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Iacopo Ciabatti Cristina Femoni Maria Carmela Iapalucci Giuliano Longoni Stefano Zacchini 《Journal of Cluster Science》2014,25(1):115-146
The state of art of the chemical, spectroscopic and structural characterization of platinum carbonyl clusters is reviewed. We begin by enlightening the fundamental contribution given to this chemistry of two great scientists: Paolo Chini and Larry Dahl, two without equal maestros of science and life. We then focus the main body of this review on the challenge represented by studying molecular ions already belonging to the nano regime by size almost 50 years ago, and the challenges their chemistry continues to present also nowadays. In detail, the possible reasons which enable the [Pt3n (CO)6n ]2? oligomers to grow up to n = 10, and why the oligomers with n > 5 may self-assemble in infinite molecular conductor wires are suggested. The interplay between the CO/Ptsurface ratios and electronic effects in driving the platinum cluster from pseudo one- to tri-dimensional globular structures, often representing chunks of the fcc metal lattice or interpenetrated pentagonal prisms and icosahedra, is examined by means of two significant examples. The nanocapacitor behavior of most high-nuclearity carbonyl clusters is briefly recalled and is confirmed by most recent results. The size-induced transition of their metal kernels from insulator to semiconductor and the expected consequences of their eventual transition to a metallic state are also discussed. Finally, we conclude by commenting the present lack of Pt cluster interstitially lodging a main group element and not yet quantitatively-assessed aggregation phenomena in solution, perhaps peculiar of ionic salts of carbonyl clusters, which could make undetectable the NMR signal of any spin-active nuclei beyond a cluster nuclearity of ca. 20–25. 相似文献
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Incoronata Tritto Maria Carmela Sacchi Paolo Locatelli San Xi Li 《Macromolecular Symposia》1995,89(1):289-298
The reaction equilibria of Cp2Ti13CH3Cl and Cp2Ti(CH3)2 with AlMe3 (TMA) and/or methylaluminoxane (MAO) have been investigated by 13C NMR. Several adducts have been identified. A study of the 13C 90% enriched ethylene polymerization in an NMR tube in the presence of the above catalytic systems, in the most experimentally significant conditions, and a comparison of the NMR data with the catalytic activity have been made as well. It has been shown that: i) some species are side products, inactive for addition ethylene polymerization; ii) active cation-like species such as Cp2TiMe+Cl·[AlMeO]n- and Cp2TiMe+Me·[AlMeO]n- are formed in titanocene-MAO systems. Concerning the role of AlMe3, contained in MAO solutions, it has been shown that: a) AlMe3 is mainly bound to MAO; b) if some “free” AlMe3 exists in solution it is not the actual cocatalyst in the metallocene-MAO based catalytic systems; c) the amount of AlMe3 influences either active or inactive species. 相似文献
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Maria Carmela Lombardo Marco Sammartino Vincenzo Sciacca 《Comptes Rendus Mathematique》2005,341(11):659-664
In this Note we are concerned with the well-posedness of the Camassa–Holm equation in analytic function spaces. Using the Abstract Cauchy–Kowalewski Theorem we prove that the Camassa–Holm equation admits, locally in time, a unique analytic solution. Moreover, if the initial data is real analytic, belongs to with , and does not change sign, we prove that the solution stays analytic globally in time. To cite this article: M.C. Lombardo et al., C. R. Acad. Sci. Paris, Ser. I 341 (2005). 相似文献
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In [2] the codes C
q
(r,n) over
were introduced. These linear codes have parameters
, can be viewed as analogues of the binary Reed-Muller codes and share several features in common with them. In [2], the weight distribution of C
3(1,n) is completely determined.In this paper we compute the weight distribution of C
5(1,n). To this end we transform a sum of a product of two binomial coefficients into an expression involving only exponentials an Lucas numbers. We prove an effective result on the set of Lucas numbers which are powers of two to arrive to the complete determination of the weight distribution of C
5(1,n). The final result is stated as Theorem 2. 相似文献
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