A 200 W diode-side-pumped CW 2 μm Tm:YAG laser with water cooling at 8°C

A water-cooled 785 nm diode-side-pumped high-power CW Tm:YAG laser system at 2 μm is reported. 200 W output power is achieved with cooling water running at 8°C. As far as we know, this is the highest output power for a diode-pumped all solid-state 2 μm Tm:YAG laser. The output corresponds to optical-to-optical conversion efficiency of 11.2%, with a slope efficiency of about 22.8%. To make the system structure simple, only deionized water is used as the coolant instead of alcohol- or glycol-water mixture or the liquid nitrogen in the reported high-power Tm rod laser experiments, which were performed at low temperature near the freezing point of water, or even below.     

Novel electrospun PAN�CPVC composite fibrous membranes as polymer electrolytes for polymer lithium-ion batteries

Composite fibrous membranes based on poly(acrylonitrile)(PAN)-poly(vinyl chloride)(PVC) have been prepared by electrospinning. The fibrous membranes are made up of fibers of 850- to 1,300-nm diameters. These fibers are stacked in layers to produce a fully interconnected pore structure. Polymer electrolytes were prepared by immersing the fibrous membranes in 1 M LiClO₄-PC solution for 60 min. The condition of pure PAN polymer electrolytes is jelly, which has poor mechanical performance and cannot be used. But when PVC with a good mechanical stiffener was added to PAN, the condition of composite PAN?CPVC polymer electrolytes becomes free-standing. In addition, the optimum electrochemical properties have been observed for the polymer electrolyte based on PAN?CPVC (8:2, w/w) to show ionic conductivity of 1.05?×?10^?3 S cm^?1 at 25 °C, anodic stability up to 4.9 V versus Li/Li⁺, and a good compatibility with lithium metal resulting in low interfacial resistance. The promising results showed that fibrous PEs based on PAN?CPVC (8:2, w/w) have good mechanical stability and electrochemical properties. This shows a great potential application in polymer lithium-ion batteries.     

Magnetic surface plasmon-induced tunable photonic bandgaps in two-dimensional magnetic photonic crystals

We experimentally studied magnetically controllable photonic band gaps (PBGs) in two-dimensional magnetic photonic crystals consisting of ferrite rods. Besides the conventional PBG that relates to Bragg scattering, two other types of PBG, resulting from magnetic surface plasmon (MSP) resonance and spin-wave resonance, respectively, are observed. The PBG due to MSP resonance is particularly interesting because of its analogy to surface plasmon in metal; furthermore, it is shown to be completely tunable by an external static magnetic field from both an experimental and a theoretical point of view.     

Surfactant-free hydrothermal synthesis of?submicron?BiFeO3?powders

Submicron BiFeO₃ powders were successfully synthesized via a simple hydrothermal process with the assistance of mineralizer (NaOH) at 150–190°C, using FeCl₃ and Bi(NO₃)₃⋅5H₂O as reactants. The effects of mineralizer concentration, reaction temperature and time on the phase evolution and crystal morphology of the resulting samples were investigated. X-ray diffraction (XRD), transmission electron microscopy (TEM), thermogravimetry and differential scanning calorimetry (TG-DSC), and vibrating sample magnetometry (VSM) were used to characterize the as-synthesized samples. The experimental results revealed that a pure BiFeO₃ phase could be formed at a temperature ranging from 170 to 190°C for 4–20 h in the presence of 0.03–0.12 M NaOH. It was found that the mineralizer concentration, reaction temperature and time played a key role in controlling the growing speed of nuclei and formation of BiFeO₃ crystallites. The possible formation mechanisms of submicron BiFeO₃ powders with different morphologies were presented. The magnetization of BiFeO₃ powders showed a weak ferromagnetic behavior at room temperature.     

基于波数均匀展宽模型的全反射傅里叶变换成像光谱仪高精度光谱定标处理方法

全反射傅里叶变换成像光谱仪ARFTIS(all-reflection Fourier transform imaging spectrometer)是基于FT成像光谱理论的一种新型仪器,它不但具有高光谱分辨率特点,而且还具有宽波段、无色差的特点,特别适合应用在宽波段成像的遥感领域.目前常用的光谱定标方法有单色法、平均法...     

