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71.
Ilia A. Guzei Charmaine Arderne 《Acta Crystallographica. Section C, Structural Chemistry》2015,71(8):695-700
Three polymorphs of bis(nitrito‐κN)[tris(2‐aminoethyl)amine‐κ4N,N′,N′′,N′′′]cobalt(III) chloride, [Co(NO2)2(C6H18N4)]Cl, have been structurally characterized in the 100–300 K temperature range. Two orthorhombic polymorphs are related by a solid‐state enantiotropic order–disorder k2 phase transition at ca 152 K. The third, monoclinic, polymorph crystallizes as a nonmerohedral twin. In the structure of the high‐temperature (300 K) orthorhombic polymorph, the CoIII complex cation resides on a crystallographic mirror plane, whereas the Cl− anion occupies a crystallographic twofold axis. In the unit cell of the monoclinic polymorph, the cationic CoIII complex is in a general position, whose charge is balanced by two halves of two Cl− anions, each residing on a crystallographic twofold axis. 相似文献
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Susan Sia Isabel M. Saez Stephen J. Cowling John W. Goodby 《Helvetica chimica acta》2023,106(7):e202300041
Liquid Crystals are thought of as being complex fluids, underpinned by self-assembly and self-organisation within partially ordered fluids, and which sit between solid and liquid states of matter. The realm of the field stretches from low molar mass to polymeric materials, from organic to inorganic substances, and from being functional materials to biological organelles. In this article, we explore the cusp of the change over from nano- to macro-sciences through the formation of ‘supermolecular’ systems, and we debate if such materials are in fact oligomers or materials having giant molecules possessing discrete chemical constitutions? We performed this investigation by synthesising mesogenic materials based upon difluoroterphenyls, terminally substituted with a chiral motif based on (S)-2-octanol, and which could be appended onto a variety of siloxane scaffolds. We studied the structures and properties of six mesomorphic materials in which we systematically increased the number of mesogenic units attached to the scaffold. 相似文献
74.
Charmaine van Blerk Gert J. Kruger 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(10):o537-o542
The redetermined crystal structures of hexane‐1,6‐diammonium dichloride, C6H18N22+·2Cl−, (I), hexane‐1,6‐diammonium dibromide, C6H18N22+·2Br−, (II), and hexane‐1,6‐diammonium diiodide, C6H18N22+·2I−, (III), are described, focusing on their hydrogen‐bonding motifs. The chloride and bromide salts are isomorphous, with both demonstrating a small deviation from planarity [173.89 (10) and 173.0 (2)°, respectively] in the central C—C—C—C torsion angle of the hydrocarbon backbone. The chloride and bromide salts also show marked similarities in their hydrogen‐bonding interactions, with subtle differences evident in the hydrogen‐bond lengths reported. Bifurcated interactions are exhibited between the N‐donor atoms and the halide acceptors in the chloride and bromide salts. The iodide salt is very different in molecular structure, packing and intermolecular interactions. The hydrocarbon chain of the iodide straddles an inversion centre and the ammonium groups on the diammonium cation of the iodide salt are offset from the planar hydrocarbon backbone by a torsion angle of 69.6 (4)°. All three salts exhibit thermotropic polymorphism, as is evident from differential scanning calorimetry analysis and variable‐temperature powder X‐ray diffraction studies. 相似文献
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Adams GS Anderson M Cummings JP Danko I Hu D Moziak B Napolitano J He Q Insler J Muramatsu H Park CS Thorndike EH Yang F Artuso M Blusk S Khalil S Li J Menaa N Mountain R Nisar S Randrianarivony K Sia R Skwarnicki T Stone S Wang JC Bonvicini G Cinabro D Dubrovin M Lincoln A Asner DM Edwards KW Naik P Briere RA Ferguson T Tatishvili G Vogel H Watkins ME Rosner JL Adam NE Alexander JP Cassel DG Duboscq JE Ehrlich R Fields L Gibbons L Gray R Gray SW Hartill DL Heltsley BK Hertz D Jones CD 《Physical review letters》2007,99(19):191805
