基于RBF神经网络的较低浓度下同步荧光光谱的溢油鉴别

针对海面溢油样品的含量难以确定,同时考虑到海水掺杂及风化等问题的影响,提出了在较低非线性浓度范围内采集溢油嫌疑样品的同步荧光光谱,获取其训练样本集,利用主成分分析法(Principal com-ponent analysis,PCA)提取其特征光谱,结合径向基函数(Radial basis function,RBF)神经网络对肇事样本和嫌疑样本进行模式识别的方法。通过对相近油源原油样品分类识别研究表明:该方法仅需单次对肇事样本同步光谱测量,再借助数据分析,就可以很好区分相近油源溢油样品,外扰对识别率影响也不大。RBF神经网络算法识别率在92%左右。该结论对海洋环境中溢油的实时检测及油指纹数据信息库的建立有重要意义。     

嫦娥一号干涉成像光谱仪(IIM)2C级数据信息提取

通过分析Chang’E-1卫星所获取的高光谱数据的太阳高度角因素,选取了太阳高度角较高的IIM2C数据进行光谱定标。采用邻域平均法及邻域加权均值法对原始数据进行了杂点、条带修复。由于干涉成像光谱仪CCD阵列增益畸变以及它的自身问题使得干涉影像存在横向响应不均一性,提出采用基于子空间最大特征值法进行校正,结果影像亮度统计其强度表现均一,符合自然图像特征,并采用自编程序进行几何校正。运用国际上较为成熟的经验线性法对Chang’E-1IIM 2C数据进行绝对定标;与此同时,为了修正线性定标的偏置系数及降低数据噪声,首次采用自适应小波变换法对辐射定标后数据进行后处理,确定了IIM2C数据可用波段。通过对比国际标准定标点数据,制订了嫦娥IIM2C数据分析方案,完成了第一幅完整的Chang’E-1IIM 2C月球正面反射率影像。     

10－5000 伏下电子被多原子分子CF4, CF3H, C2F4, C2F6, 及 C2H3F3散射总结面的计算

利用可加性规则和光学势方法计算了能量在10-5000 eV范围内电子被多原子分子CF4, CF3H, C2F4, C2F6, 及 C2H3F3的总结面，并与已有的实验结果和理论计算进行了比较，与这些结果符合得很好。对于CF4, CF3H, C2F4, C2F6, 及 C2H3F3在1000eV以上没有实验数据，本文对实验研究提供了对比和预测的数据。     

Total cross sections for electrons scattering from simple molecules containing the larger atom sulfur at 30-5000eV

A complex optical model potential modified by the concept of bonded atom, which takes into consideration the overlapping effect of electron clouds, is employed to calculate the total cross sections for electrons scattering from simple molecules （SO2, H2S, OCS, CS2 and SO3） containing the larger atom, sulfur, at 30-5000eV by using the additivity rule model at Hartree-Fock level. The quantitative molecular total cross section results are compared with those obtained in experiments and other calculations wherever available, and good agreement is obtained. It is shown that the additivity rule model together with the complex optical model potential modified by the concept of bonded atom can give the results closer to the experiments than the one unmodified by it. So, the introduction of bonded-atom concept in complex optical model potential betters the accuracy of the total cross section calculations of electrons from the molecules containing the larger atom, sulfur.     

Four-channel coarse WDM for inter- and intra-satellite optical communications

A polymer volume grating-based four-channel coarse wavelength division multiplexer (WDM) for inter- and intra-satellite optical communication application is reported for the first time. This compact four-channel WDM device working at 0.83, 1.06, 1.34 and 1.55 μm is designed to build a complete optical link between two satellites, where wavelengths of 0.83 and 1.55 μm are used for data stream channels, 1.06 and 1.34 μm are used for inter- and intra-satellite connection. It is for the first time reported that a WDM device can cover such a large wavelength range in a single substrate. For transverse electric (TE) wave, the channel efficiencies at 0.83, 1.06, 1.34 and 1.55 μm are 55%, 40%, 35% and 45%, respectively. Channel efficiencies for transverse magnetic (TM) waves are 20% lower than those of TE waves on average. Wavelength shifts due to Doppler effect, temperature variations and radiation effects in space can be adequately accommodated.     

