Spectroscopic Properties and Electronic Structure of Bis(L—Histidine)Copper(II) Dinitrate Dihydrate

Electronic absorption spectrum, photoacoustic absorption spectrum and ESR spectrum of bis(L-histidine)copper(II) dinitrate dihydrate crystal were recorded. The experimental results are discussed quantitatively with ligand field theory (LFT) and the radial wave function of non-free copper(II). Our calculations coincides well with the experimental results, and in particular, provides significant correlations between the spectra and coordination structures. The ESR spectrum gives some information about the restudy of classification for the ESR spectra of bis(amino acidato)copper(II) complexs. Additionally, the differences between crystal and frozen solution spectra due to the variance of PH are also reported for the title compound.     

Comparison of shear banding in BMGs due to thermal-softening and free volume creation

This paper reports a comparative study of shear banding in BMGs resulting from thermal softening and free volume creation. Firstly, the effects of thermal softening and free volume creation on shear instability are discussed. It is known that thermal softening governs thermal shear banding, hence it is essentially energy related. However, compound free volume creation is the key factor to the other instability, though void-induced softening seems to be the counterpart of thermal softening. So, the driving force for shear instability owing to free volume creation is very different from the thermally assisted one. In particular, long wave perturbations are always unstable owing to compound free volume creation. Therefore, the shear instability resulting from coupled compound free volume creation and thermal softening may start more like that due to free volume creation. Also, the compound free volume creation implies a specific and intrinsic characteristic growth time of shear instability. Finally, the mature shear band width is governed by the corresponding diffusions (thermal or void diffusion) within the band. As a rough guide, the dimensionless numbers: Thermal softening related number B, Deborah number (denoting the relation of instability growth rate owing to compound free volume and loading time) and Lewis number (denoting the competition of different diffusions) show us their relative importance of thermal softening and free volume creation in shear banding. All these results are of particular significance in understanding the mechanism of shear banding in bulk metallic glasses (BMGs). Supported by the Chinese Academy of Sciences under the project “Multi-Scale Complex System” (Grant No. KJCX-SW-L08), the National Natural Science Foundation of China (Grant Nos. 10725211 and 10721202), and the Doctorial Start-up Fund of Hunan University of Science and Technology (Grant No. E50840)     

铁、铬、钒原子激发态的光电离截面

这篇文章分别在278～288nm、335～361nm、300～310nm激光波长范围内分别报道过渡金属中的铁原子、铬原子和钒原子的共振增强多光子电离(REMPI)的实验结果.实验中采用激光烧蚀和分子束相结合的技术制备金属原子.光离子产物由飞行时间质谱仪检测.根据共振电离离子信号对探测激光功率的依赖关系,得到原子激发态的光电离截面值.     

Ultrafast photo-induced turning of magnetization and its relaxation dynamics in GaMnAs

We report that,by linearly polarized pumping of different wavelengths,Kerr transients appear at zero magnetic field only in the case when GaMnAs samples are initialized at 3 K by first applying a 0.8 Tesla field and then returning to zero field.We find that,instead of magnetization precession,the near-band gap excitation induces a coherent out-of-plane turning of magnetization,which shows very long relaxation dynamics with no precession.When photon energy increases,the peak value of the Kerr transient incre...     

不同叶轮形式下离心泵噪声特性对比研究

针对具有无短叶片和有短叶片两种叶轮形式的离心泵,对设计状态下离心泵内部流场进行了全三维、非定常数值模拟,对比分析了其非定常流场特性和噪声辐射特性。流场分析表明:叶轮叶片和蜗舌的相互作用造成了叶片表面强烈的压力脉动,对长短叶片的叶轮形式,在局部增加长叶片表面压力脉动的同时,短叶片表面的压力脉动保持较低水平;同时能够有效降低泵体进口压力脉动,但出口压力脉动有所增强。以叶轮叶片表面作为声源辐射面,对比分析了两种叶轮的偶极子噪声辐射特性,结果表明:长短叶片结构通过改变声能在频域上的分布,从而能有效降低总声压级。     

Novel Microstrip Photonic Bandgap Cell Structures

In general, a planar microstrip photonic bandgap (PBG) structure os a periodic array of holes etched in the ground plane of a microstrip line. To use a circuit with a PBG, the PBG structure cannot be fixed on a metal base and needs to be shielded. In this paper, two kinds of novel microstrip PBG unit cells with special patterns etched in the strip line, which can be used as the conventional microstrip circuits, are proposed and analyzed in detail. The results show that the transmission line theory is valid for the theoretic analysis of PBG circuits.     

大振幅驻波的实验研究Ⅲ：三次谐波的共振

在基波声压级（L_p1）为定值（148dB）的条件下,三次谐波变化曲线可用一\     

Modulation instability in metamaterials with fourth-order linear dispersion,second-order nonlinear dispersion,and three kinds of saturable nonlinearites

The linearized nonlinear propagation equation and its coefficients, gain spectrum of modulation instability (MI) in metamaterials (MMs) with fourth-order linear dispersion, second-order nonlinear dispersion, and three kinds of saturable nonlinearites, are analytically deduced by utilizing the linear stability analysis and Drude electromagnetic model. Then variations of gain spectra of MI with the normalized angular frequencies and the optical power densities are calculated in real units. In the negative refractive region, two kinds of gain spectra are discovered. The first (second) one is close to (far from) the zero perturbation frequencies and it corresponds to the lower (higher) normalized angular frequencies. Moreover, the second one has higher cutoff frequency, which is obviously beneficial to generation of high-repetition-rate pulse trains. While in the positive refractive region, only the first kind of gain spectra is found. With increase of the optical power densities, the peak gains and the spectral widths of MI increase before decrease, but they vary the most rapidly (slowly) for the exponential (conventional) saturable nonlinearities. The MI characteristics and their corresponding applications can be adjusted by several methods.     

Wavelet threshold method of resolving noise interference in periodic short-impulse signals chaotic detection

The chaotic oscillator has already been considered as a powerful method to detect weak signals, even weak signals accompanied with noises. However, many examples, analyses and simulations indicate that chaotic oscillator detection system cannot guarantee the immunity to noises (even white noise). In fact the randomness of noises has a serious or even a destructive effect on the detection results in many cases. To solve this problem, we present a new detecting method based on wavelet threshold processing that can detect the chaotic weak signal accompanied with noise. All theoretical analyses and simulation experiments indicate that the new method reduces the noise interferences to detection significantly, thereby making the corresponding chaotic oscillator that detects the weak signals accompanied with noises more stable and reliable.     

Amphoteric refraction exhibited by anisotropic crystals

Amphoteric refraction of light ray at the interface between isotropic materials and anisotropic materials is analyzed. Depending on the incident angle, the refractive light ray can either refract positively or negatively. This amphoteric refraction phenomenon can be quite prevalent when the difference of the two principal refractive indices is large. The reflectance under various incident angles has also been calculated, and an experimental demonstration with a calcite crystal in air is presented.