic and stochastic methods by an adaptive domain decomposition based on local granular equilibrium rating. This method reduces the computational effort compared to the fully stochastic method by roughly an order of magnitude, without significant loss of accuracy. Furthermore with this method appropriate boundary conditions for the solid phase can easily be derived. 相似文献
Sixteen parallel polymerization reactions of 2‐ethyl‐2‐oxazoline have been performed at different temperatures in an automated synthesizer that allowed individual heating of each reactor. During the reactions samples were taken automatically, which were characterized by means of both online GPC and offline GC, in order to optimize the reaction temperature and to determine the activation energy of the polymerization.