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151.
Klauss H.-H. Baabe D. Mienert D. Birke M. Luetkens H. Litterst F. J. Hücker M. Büchner B. Cheong S. W. 《Hyperfine Interactions》2001,136(3-8):711-715
We report zero field μSR experiments on the lanthanum nickelate La2−x
Sr
x
NiO4+δ system with strontium doping level x between 0 and 0.6. In a single crystal with x=0.33 the internal field distribution shows two separated signals reflecting the antiferromagnetic domains and the non magnetic
antiphase domain walls in the spin and charge ordered state below 190 K. Below 70 K a broadening of the low field line is
observed. A similar behavior is observed in polycrystalline samples with 0.2≤x≤0.5.
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献
152.
153.
Shengjie Wei Yu Wang Wenxing Chen Zhi Li Weng-Chon Cheong Qinghua Zhang Yue Gong Lin Gu Chen Chen Dingsheng Wang Qing Peng Yadong Li 《Chemical science》2020,11(3):786
Non-noble metal isolated single atom site (ISAS) catalysts have attracted much attention due to their low cost, ultimate atom efficiency and outstanding catalytic performance. Herein, atomically dispersed Fe atoms are prepared by a covalent organic framework (COF)-absorption–pyrolysis strategy. The obtained Fe ISASs anchored on COF-derived N-doped carbon nanospheres (Fe-ISAS/CN) served as a multi-functional catalyst in electro-catalysis and organic catalysis, exhibiting better catalytic performance than commercial Pt/C for the ORR with good stability and methanol tolerance. Besides electro-catalysis, the Fe-ISAS/CN also showed outstanding catalytic performance in organic reactions, such as the selective oxidation of ethylbenzene to acetophenone and dehydrogenation of 1,2,3,4-tetrahydroquinoline with excellent reactivity, selectivity, stability and recyclability. Co and Ni ISAS materials can also be prepared by this method, suggesting that it is a general strategy to obtain metal ISAS catalysts. This work will provide new insight into the design of COF-derived metal ISAS multi-functional catalysts for electro-catalysis and organic reactions using rationally designed synthetic routes and the optimized structure of substrates.Fe isolated single-atom sites anchored on COF-derived N-doped carbon nanospheres as efficient multi-functional catalysts. 相似文献
154.
155.
Every inverse semigroup possesses a natural partial order and therefore convexity with respect to this order is of interest.
We study the extent to which an inverse semigroup is determined by its lattice of convex inverse subsemigroups; that is, if
the lattices of two inverse semigroups are isomorphic, how are the semigroups related? We solve this problem completely for
semilattices and for inverse semigroups in general reduce it to the case where the lattice isomorphism induces an isomorphism
between the semilattices of idempotents of the semigroups. For many inverse semigroups, such as the monogenic ones, this case
is the only one that can occur. In Part II, a study of the reduced case enables us to prove that many inverse semigroups,
such as the free ones, are strictly determined by their lattices of convex inverse subsemigroups, and to show that the answer
obtained here for semilattices can be extended to a broad class of inverse semigroups, including all finite, aperiodic ones.
Received September 24, 2002; accepted in final form December 15, 2002. 相似文献
156.
Siu-Wing Cheng Otfried Cheong Hazel Everett René van Oostrum 《Discrete and Computational Geometry》2004,32(3):401-415
A hierarchical decomposition of a simple polygon is introduced. The
hierarchy has logarithmic depth, linear size, and its regions have
at most three neighbors. Using this hierarchy, circular ray
shooting queries in a simple polygon on n vertices
can be answered in O(log2
n) query time and O(n log n) space. If the radius of the circle
is fixed, the query time can be improved to O(log n) and the
space to O(n). 相似文献
157.
Summary In climate dynamics the effect of internally generated fluctuations is usually described by augmenting the balance equations
through the addition ofrandom forces. In this paper the properties of these forces are investigated. Afluctuation-dissipation theorem relating their covariance matrix to the phenomenological coefficients such as eddy diffusivity is proposed. The theorem is
subsequently used to identify the statistical properties of the climatic variables themselves, and thus to characterize climatic
variability from the standpoint of the statistical theory of irreversible processes. Applications to a simple thermal convection
problem and to a zonally averaged energy-balance model are presented; the possibility of experimental verification is discussed.
Traduzione a cura della Redazione. 相似文献
Riassunto Nella dinamica del clima si descrive solitamente l'effetto delle fluttuazioni generate internamente aumentando le equazioni del bilancio con l'aggiunta di forze casuali. In questo lavoro si studiano le proprietà di queste forze. Si propone un teorema di fluttuazione-dissipazione che correla la matrice di covarianza ai coefficienti fenomenologici come la diffusività turbolenta. Il teorema è usato successivamente per identificare le proprietà statistiche delle variabili climatiche stesse e per caratterizzare la variabilità climatica dal punto di vista della teoria statistica dei processi irreversibili. Si presentano applicazioni a un problema semplice di convezione termica e ad un modello di bilancio d'energia mediato a zone; si discute la possibilità di verifica sperimentale.
Traduzione a cura della Redazione. 相似文献
158.
Tetsuo Asano Mark de Berg Otfried Cheong Leonidas J. Guibas Jack Snoeyink Hisao Tamaki 《Discrete and Computational Geometry》2003,30(4):591-606
We consider the problem of finding low-cost spanning trees for sets
of $n$ points in the plane, where the cost of a spanning tree is
defined as the total number of intersections of tree edges with
a given set of $m$ barriers. We obtain the following results:
(i) if the barriers are possibly intersecting line segments,
then there is always a spanning tree of cost
$O(\min(m^2,m\sqrt{n}))$; (ii) if the barriers are disjoint line segments,
then there is always a spanning tree of cost $O(m)$; (iii) ] if the barriers are disjoint
convex objects,
then there is always a spanning tree of cost $O(n+m)$.
All our bounds are worst-case optimal, up to multiplicative constants. 相似文献
159.
Static and dynamic linear analyses of axisymmetric capillary instabilities in textured nematic liquid crystalline fibres are performed using the equations of nemato-statics and inviscid nemato-dynamics. Three representative textures, viz. axial, onion, and radial, are analysed to show all possible effects of Frank gradient elasticity on the wavelength selection and growth rate of peristaltic modes driven by surface area reduction. It is found that Frank elasticity may tend to stabilize or destabilize the fibre, depending on the initial fibre texture. Axial textures tend to stabilize the fibre through the director splay-bend distortions driven by surface tilting. Onion textures are destabilized by decreasing azimuthal bend elastic energy caused by surface displacement. Radial textures exhibit a stabilizing tilt mechanism due to bend modes and a destabilizing displacement mechanism due to splay modes, but the former is predicted to be dominant. The static analysis provides good estimates of the instability thresholds while the transient energy balance provides information on the fastest growing modes. The static and dynamic results are compared and shown to be fully consistent. The couplings between splay and/or bend distortions, surface tilting, and surface displacement in nematic fibres are characterized and used to explain the deviations from the classical Rayleigh instability. 相似文献
160.