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191.
Jiajia Ru Ting He Binjie Chen Yutong Feng Lianhai Zu Zhijun Wang Qiaobao Zhang Tianzi Hao Ruijin Meng Renchao Che Chi Zhang Jinhu Yang 《Angewandte Chemie (International ed. in English)》2020,59(34):14621-14627
Weak van der Waals interactions between interlayers of two‐dimensional layered materials result in disabled across‐interlayer electron transfer and poor layered structural stability, seriously deteriorating their performance in energy applications. Herein, we propose a novel covalent assembly strategy for MoS2 nanosheets to realize unique MoS2/SnS hollow superassemblies (HSs) by using SnS nanodots as covalent linkages. The covalent assembly based on all‐inorganic and carbon‐free concept enables effective across‐interlayer electron transfer, facilitated ion diffusion kinetics, and outstanding mechanical stability, which are evidenced by experimental characterization, DFT calculations, and mechanical simulations. Consequently, the MoS2/SnS HSs exhibit superb rate performance and long cycling stability in lithium‐ion batteries, representing the best comprehensive performance in carbon‐free MoS2‐based anodes to date. Moreover, the MoS2/SnS HSs also show excellent sodium storage performance in sodium‐ion batteries. 相似文献
192.
Hongyun Ma Hongwu Chen Mingmao Wu Fengyao Chi Feng Liu Jiaxin Bai Huhu Cheng Chun Li Liangti Qu 《Angewandte Chemie (International ed. in English)》2020,59(34):14541-14549
Capacitive energy storage has advantages of high power density, long lifespan, and good safety, but is restricted by low energy density. Inspired by the charge storage mechanism of batteries, a spatial charge density (SCD) maximization strategy is developed to compensate this shortage by densely and neatly packing ionic charges in capacitive materials. A record high SCD (ca. 550 C cm?3) was achieved by balancing the valance and size of charge‐carrier ions and matching the ion sizes with the pore structure of electrode materials, nearly five times higher than those of conventional ones (ca. 120 C cm?3). The maximization of SCD was confirmed by Monte Carlo calculations, molecular dynamics simulations, and in situ electrochemical Raman spectroscopy. A full‐cell supercapacitor was further constructed; it delivers an ultrahigh energy density of 165 Wh L?1 at a power density of 150 WL?1 and retains 120 Wh L?1 even at 36 kW L?1, opening a pathway towards high‐energy‐density capacitive energy storage. 相似文献
193.
Kai Wu Liang‐Liang Wu Cong‐Ying Zhou Chi‐Ming Che 《Angewandte Chemie (International ed. in English)》2020,59(37):16202-16208
A transition‐metal‐free C(sp2)?C(sp2) bond formation reaction by the cross‐coupling of diazo quinones with catechol boronic esters was developed. With this protocol, a variety of biaryls and alkenyl phenols were obtained in good to high yields under mild conditions. The reaction tolerates various functionalities and is applicable to the derivatization of pharmaceuticals and natural products. The synthetic utility of the method was demonstrated by the short synthesis of multi‐substituted triphenylenes and three bioactive natural products, honokiol, moracin M, and stemofuran A. Mechanistic studies and density functional theory (DFT) calculations revealed that the reaction involves attack of the boronic ester by a singlet quinone carbene followed by a 1,2‐rearrangement through a stepwise mechanism. 相似文献
194.
Chi‐Cheung Su Meinan He Jiayan Shi Rachid Amine Jian Zhang Khalil Amine 《Angewandte Chemie (International ed. in English)》2020,59(41):18229-18233
Despite the exceptionally high energy density of lithium metal anodes, the practical application of lithium‐metal batteries (LMBs) is still impeded by the instability of the interphase between the lithium metal and the electrolyte. To formulate a functional electrolyte system that can stabilize the lithium‐metal anode, the solvation behavior of the solvent molecules must be understood because the electrochemical properties of a solvent can be heavily influenced by its solvation status. We unambiguously demonstrated the solvation rule for the solid‐electrolyte interphase (SEI) enabler in an electrolyte system. In this study, fluoroethylene carbonate was used as the SEI enabler due to its ability to form a robust SEI on the lithium metal surface, allowing relatively stable LMB cycling. The results revealed that the solvation number of fluoroethylene carbonate must be ≥1 to ensure the formation of a stable SEI in which the sacrificial reduction of the SEI enabler subsequently leads to the stable cycling of LMBs. 相似文献
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197.
GaAs与InP半导体光导开关特性实验研究 总被引:1,自引:0,他引:1
利用Ⅲ-Ⅴ族化合物半导体材料砷化镓(GaAs)和磷化铟(InP)及其掺杂材料制作的光导开关具有很好的时间响应及高功率输出特性.比较了这两种材料制作的不同电极间隙类型的光导开关的开关时间响应速度、导通光能与饱和触发激光能量、线性与非线性工作模式及触发稳定性等特性.结果表明,利用InP和GaAs两种材料制作的光导开关都具有达到皮秒级的超快时间响应,其对时间最佳响应与偏置电场有关.两种开关的多次触发时间抖动在几个皮秒范围,输出电压峰峰值抖动优于10%.GaAs开关的非线性工作电场阈值比InP开关低,更容易实现非线性输出. 相似文献
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199.
单极型马赫-曾德尔调制器的互调失真分析 总被引:7,自引:2,他引:5
针对单极型马赫曾德尔电光调制器在Radio over Fiber(RoF)和副载波复用系统中的应用,讨论了输入两路射频信号的情形,给出了电光调制器互调失真的严格通用解析解。该解析解可用于表示任意阶的互调失真项和谐波项。数值结果表明了该解析解的正确性。分析结果表明,调制器的三阶互调失真与调制器偏置相移无关,只与输入射频信号的调制系数有关,并且当外加偏置电压等于调制器的半波电压时,只存在偶数阶的失真项。根据该解析解,可方便地设计模拟光通信系统,精确地预计外调制器的非线性特征,优化系统性能。 相似文献
200.
How to choose an optimal threshold is a key problemin the generalized Pareto distribution (GPD) model.This paper attains the exactthreshold by testing for GPD,and shows that GPD model allows the actuary to easily estimate high quantiles and the probable maximum loss from the medical insurance claims data. 相似文献