Using data collected near the D{s}{*+}D{s}{-} peak production energy E_{cm}=4170 MeV by the CLEO-c detector, we study the decays of D{s}{+} mesons to two pseudoscalar mesons. We report on searches for the singly Cabibbo-suppressed D{s}{+} decay modes K{+}eta, K{+}eta', pi{+}K{S}{0}, K{+}pi{0}, and the isospin-forbidden decay mode D{s}{+}-->pi{+}pi{0}. We normalize with respect to the Cabibbo-favored D{s}{+} modes pi{+}eta, pi{+}eta', and K{+}K{S}{0}, and obtain ratios of branching fractions: B(D{s}{+}-->K{+}eta)/B(D{s}{+}-->pi{+}eta)=(8.9+/-1.5+/-0.4)%, B(D{s}{+}-->K{+}eta')/B(D{s}{+}-->pi{+}eta')=(4.2+/-1.3+/-0.3)%, B(D{s}{+}-->pi{+}K{S}{0})/B(D{s}{+}-->K{+}K{S}{0})=(8.2+/-0.9+/-0.2)%, B(D{s}{+}-->K{+}pi{0})/B(D{s}{+}-->K{+}K{S}{0})=(5.5+/-1.3+/-0.7)%, and B(D{s}{+}-->pi{+}pi{0})/B(D{s}{+}-->K{+}K{S}{0})<4.1% at 90% C.L., where the uncertainties are statistical and systematic, respectively. 相似文献
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Lopez A Mehrabyan S Mendez H Ramirez J Ge JY Miller DH Sanghi B Shipsey IP Xin B Adams GS Anderson M Cummings JP Danko I Hu D Moziak B Napolitano J He Q Insler J Muramatsu H Park CS Thorndike EH Yang F Artuso M Blusk S Khalil S Li J Menaa N Mountain R Nisar S Randrianarivony K Sia R Skwarnicki T Stone S Wang JC Bonvicini G Cinabro D Dubrovin M Lincoln A Asner DM Edwards KW Naik P Briere RA Ferguson T Tatishvili G Vogel H Watkins ME Rosner JL Adam NE Alexander JP Cassel DG Duboscq JE Ehrlich R 《Physical review letters》2007,99(12):122001
The decay psi(2S) --> etaJ/psi is used to measure, for the first time, all prominent eta-meson branching fractions with the same experiment in the same dataset, thereby providing a consistent treatment of systematics across branching fractions. We present results for eta decays to gamma gamma, pi(+)pi(-)pi(0), 3pi(0), pi(+)pi(-)gamma and e(+)e(-)gamma, accounting for 99.9% of all eta decays. The precision of several of the branching fractions and their ratios is improved. Two channels, pi(+)pi(-)gamma and e(+)e(-)gamma, show results that differ at the level of three standard deviations from those previously determined. 相似文献
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Aquines O Li Z Lopez A Mendez H Ramirez J Huang GS Miller DH Pavlunin V Sanghi B Shipsey IP Xin B Adams GS Anderson M Cummings JP Danko I Napolitano J He Q Insler J Muramatsu H Park CS Thorndike EH Coan TE Gao YS Liu F Stroynowski R Artuso M Blusk S Butt J Li J Menaa N Mountain R Nisar S Randrianarivony K Redjimi R Sia R Skwarnicki T Stone S Wang JC Zhang K Csorna SE Bonvicini G Cinabro D Dubrovin M Lincoln A Asner DM Edwards KW Briere RA Brock I Chen J Ferguson T Tatishvili G Vogel H 《Physical review letters》2006,96(15):152001
Using 420 pb(-1) of data collected on the upsilon(5S) resonance with the CLEO III detector, we reconstruct B mesons in 25 exclusive decay channels to measure or set upper limits on the decay rate of upsilon(5S) into B meson final states. We measure the inclusive B cross section to be sigma(upsilon(5S) --> BB(X)) = (0.177 +/- 0.030 +/- 0.016) nb and make the first measurements of the production rates of sigma(upsilon(5S) --> B*B*) = (0.131 +/- 0.025 +/- 0.014) nb and sigma(upsilon(5S) --> BB*) = (0.043 +/- 0.016 +/- 0.006) nb, respectively. We set 90% confidence level limits of sigma(upsilon(5S) -->BB) < 0.038 nb, sigma(upsilon(5S) --> B(*)B(*)pi) < 0.055 nb and sigma(upsilon(5S) --> BBpipi) < 0.024 nb. We also extract the most precise value of the B(s)* mass to date, M(B(s)*) = (5411.7 +/- 1.6 +/- 0.6) MeV/c2. 相似文献
80.
Colin Adams Dan Collins Katherine Hawkins Charmaine Sia Rob Silversmith Bena Tshishiku 《Geometriae Dedicata》2012,159(1):185-206
The bridge index and superbridge index of a knot are important invariants in knot theory. We define the bridge map of a knot conformation, which is closely related to these two invariants, and interpret it in terms of the tangent indicatrix of the knot conformation. Using the concepts of dual and derivative curves of spherical curves as introduced by Arnold, we show that the graph of the bridge map is the union of the binormal indicatrix, its antipodal curve, and some number of great circles. Similarly, we define the inflection map of a knot conformation, interpret it in terms of the binormal indicatrix, and express its graph in terms of the tangent indicatrix. This duality relationship is also studied for another dual pair of curves, the normal and Darboux indicatrices of a knot conformation. The analogous concepts are defined and results are derived for stick knots. 相似文献