Effects of hydroxyls on the structural and room temperature ferromagnetic properties of Co doped SnO2 nanoparticles

Co doped SnO₂ nanoparticles have been prepared via a wet chemical method with different precipitation processes. The structure and morphology of Co doped SnO₂ nanoparticles demonstrate that the nanoparticles are in a rutile single phase and uniform, respectively. X-ray photoelectron spectroscopy shows that the Co dopants are in 2+ oxidation valence state and doped ∼2 atm% in SnO₂ nanoparticles. Moreover, Raman spectroscopy further confirms that Co doped SnO₂ nanoparticles have single phase crystallinity without forming any extra modes related to secondary phases. The magnetic measurements reveal that all nanoparticles exhibit room temperature ferromagnetism (RTFM) due to the presence of disorders and defects introduced by hydroxyls in the crystal structure. In addition, it has been clearly observed that the saturated magnetic moments are strongly affected by the precipitation processes which control the incorporation of hydroxyls into the lattice.     

牵引变流器网侧电流谐波抑制研究

作为电力机车牵引传动系统核心部件的牵引变流器是牵引供电网的主要谐波来源之一。牵引变流器采用的单相四象限整流器,输出含有二次脉动,且工作开关频率较低,导致变流器网侧电流谐波问题严重。目前单相四象限整流器的控制脉冲产生主要采用SPWM技术。与SPWM相比,SHEPWM（特定谐波消除PWM）可以针对性的消除特定的谐波,谐波含量更小,效率更高,但其无法消除调制波中本身就存在的谐波。针对SHEPWM调制策略进行了分析设计,同时对陷波滤波器技术、PR控制策略和LC回路在降低谐波含量中的作用进行深入分析。经过合理的方案选择,有效的降低了网侧电流谐波含量,并通过MATLAB仿真实验进行了分析验证。     

Removal of oxygen from silicon by electron beam melting

Small amounts of multicrystalline silicon were melted in an electron beam furnace in different experimental conditions in order to investigate the oxygen evaporation behavior during the electron beam melting (EBM) process. The oxygen content level before and after EBM was determined by secondary ion mass spectroscopy. The oxygen content was reduced from 6.177 to 1.629 ppmw when silicon was melted completely at 15 kW with removal efficiency up to 73.6 %. After that, it decreased continually to <0.0517 ppmw when the refining time exceeded 600 s with a removal efficiency of more than 99.08 %. During the melting process, the evaporation rate of silicon is 1.10 × 10^?5 kg/s. The loss of silicon could be reduced up to 1.7 % during oxygen removal process to a desirable figure, indicating EBM is an effective method to remove oxygen from silicon and decrease the loss of silicon.     

High-temperature impedance spectroscopy of BaFe0.5Nb0.5O3 ceramics doped with Bi0.5Na0.5TiO3

Bi_0.5Na_0.5TiO₃ (BNT)-doped BaFe_0.5Nb_0.5O₃ (BFN) ceramics were synthesized by a two-step solid-state reaction. Temperature dependence of dielectric properties measured at different frequencies was investigated over broad temperature and frequency ranges. Impedance spectroscopy and universal dielectric response were employed to study the relaxation behavior and conductivity mechanism of the ceramics in a frequency range from 40 Hz to 100 MHz and a temperature range from 300 K to 800 K. The complex plane impedance data revealed the bulk and grain boundary contributions toward conductivity processes in the form of semicircular arcs. The high-temperature conductivity of ceramics is attributable to thermally activated second ionized oxygen vacancy.     

高辐射效率超宽谱脉冲辐射天线的设计与实验

设计了一种采用共面TEM馈电结构的抛物反射面超宽谱脉冲辐射天线,分析了该种馈电结构的阻抗特性与辐射特性。实验表明当馈入电压为3kV、前沿180ps的超宽谱脉冲时,该天线主轴辐射场测试距离与峰值场强之积平均值达到18.3kV,相较于常用的TEM喇叭馈电的超宽带反射面天线,其辐射效率有了显著的提高。