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991.
DAI Jian-ying ZHANG Li-fu XIU Zhi-long School of Life Science Biotechnology Dalian University of Technology Dalian P. R. China 《高等学校化学研究》2011,(2):273-276
S-Ribosylhomocysteinase(LuxS) is the key enzyme in the synthetic pathway of a quorum sensing autoinducer AI-2. LuxS from a 2,3-butanediol produced strain Klebisella pneumoniae CICC 10011 was cloned and characterized. The luxS gene is composed of 540 bp with 172 amino acids encoded. The Km value for S-ribosylhomo- cysteine(SRH) was (27±1) umol/L, kcat was (0.112±0.004) s-1 and kcat/Km was 4.4×103 L umol-1·s-1 at 25 ℃. LuxS was activated by divalent metal ions, the highest activity was detected with Co2+ form... 相似文献
992.
LI Dang-guo WANG Jia-dao CHEN Da-rong State Key Laboratory of Tribology School of Mechanical Enginering Tsinghua University Beijing P. R. China 《高等学校化学研究》2011,(2)
The electronic properties of passive films formed on G3 and G30 alloys in bicarbonate/carbonate buffer solution were comparatively studied by electrochemical impedance spectra(EIS) and Mott-Schottky analysis, the chemical composition of the passive film formed on G3 alloy was detected by X-ray photoelectron spectroscopy (XPS). The results show that passive film on G3 alloy had better protection than that on G30 alloy. The transfer resistance, film resistance and diffusion resistance of the passive films on ... 相似文献
993.
GUO Jin-shan LI Jian-zheng JING Xia-bin CHEN Xue-si HUANG Yu-bin . State Key Laboratory of Polymer Physics Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun P. R. China . Graduate School of Chinese Academy of Sciences Beijing 《高等学校化学研究》2011,(2):329-333
A new kind of biodegradable pH-sensitive drug delivery system was developed via chitosan-albumin conjugate hydrogel. Through changing the feeding modes of reactants, two types of hydrogels(comb-type and reticular-type) were synthesized by amidation reactions between 6-O-succinoylated N-phthaloyl chitosan and albumin. The structures and morphologies of the hydrogels were characterized by SEM. And their water swelling capacity, drug loading and releasing properties at different pH values were also investigate... 相似文献
994.
HAN Tian-jiao WANG Qing SONG Feng-rui LIU Zhong-ying LIU Zhi-qiang LIU Shu-ying . Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Center of Mass Spectrometry Changchun P. R. China 《高等学校化学研究》2011,(3):380-384
In vitro models of human colon carcinoma cell line(Caco-2 cell monolayer) and human intestinal bacteria were used to investigate the intestinal transport and biotransformation of resibufogenin and cinobufagin in Chan Su by HPLC/APCI-MSn. The experimental results of Caco-2 cell monolayer demonstrate that the apparent permeability coefficients(Papp) of resibufogenin and cinobufagin are higher than 10-6 cm/s, which indicates that both resibufogenin and cinobufagin have a good absorption in the small intestine.... 相似文献
995.
HAO YingHang GONG YuBing LIN Xiu & WANG Li School of Physics Ludong University Yantai China 《中国科学B辑(英文版)》2011,(5)
The spiking behavior with varying time delay in scale-free networks of Hodgkin-Huxley neurons with non-Gaussian noise has been studied,and the effect of non-Gaussian noise on the delay-induced spiking behavior is discussed. It was found that multiple spatio-temporal resonances occur when the delay lengths are integer multiples of the spiking periods,and the resonances may be strengthened when the non-Gaussian noise is appropriate. This result shows that time delays can optimize the spiking temporal regulari... 相似文献
996.
SUN ChuanFu YANG BingPing & MAO JiangGao State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou China 《中国科学B辑(英文版)》2011,(6)
Metal iodates with a lone-pair containing I(V) that is in an asymmetric coordination geometry can form a diversity of unusual structures and many of them are promising new second homonic generation (SHG) materials. They exhibit wide transparency wavelength regions, large SHG coefficients and high optical-damage thresholds as well as moderately high thermal stability. In this paper, the structures and properties of the metal iodates are reviewed. The combination of d0 transition-metal cations with the iodate... 相似文献
997.
CUI Tao TANG ShunLin ZHANG Lei & YU DaRen School of Energy Science Engineering Harbin Institute of Technology Harbin China Pharmaceutical College Heilongjiang University of Chinese Medicine Institution Harbin China 《中国科学B辑(英文版)》2011,(7)
Catalytic CO oxidation on platinum group metals exhibits nonlinear phenomena such as hysteresis and bifurcation.Elucidation of the nonlinear mechanisms is important for catalyst design and control of reaction routes.Previous studies have offered initial insights into the local bifurcation behavior of CO oxidation.However,since the bifurcation behavior of CO oxidation is determined by multiple parameters such as temperature,total flux,and CO fraction,it is difficult to predict the global bifurcation behavior... 相似文献
998.
WANG Wei & ZHU Jun-Jie State Key Laboratory of Analytical Chemistry for Life Science School of Chemistry Chemical Engineering Nanjing University Nanjing China 《中国科学B辑(英文版)》2011,(8)
This review presents a simple introduction on the unique properties and general synthesis of quantum dots (QDs) in which we lay emphasis on the optical applications in the biological system. The detection of biological molecules such as DNA, protein and enzyme, the cell-based analysis and in vivo animal imaging are mainly discussed. 相似文献
999.
LI YouJi CHEN Wei LI LeiYong & MA MingYuan College of Chemistry Chemical Engineering Jishou University Jishou China 《中国科学B辑(英文版)》2011,(3)
TiO2-coated carbon felt(TCF)composite catalysts have been prepared via a supercritical treatment of titanium tetraisopropoxide(TTIP)as the precursor.The physical properties of the catalysts were characterized by means of thermogravimetric and differential thermal analysis(TG–DTA),X-ray diffraction(XRD),fluorescence spectroscopy,scanning electron microscopy (SEM),and BET surface areas techniques.The photocatalytic activities of the materials were evaluated using the degradation of Congo red(CR)as a probe rea... 相似文献
1000.
ASIF Anila 《中国科学B辑(英文版)》2011,(9)
A novel hyperbranched poly(urethane-tetrazole)(HPUTZ) was synthesized via the A2+BB2' approach using hexadiisocyanate(HDI) and 3-(bis-(2-hydroxyethyl)) aminopropyltetrazole(HAPTZ).The molecular structure was characterized by FTIR and 1H NMR spectroscopy.The number average molecular weight was measured to be 1.05×104 g/mol with a polydispersity of 1.27 by GPC analysis.The HPUTZ was further cured by the semi-adduct(PEG-IPDI) from polyethylene glycol(PEG) reacting with isophorone diisocyanate(IPDI) to form th... 相似文献