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141.
A new method for the analysis of volatile analytes using a stopped-flow injection system originating from either a gas or liquid phase has been developed. It uses an integrated fiber optic detector which also serves as a reactor. This system combines the advantages of gas diffusion and stopped-flow, making the overall assay very sensitive. Both gas streams and aqueous solutions containing ammonia were analyzed. The limits of detection are 40 ppb for gas phase analysis and 1.0 ppm for aqueous phase analysis. 相似文献
142.
Ergodicity of a Class of Cocycles Over Irrational Rotations 总被引:1,自引:0,他引:1
It is proved that if is irrational and L2(S1) with o(l/n)then for each mZ\{0} the corresponding skew product
is ergodic. The rigidity of specialflows over irrational rotations with roof functions whose Fouriercoefficients are in o(l/n) is also shown. 相似文献
143.
Christian Sunyach 《Potential Analysis》1994,3(2):171-187
Résumé Dans cet article j'étudie le comportement à l'infini des potentiels des chaînes de Markov sur
d
(d3) proches du mouvement brownien, tout spécialement le cas des marches aléatoires, ainsi que des critères de transience et de récurrence inspirés de la méthode utilisée.
We study the asymptotic behaviour of potentials of Markov chains on d (d3), closed to Brownian motion, and particularly the case of random walks. Following a similar approach, we give transience and recurrence criteria.相似文献
144.
145.
146.
Christian Remling 《Proceedings of the American Mathematical Society》1996,124(7):2097-2100
In 1949, Hartman and Wintner showed that if the eigenvalue equations of a one-dimensional Schrödinger operator possess square integrable solutions, then the essential spectrum is nowhere dense. Furthermore, they conjectured that this statement could be improved and that under this condition the essential spectrum might always be void. This is shown to be false. It is proved that, on the contrary, every closed, nowhere dense set does occur as the essential spectrum of Schrödinger operators which satisfy the condition of existence of -solutions. The proof of this theorem is based on inverse spectral theory.
147.
148.
We study the derivation of a Langevin equation from a microscopic basis in order to elucidate the nature of the random force. We arrive at the conclusion that the consistent interpretation of the microscopic Langevin equation in terms of a stochastic differential equation (SDE) is according to I
o rules. In addition, the random force is in general not Gaussian, and it is hence not completely characterized by its second moments. 相似文献
149.
M. Niaz Khan Jean-Pierre Fleury Philippe Baumlin Christian Hubschwerlen 《Tetrahedron》1985,41(22):5341-5345
Amides or vinylogous amides react with tosyl chloride-pyridine to form activated intermediates which condense with Fischer's base or their vinylogs to give carbocyanine structures. Under the same conditions formylated Fischer's base reacts with vinylogous Fischer's bases to give trinuclear carbocyanines in good yields. Their structure and the limitations of this route are discussed. 相似文献
150.
Limberg C 《Angewandte Chemie (International ed. in English)》2003,42(48):5932-5954
The oxo-functionalization of organic substrates with the aid of metal oxo moieties is of fundamental importance not only in nature but also in academic and industrial research. Nevertheless the corresponding reaction mechanisms remain among the most enigmatic in chemistry and few of them are understood in detail. Recent research efforts have resulted in significantly improved information: in the cases of many oxygenation reactions evidence has been provided for the occurrence radical intermediates, even though the high selectivity observed suggests to a different mechanism. Examples stem from various areas of chemistry and include processes involving molecular metal oxo complexes, gas-phase and matrix-isolated species, metalloenzymes, and solid-state oxide surfaces. This review treats this seemingly wide variety of systems with the aim of providing an overview of common reactivity patterns and principles, as well as open problems. 相似文献