Stable and Storable N(CF3)2 Transfer Reagents

Fluorinated groups are essential for drug design, agrochemicals, and materials science. The bis(trifluoromethyl)amino group is an example of a stable group that has a high potential. While the number of molecules containing perfluoroalkyl, perfluoroalkoxy, and other fluorinated groups is steadily increasing, examples with the N(CF₃)₂ group are rare. One reason is that transfer reagents are scarce and metal-based storable reagents are unknown. Herein, a set of Cu^I and Ag^I bis(trifluoromethyl)amido complexes stabilized by N- and P-donor ligands with unprecedented stability are presented. The complexes are stable solids that can even be manipulated in air for a short time. They are bis(trifluoromethyl)amination reagents as shown by nucleophilic substitution and Sandmeyer reactions. In addition to a series of benzylbis(trifluoromethyl)amines, 2-bis(trifluoromethyl)amino acetate was obtained, which, upon hydrolysis, gives the fluorinated amino acid N,N-bis(trifluoromethyl)glycine.     

A New Cationic Fluorescent Probe for HSO3− Based on Bisulfite Induced Aggregation Self-Assembly

In comparison with the numerous studies that have centered on developing molecular frameworks for the functionalization of fluorescent materials, less research has addressed the influence of the side chains, despite such appendages contributing significantly to the properties and applications of fluorescent materials. In this work, a new series of cationic fluorescent probes with AIE characteristics have been developed, which exhibit unique sensitivity for charge-diffusion anions, namely HSO₃⁻, via the interactions of ions and the cooperation of the controllable hydrophobicity. The impact of the alkyl chain length attached at the cationic probes suggested that the fluorescent intensity and sensitivity of the probes could be partially enhanced by adjusting their aggregation tendency through the action of the hydrophobic effect under aqueous conditions. DLS and SEM images indicated that different particle sizes and new morphologies of the probes were formed in the anion-recognition-triggered self-assembly process, which could be attributed to the composite effect of electrostatic actions, Van der Waals forces and π-π stacking.     

An Inexpensive Laser Raman Spectrometer Based on CCD Detection

We describe an inexpensive modular Raman spectrometer system that can be assembled from commercial components for under $5000. Three typical applications are presented: a demonstration of a vibrational isotope effect, a Raman polarization experiment, and a resonance Raman experiment. This spectrometer system should make it easier to include the important topic of Raman spectroscopy in the undergraduate physical and analytical chemistry laboratory curricula.     

Effective Potential for \mathcal{P}\mathcal{T}-Symmetric Quantum Field Theories

Recently, a class of -invariant scalar quantum field theories described by the non-Hermitian Lagrangian = () ² +g ² (i) was studied. It was found that there are two regions of . For <0 the -invariance of the Lagrangian is spontaneously broken, and as a consequence, all but the lowest-lying energy levels are complex. For 0 the -invariance of the Lagrangian is unbroken, and the entire energy spectrum is real and positive. The subtle transition at =0 is not well understood. In this paper we initiate an investigation of this transition by carrying out a detailed numerical study of the effective potential V _eff (_c) in zero-dimensional spacetime. Although this numerical work reveals some differences between the <0 and the >0 regimes, we cannot yet see convincing evidence of the transition at =0 in the structure of the effective potential for -symmetric quantum field theories.     

On a problem of Oppenheim concerning “factorisatio numerorum”

Let f(n) denote the number of factorizations of the natural number n into factors larger than 1 where the order of the factors does not count. We say n is “highly factorable” if f(m)<f(n) for all m < n. We prove that f(n)=n·L(n)^?1+0(1) for n highly factorable, where $\text{L(n)=}\text{exp}\text{{}\text{log}\text{n}\text{logloglog}\text{n}\text{loglog}\text{n}\text{}}$. This result corrects the 1926 paper of Oppenheim where it is asserted that f(n)=n·L(n)^?2+0(1). Some results on the multiplicative structure of highly factorable numbers are proved and a table of them up to 10⁹ is provided. Of independent interest, a new lower bound is established for the function Ψ(x, y), the number of n≤x free of prime factors exceeding y.     

Parity anomaly in a \mathcal{P}\mathcal{T}-symmetric quartic Hamiltonian

In this paper, two independent methods are used to show that the non-Hermitian -symmetric wrong-sign quartic Hamiltonian H = (1/2m)p ² − gx ⁴ is exactly equivalent to the conventional Hermitian Hamiltonian . First, this equivalence is demonstrated by using elementary differential-equation techniques and second, it is demonstrated by using functional-integration methods. As the linear term in the Hermitian Hamiltonian is proportional to ℏ, this term is anomalous; that is, the linear term in the potential has no classical analog. The anomaly is a consequence of the broken parity symmetry of the original non-Hermitian -symmetric Hamiltonian. The anomaly term in remains unchanged if an x ² term is introduced into H. When such a quadratic term is present in H, this Hamiltonian possesses bound states. The corresponding bound states in are a direct physical measure of the anomaly. If there were no anomaly term, there would be no bound states.     

How to grow it? Strategies of mathematical development presented by the example of enumerating certain set partitions

Mathematische Semesterberichte - We describe in the form of a&nbsp;dialogue a&nbsp;development of various reflections on the combinatorics of set partitions; among the topics we pursue are...     

Novel perturbation expansion for the Langevin equation

We discuss the randomly driven systemdx/dt= -W(x) +f(t), wheref(t) is a Gaussian random function or stirring force withf(t)f(t)=2(t–t), andW(x) is of the formgx ¹⁺². The parameter is a measure of the nonlinearity of the equation. We show how to obtain the correlation functionsx(t)f(t)···x(t( n)) _f as a power series in. We obtain three terms in the expansion and show how to use Padé approximants to analytically continue the answer in the variable. By using scaling relations, we show how to get a uniform approximation to the equal-time correlation functions valid for allg and.     

Transportation problems which can be solved by the use of hirsch-paths for the dual problems

Balinski uses his signature method for the proof of the Hirsch-conjecture for dual transportation polyhedra to obtain an efficient algorithm for the assignment problem. We will show how to extend this method to other primal transportation problems, including transportation problems with unit demands. We then prove that Balinski's assignment algorithm is equivalent, cycle by cycle, to that of Hung and Rom. We demonstrate that, under some assumptions for our probability model, a modification of the latter algorithm has an average complexity of O(n ²logn) and present some computational results confirming this. We also present results that indicate that this modification compares favorably with Balinski's algorithm and other codes. Research of both authors supported, in part, by grants of the Alexander von Humboldt-Stiftung. Supported, in part, by NSF grant DMS-8504050.