基于小波变换和高斯拟合的在线谱图综合处理方法

微小型移动式现场在线检测技术是分析仪器发展的新领域。针对复杂工作环境中谱图存在强噪声干扰、谱峰重叠、不规则峰形等严重影响仪器的定性和定量准确度的瓶颈技术,提出了一种基于小波变换和高斯拟合相结合的谱图在线综合处理方法,用自研的仪器对甲苯和全氟三丁胺两种典型化合物的谱图进行了处理,并与实验室分析仪器普遍应用的算法进行了对比分析。结果表明,综合方法能够有效解决强噪声干扰、谱峰重叠、不规则峰形问题,提高仪器的定性和定量准确性,同时能够实现数据压缩,满足仪器的在线实时检测要求。综合方法处理甲苯特征峰的平均信噪比(SNR)较移动平滑方法提高了1.3倍,峰位误差ΔM降低了3.6倍,处理全氟三丁胺谱图的数据压缩比为197∶1。     

资料同化中的数字滤波弱约束试验及分析

气象数值预报中,由于分析过程引入初始非平衡,从而引起虚假快波振荡,重力波控制弱约束把资料分析过程和初始化过程结合在一起,通过数字滤波弱约束在极小化过程中实现对分析场的平衡约束,克服非平衡问题. 以2008年初的一次南方雨雪天气为研究个例,进行了数字滤波弱约束的同化试验和预报试验,结果表明,数字滤波弱约束4D-Var能充分控制快波振荡的出现和初始调整现象,使得到的分析场不仅能更好的逼近观测,而且能更好地与模式动力相协调. 预报检验的结果表明,在同化过程中施加数字滤波弱约束,能有效滤除由于地形或观测资料等因素 关键词： 变分同化 初始非平衡 数字滤波 弱约束     

Eu2+掺杂浓度对Ca2MgSi2O7∶Eu2+荧光粉发光特性的影响

采用化学共沉淀法制备了Ca_2-xMgSi₂O₇:xEu²⁺绿色荧光粉.用X射线衍射仪、荧光分光光度计及光色综合测试系统对Ca_2-xMgSi₂O₇:xEu²⁺绿色荧光粉的相结构、发光性能进行了测试.结果表明:其激发光谱分布在300–480 nm波长范围,谱峰位于389,430 nm处,可以被InGaN管芯产生的360–480 nm辐射有效激发;在波长为430 nm蓝光激发下,其发射光谱谱峰位于531 nm处.Ca_2-xMgSi₂O₇:xEu²⁺绿色荧光粉的发光强度随Eu²⁺掺杂量的增加而增强,当Eu²⁺掺杂量x为0.04时,发光强度达到最大值,而后开始降低,发生浓度猝灭.根据Dexter能量共振理论,浓度猝灭是由电偶极-电偶极相互作用引起的. 关键词： 2MgSi₂O₇∶Eu²⁺')" href="#">Ca₂MgSi₂O₇∶Eu²⁺ 绿色荧光粉 发光特性 白光发光二极管     

NaLa(MoO4)2∶Eu3+的水热调控合成与发光特性研究

采用水热法合成了不同粒径的NaLa(MoO₄)₂∶Eu³⁺微晶.通过调节乙二醇浓度和反应时间,研究了NaLa(MoO₄)₂∶Eu³⁺微晶的形貌演变过程,在水热条件下180 ℃反应16 h获得了均一梭子形NaLa(MoO₄)₂∶Eu³⁺微晶,其晶粒长度约为2.0 μm.荧光光谱分析表明,Eu³⁺取代了NaLa(MoO₄)₂中La³⁺的格位, Eu³⁺在613 nm处红光发射(⁵D₀–⁷F₂跃迁)的浓度猝灭机理是电偶极-电四极相互作用,并发生了Eu³⁺( ⁵D₁ ) + Eu³⁺(⁷F₀ )→ Eu³⁺( ⁵D₀ ) + Eu³⁺(⁷F₃) 交叉弛豫,由此导致浓度猝灭. 关键词： 钼酸盐 水热法 稀土离子 发光     

散射体排列方式对二维磁振子晶体带隙结构的影响

本文采用平面波展开法数值计算了由铁圆柱分别按正方排列、三角排列以及六角排列在氧化铕基底材料中构成的二维磁振子晶体带结构,讨论了散射体的不同排列方式对磁振子晶体带隙结构的影响.计算结果表明,三角排列散射体的磁振子晶体能够获得最大的自旋波带隙结构. 关键词： 磁振子晶体 带隙 排列方式