The possibility of different time scales in the dynamics of pore imbibition

To model the imbibition of liquids into porous solids, use is often made of the Lucas-Washburn equation, which relates the distance of penetration of a liquid at a given time to the pore radius, the viscosity and surface tension of the liquid, and the effective contact angle between the liquid and the solid. In this paper, we extend previous large-scale molecular dynamics simulations to show how this tool can be used to study the details of liquid imbibition, including the impact of the contact angle on the dynamics of penetration and the evolution of the internal flow field. In particular, we show that the asymptotic behavior of the contact angle versus time for a completely wetting liquid is given by approximately t(-1/4).     

Liquid-liquid extraction of cadmium(II) from aqueous thiocyanate solutions with liquid anion-exchangers

An investigation has been made on the system liquid anion-exchanger-Cd(II)-NCS⁻. The influence of the acidity and thiocyanate concentration of the aqueous phase on the extraction has been studied. Using various methods of analysis, it has been shown that the complex anion present in the organic extracts is Cd(NCS) ₄ ²⁻ . Details are given concerning the removal of traces of Zn(II) from Cd(II)-containing solutions, and the quantitative separation of Cd(II) from Cr(III).     

An application of factorial design to the development of fused silica capillary columns

Stationary phase crosslinking conditions for fused silica capillary columns were optimized with the use of a factorial design experiment. This experimental strategy was chosen because it provided for the determination of two-factor interactions. A predictive model was developed for the desired chromatographic performance parameters as a function of the variables of the crosslinking reaction. Confirmatory experiments proved the usefulness of the mathematical model which resulted in the production of capillary columns of superior performance with significant improvements in reproducibility.     

The synthesis of functionalized cis'-bicyclo ¦3.3.0¦octanes

A number of polyfunctionalized cis-bicycio ¦3.3.0¦octanes have been synthesized starting from the tricyclic key intermediate $\text{5}$ which was obtained by the intramolecular cyclopropanation reaction of the diazo keto ester $\text{4}$. Selected stereocontrolled transformations of $\text{5}$ using nucleophiles and electrophiles have been studied for the preparation of the title compounds.     

The oxidation state of tungsten in NaxWO3 bronzes as determined by X-ray photoelectron spectroscopy

The XPS spectrum of the 4f levels of W in Na_xWO₃ bronzes is explained by assuming the presence of three oxidation states (W⁶⁺, W⁵⁺ and W⁴⁺). Tetravalent tungsten is formed by dismutation of W⁵⁺. The partial reduction of W⁶⁺ and W⁵⁺. during the recording of XPS spectra is briefly considered.     

NMR experiments on acetals—XXXVII: NMR spectral study of cis-, and trans-6-methyl-4-r-1,3-oxaselenans

The NMR spectral parameters are reported for cis-, and trans-6-Me-4-alkyl-1,3-oxaselenans with the aid of the INDOR- technique. Low temperature studies show the conformational equilibrium in the trans series to be pronouncedly one-sided and a value for the inversion barrier has been obtained.     

The key elements of traceability in chemical measurement: agreed or still under debate?

Talking about "traceability" means talking about a "property of the result of a measurement", about "the value of a standard", about "stated references" and about an "unbroken chain of comparisons". It describes by which comparison, and to which other value, the result of a measurement has been obtained, i.e. is "traceable to". It is about the underlying structure of the measurement process of the result of a measurement and therefore about the authority of the result. Since values carried by (certified) reference materials have also been obtained by measurement, the definition of traceability equally applies. Traceability in the context of reference materials is also about the authority of the values carried by the (certified) reference materials and is, therefore, of key importance for the authority of the reference materials themselves. Hence, values of results of measurements constitute part of the traceability chain and their uncertainties are an intrinsic accompanying phenomenon. Uncertainties need a traceability chain against which they can be evaluated, and a traceability chain is an a priori requirement for evaluating the uncertainty budget of a measurement result. An attempt has been made to exemplify "traceability" chains in some types of chemical measurement and to identify the degree of international agreement on the key elements of "traceability". It is concluded that there is less than universal agreement on this issue. The debate should continue in order to arrive at the international understanding and agreement needed, as "traceability" is now being incorporated in the International Organization for Standardization (ISO), the International Laboratory Accreditation Co-operation (ILAC) and in other "guiding" or regulatory documents. It is also the reason why the Institute for Reference Materials and Measurements (IRMM) has taken up the study of the concept in its core programme on Metrology in Chemistry, and why it sponsored the Workshop in Bratislava.     

Natural radionuclide-free phosphoric acid production

High-uranium phosphate rock from Itataia, Brazil, was milled for wet-process phosphoric acid production using the dihydrate method. Uranium contained in the phosphoric acid was recovered by solvent extraction. The distribution of long-lived natural radionuclides of the ²³⁸U and ²³²Th decay series involved in these operations was evaluated. ²²⁶Ra, ²²⁸Ra and ²¹⁰Pb were found to predominate in the phosphogypsum, while ²²⁸Th, ²³⁰Th and ²³²Th in the uranium-free phosphoric acid. Thorium is removed from the phosphoric acid by solvent extraction to produce a NORM-free phosphoric acid.     

Elemental concentration in the cortex and hippocampus of Wistar rats by X-ray total reflection fluorescence with synchrotron radiation

Summary The study of trace element levels is of great importance due to their relevance in agingand several neurodegenerative diseases. This work compares the elemental concentrations in different postnatal ages and between the temporal cortex, entorhinal cortex and hippocampus from Wistar rats, using X-ray total reflection fluorescence with synchrotron radiation. Ten elements were determined in brain samples: Ti, Cr, Mn, Fe, Cu, Zn, (at trace level) and P, S, Cl and K (at major levels). The elements that increased with aging in cortical areas were: S, K, Fe, Cu and Zn. Ca and Zn levels decreased with advancing age in the hippocampus. In addition to this, Ti, Mn and Fe levels were more conspicuous in the entorhinal cortex.     

Bioaccumulation of vanadium in the epiphytic lichen Parmelia caperata from Liguria (north-west Italy)

The concentration of vanadium was measured in 35 samples of the epiphytic lichen Parmelia caperata collected along the coast of the Ligurian Sea (Italy), in order to detect the possible bioaccumulation of vanadium due to a huge crude oil burning occurred in that area in 1991. The cartographic elaboration of data shows a pattern of distribution of vanadium concentrations according to different degrees of deviation from background condition, showing that 8 years later memory of the accident is still detectable in foliose lichen thalli.