YP1xVxO4∶Eu3+在真空紫外区发光的优化

系统地考查了Eu3 + 在YPO4 YVO4 固溶体中的发光。当V5+ 的浓度低于 0 3 ,出现VO4 3 -离子团的蓝色发射 ;直到V5+ 的浓度等于或大于 0 3时 ,VO4 3 -离子团的蓝色发射才被Eu3 + 离子的红色发射所猝灭 ,发射主波长在 61 9nm。在真空紫外线的激发下 ,Eu3 + 在YPO4 YVO4 固溶体有较强发光 ,并随着P5+ 浓度的增加 ,Eu3 + 离子的发光增强。经过优化的组成为YP0 7V0 3 O4 ∶Eu3 + 的荧光粉在真空紫外激发下既具有较强的发光 ,又具有优良的色纯度 ,将是一种新型的良好的等离子体平板显示用荧光粉。     

利用加权对称估计量对季节性时间序列的单位根检验

本文提出对季节性时间序列利用加权对称估计量的单位根检验,导出相应统计量的极限分布。用MonteCarlo方法计算经验百分位数及检验势,并对最小平方估计量,简单对称估计量和加权对称估计量的经验检验势作了比较。     

3-Variable Additive {\rho} -Functional Inequalities and Equations

In this paper, we introduce and investigate additive \({\rho}\) -functional inequalities associated with the following additive functional equations $$\begin{array}{lll} \,\,\,\,\,\,\, f(x+y+z) - f(x)-f(y)-f(z) \,\,\,\, = 0 \\ 2f \left(\frac{x+y}{2}+z \right) - f(x)-f(y)-2f(z) = 0 \\ \,\,2f \left(\frac{x+y+z}{2} \right) - f(x)-f(y)-f(z) = 0\end{array}$$ Furthermore, we prove the Hyers–Ulam stability of the additive \({\rho}\) -functional inequalities in complex Banach spaces and prove the Hyers–Ulam stability of additive \({\rho}\) -functional equations associated with the additive \({\rho}\) -functional inequalities in complex Banach spaces.     

表面含磺酸基的介孔分子筛催化剂SBA-15-SO3H的制备及其催化性能

采用直接和后合成两种方法制备出含磺酸基的介孔分子筛SBA-15-SO₃H,用XRD和红外光谱分析制备过程中催化剂结构和组成的变化.结果表明,两种方法制备出的含磺酸基的催化剂都保持了SBA-15分子筛的完整晶体结构,并含有质子酸中心-SO₃H;固体核磁共振表征结果证明,两种方法都使MPTMS存在于分子筛的表面;用N₂吸附-脱附测定了它们的比表面积、孔径和孔容;TGA分析认为,MPTMS在分子筛表面的热稳定性大于300℃,酸碱滴定结果说明,直接法获得的催化剂的酸中心多于后合成法.酯化反应结果表明,直接法合成的催化剂比后合成法具有更高的稳定性,且简便、快捷、高效.     

Reconstruction of Rabbit Corneal Layer Composed of Corneal Fibroblasts and Corneal Epithelium on the Lyophilized Amniotic Membrane

Introduction Thehumancornea,animportantopticalcompo nentthatfocusesthelightontheiris,isatransparent avasculartissuethatalsoplaysaprotectiveroleforthe eye.Therefore,anyinjury,diseaseorcelldamagethat canleadtoopacificationofthecornea,canimpairthe vision,and…     

On the stability of <Emphasis Type="Italic">θ</Emphasis>-derivations on <Emphasis Type="Italic">JB</Emphasis>*-triples

We introduce the concept of θ-derivations on JB*-triples and prove the Hyers–Ulam-Rassias stability of θ-derivations on JB*-triples. We deal with the Hyers-Ulam-Rassias stability that was first introduced by Th. M. Rassias in the paper “On the stability of the linear mapping in Banach spaces, Proc. Amer. Math. Soc. 72 (1978), 297–300”. The first author was supported by Korea Research Foundation Grant KRF-2005-070-C00009.     

TiO2改性的镁基中温吸附剂及其CO2吸附性能的研究

采用沉淀法合成一系列TiO₂改性的镁基吸附剂,利用XRD、SEM和氮气吸附等方法对吸附剂进行表征,通过变温吸附-脱附动态循环实验考察其CO₂吸附性能。随着TiO₂含量的增加,样品的结晶度逐渐下降,同时由于焙烧后生成钛酸镁,样品比表面积逐渐减小。当TiO₂添加量为2%(质量分数),此时吸附剂呈直径为4.0~5.0μm的球形,局部为纳米片状结构,该吸附剂自第二次循环开始吸附能力无明显变化;经过50次变温吸附脱附循环实验后,动态吸附容量可达6.64%(质量分数),这是由于TiO₂改性后生成的钛酸镁为该吸附剂提供了刚性骨架,促进了活性组分的分散,并提高了吸附剂的稳定性。     

ZSM-5沸石结晶度对乙苯叔丁基化对位选择性的影响(英文)

Highly crystalline ZSM-5 zeolites are important for para-selective alkylation of alkyl aromatics, because they carry few external acid sites for isomerization of p-dialkyl products. Such zeolites (Si/Al = 25, 50, and 75) were synthesized in a fluoride medium between pH 4 and 6. Their crystallinities, crystal sizes, and surface areas were higher than those of a commercial ZSM-5 zeolite. Their para selectivities in alkylation were tested for vapor-phase tert-butylation of ethylbenzene between 200 and 400 °C. As expected, all the catalysts showed more than 90% para selectivity. At 300 °C, ethylbenzene conversion decreased in the order ZSM-5(25, commercial) > ZSM-5(25) > ZSM-5(50) > ZSM-5(75). The catalysts had weak, medium, and strong acid sites, but all the acid sites of ZSM-5(75) were weaker than those of ZSM-5(25) and ZSM-5(50). The high activity of commercial ZSM-5 was caused by its strong acid sites being stronger than those of the synthesized zeolites. Although the activity of the commercial catalyst was higher than those of the present catalysts, the selectivity for 4-t-butylethylbenzene (4-t-BEB) was low. The optimum feed ratio (ethylbenzene:t-butyl alcohol) was 2:1 and the feed rate was 1.65 h?1 for high ethylbenzene conversion and 4-t-BEB selectivity. Time-on-stream studies showed slow catalyst deactivation. Highly crystalline ZSM-5 zeolites are therefore better than a commercial zeolite for para-selective alkylation of alkyl aromatics. They do not require much post-modification for high para selectivity. A fluoride medium is therefore better than an alkaline medium for obtaining highly crystalline para-selective ZSM-5 zeolites.     

保持因子交换性的可加映射

设x和y是代数中的两个元.如果存在某个数ξ,使得xy=ξyx,称x和y关于因子ξ交换.给出了标准算子代数间双边保关于因子交换的可加满射的刻画和分类以及C*-代数间保关于因子交换的有界线性满射的刻画和分类.     

GENERAL DECAY OF A TRANSMISSION PROBLEM FOR KIRCHHOFF TYPE WAVE EQUATIONS WITH BOUNDARY MEMORY CONDITION

In this paper, we investigate the influence of boundary dissipation on the de-cay property of solutions for a transmission problem of Kirchhoff type wave equation with boundary memory condition. By introducing suitable energy and Lyapunov functionals, we establish a general decay estimate for the energy, which depends on the behavior of relaxation function.