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11.
Caterina Viglianisi Stefano Menichetti Giulio Assanelli Maria Carmela Sacchi Incoronata Tritto Simona Losio 《Journal of polymer science. Part A, Polymer chemistry》2012,50(22):4647-4655
A new family of ethylene‐based copolymers with controlled amounts of a norbornene comonomer (NArOH) bearing a stabilizing antioxidant functionality (2,6‐di‐tert‐butyl phenol) was prepared. Due to unavoidable exo/endo equilibrium operative in NArOH comonomer, a complete and detailed NMR assignment of the structure of the prepared ethylene/NArOH copolymers was carried out for the determination of the exo/endo ratio inside the polymer. These novel functionalized comonomers can be considered suitable starting material for preparing ethylene‐based copolymers, with tunable comonomer content, as non‐releasing macromolecular antioxidant additives for specific application in safe food and/or drug packaging © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
12.
13.
Caterina Costa Carmela Cavalcante Francesca Zito Yukio Yokota Valeria Matranga 《Molecular diversity》2010,14(4):653-665
The extracellular matrix protein Pl-nectin, a 210-kDa homodimer originally purified from sea urchin eggs, plays a crucial role in cell adhesion and embryonic
morphogenesis. The compiled cDNA sequence, obtained by RT-PCR primer walking and 3′ RACE, identified a 984aa product containing
a 23aa signal peptide and including all six internal peptides identified by protein microsequencing. The protein is a new
member of the galactose-binding protein superfamily as it consists of six 151–156aa-long tandemly repeated domains (D1–D6),
homologous to the discoidin-like domains, also known as F5/8-type C domains. Based on homology modelling, we present a three-dimensional
structure (3D) for D5, identified as the prototype domain. The molecular modelling of the assembled Pl-nectin homodimer accounts for a Pl-nectin quaternary structure composed of two 105-kDa C-shaped monomers linked by a S–S bridge. The presence of an LDT motif
between the first and the second exposed loops of the D2 domain suggests the binding of Pl-nectin to an integrin receptor. Altogether, the in silico analysis described here is consistent with previous biochemical
reports and offers a basis for predictions to be experimentally tested. 相似文献
14.
Caterina Fraschetti Antonello Filippi Maria Elisa Crestoni Tadashi Ema Maurizio Speranza 《Journal of the American Society for Mass Spectrometry》2013,24(4):573-578
The most common protocols for the quantitative determination of the enantiomeric excess (ee) of raw mixtures by ESI-MS reveal inadequate in cases where the distribution of diastereomeric derivatives diverges from the ee of original solutions. This phenomenon is attributable to a matrix effect, i.e., to the stereospecific formation of high order noncovalent adducts in the ESI droplets, which alters the actual availability of the diastereomeric species under MS analysis. In this frame, the assumption of classic protocols that the ionization correction factor q is independent on the composition of the mixture submitted to analysis is questionable. An alternative methodology is presented in this paper, which is aimed at circumventing the problem by excluding any chemical derivatization of the original raw mixture. It is based on the measurement of the actual distribution of ESI-formed proton-bound diastereomeric complexes from the enantiomeric mixture through a careful analysis of their reaction kinetics with a suitable reactant. 相似文献
15.
Dr. Andrea Aloia Dr. Michele Casiello Prof. Lucia D'Accolti Dr. Caterina Fusco Prof. Angelo Nacci Dr. Antonio Monopoli 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(65):e202202350
A novel Pd-catalysed oxidative coupling between benzoic acids and vinylarenes or acrylates to furnish isocoumarins and phthalides is reported. The reaction proceeds smoothly in molten tetrabutylammonium acetate via a selective C−H bond activation, with very low percentage of ligand-free palladium acetate as the catalyst, under atmospheric pressure of oxygen. Sub-stoichiometric amount of copper acetate is also required as a reoxidant for the palladium. 相似文献
16.
17.
Giacomo Aletti Caterina May Piercesare Secchi 《Journal of Theoretical Probability》2012,25(4):1207-1232
We study a functional equation whose unknown maps a Euclidean space into the space of probability distributions on [0,1]. We prove existence and uniqueness of its solution under suitable regularity and boundary conditions, we show that it depends continuously on the boundary datum, and we characterize solutions that are diffuse on [0,1]. A canonical solution is obtained by means of a Randomly Reinforced Urn with different reinforcement distributions having equal means. The general solution to the functional equation defines a new parametric collection of distributions on [0,1] generalizing the Beta family. 相似文献
18.
Let P(G,λ) be the chromatic polynomial of a graph G with n vertices, independence number α and clique number ω. We show that for every λ≥n, ()α≤≤ ()
n
−ω. We characterize the graphs that yield the lower bound or the upper bound.?These results give new bounds on the mean colour
number μ(G) of G: n− (n−ω)()
n
−ω≤μ(G)≤n−α() α.
Received: December 12, 2000 / Accepted: October 18, 2001?Published online February 14, 2002 相似文献
19.
Carlo Bianca Caterina Mogno 《Mathematical and Computer Modelling of Dynamical Systems: Methods, Tools and Applications in Engineering and Related Sciences》2018,24(2):207-235
This paper deals with the modelling of pedestrian dynamics at the entry of a metro station by means of the thermostatted kinetic theory framework. Specifically, the model depicts the time evolution of the pedestrian dynamics at the turnstiles under no panic conditions. The modelling of the microscopic interactions is based on the stochastic game theory and reflects the decision dynamics of the turnstiles pursued by pedestrians. A qualitative analysis is addressed to the equilibrium solutions by means of the classical stability theory of perturbations. Numerical simulations aim at showing the emerging behaviours captured by the model. In particular the model validation is obtained by performing a sensitivity analysis on the parameters and on the initial conditions. Further refinements and research perspective, including the modelling under panic conditions, are discussed in the last section of the paper. 相似文献
20.
Investigation of anthropic effects connected with metal ions concentration, organic matter and grain size in Bormida river sediments 总被引:9,自引:0,他引:9
Emilio Marengo Maria Carla Gennaro Elisa Robotti Piero Rossanigo Caterina Rinaudo Manuela Roz-Gastaldi 《Analytica chimica acta》2006,560(1-2):172-183
An investigation on the sediment composition and grain size was carried out along the Bormida river (Piedmont, Northern Italy). The samples were taken both in the riverbed and on its banks. Multivariate statistical exploratory methods permitted to identify possible sources of primary pollution. In particular, principal component analysis (PCA) showed that there are probably at least three anthropogenic main causes of pollution, one connected with Cr, Ni and Sn, the second with cadmium and the last one with mercury. Some correlations were found between heavy metal ion concentrations and organic matter and/or the sediment grain size. Differences between the samples collected in the riverbed and on the banks were identified and the relationships between the principal components and the distance of the samples from the riverbed and from the hot spot represented by the ACNA industrial site were also analyzed. 相似文献