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排序方式: 共有179条查询结果,搜索用时 15 毫秒
1.
Cang Li 《Journal of solid state chemistry》2004,177(12):4569-4575
Reaction of an aqueous slurry of an Mg2Al-NO3 layered double hydroxide with a four-fold excess of Na[Eu(EDTA)] gives a material which analyses for Mg0.68Al0.32(OH)2[Eu(EDTA)]0.10(CO3)0.11·0.66H2O. The interlayer spacing of the material is 13.8 Å, corresponding to a gallery height of 9.0 Å, which accords with the maximal dimensions (9-10 Å) of the anion in metal-EDTA complex salts as determined by single crystal X-ray diffraction. Geometrical considerations show that the charge density on the layered double hydroxide layers is too high to be balanced by intercalation of [Eu(EDTA)]− alone, necessitating the co-intercalation of carbonate ions which have a much higher charge density. 相似文献
2.
Kunqian Mu Kaiwen Jiang Yue Wang Zihan Zhao Song Cang Kaishun Bi Qing Li Ran Liu 《Molecules (Basel, Switzerland)》2022,27(3)
β-cyclodextrin has a unique annular hollow ultrastructure that allows encapsulation of various poorly water-soluble drugs in the resulting cavity, thereby increasing drug stability. As a bioactive molecule, the metabolism of β-cyclodextrin is mainly completed by the flora in the colon, which can interact with API. In this study, understanding the in vivo fate of β-cyclodextrin, a LC-MS/MS method was developed to facilitate simultaneous quantitative analysis of pharmaceutical excipient β-cyclodextrin and API dextromethorphan hydrobromide. The established method had been effectively used to study the pharmacokinetics, tissue distribution, excretion, and metabolism of β-cyclodextrin after oral administration in rats. Results showed that β-cyclodextrin was almost wholly removed from rat plasma within 36 h, and high concentrations of β-cyclodextrin distributed hastily to organs with increased blood flow velocities such as the spleen, liver, and kidney after administration. The excretion of intact β-cyclodextrin to urine and feces was lower than the administration dose. It can be speculated that β-cyclodextrin metabolized to maltodextrin, which was further metabolized, absorbed, and eventually discharged in the form of CO2 and H2O. Results proved that β-cyclodextrin, with relative low accumulation in the body, had good safety. The results will assist further study of the design and safety evaluation of adjuvant β-cyclodextrin and promote its clinical development. 相似文献
3.
Nonlinear Dynamics - This paper reports a pulse-width modulation voltage-mode- and current-mode-controlled DC–DC boost converter with parallel memristance and resistance loads. This circuit... 相似文献
4.
Gansäuer A Knebel K Kube C van Gastel M Cangönül A Daasbjerg K Hangele T Hülsen M Dolg M Friedrich J 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(9):2591-2599
The mechanism of catalytic 4-exo cyclizations without gem-dialkyl substitution was investigated by a comparison of cyclic voltammetry, EPR, and computational studies with previously published synthetic results. The most active catalyst is a super-unsaturated 13-electron titanocene(III) complex that is formed by supramolecular activation through hydrogen bonding. The template catalyst binds radicals via a two-point binding that is mandatory for the success of the 4-exo cyclization. The computational investigations revealed that formation of the observed trans-cyclobutane product is not possible from the most stable substrate radical. Instead, the most stable product is formed with the lowest energy of activation from a disfavored substrate in a Curtin-Hammett related scenario. 相似文献
5.
Brightness reversion of softwood (SW) and hardwood (HW) bleached chemithermomechanical pulps (BCTMP) with a 300–400nm light source under argon, oxygen, and air were studied in the absence and presence of UV-screens using UV–Vis reflectance difference spectroscopy. The UV-Vis difference absorption spectra of control SW and HW BCTMP testsheets indicate that as the concentration of atmospheric oxygen is increased, the absorption at max 360nm increases and a blue shift occurs. In all of the cases studied, brightness reversion was observed to occur under an argon atmosphere. The addition of benzophenone and benzotriazole additives to BCTMP testsheets resulted in a significant decrease in formation of chromophores absorbed at 400nm and 360nm. The possible mechanisms contributing to these effects are discussed in terms of the photoformation of lignin chromophoric structures. 相似文献
6.
A new two‐phase structure‐preserving doubling algorithm for critically singular M‐matrix algebraic Riccati equations 下载免费PDF全文
Tsung‐Ming Huang Wei‐Qiang Huang Ren‐Cang Li Wen‐Wei Lin 《Numerical Linear Algebra with Applications》2016,23(2):291-313
Among numerous iterative methods for solving the minimal nonnegative solution of an M‐matrix algebraic Riccati equation, the structure‐preserving doubling algorithm (SDA) stands out owing to its overall efficiency as well as accuracy. SDA is globally convergent and its convergence is quadratic, except for the critical case for which it converges linearly with the linear rate 1/2. In this paper, we first undertake a delineatory convergence analysis that reveals that the approximations by SDA can be decomposed into two components: the stable component that converges quadratically and the rank‐one component that converges linearly with the linear rate 1/2. Our analysis also shows that as soon as the stable component is fully converged, the rank‐one component can be accurately recovered. We then propose an efficient hybrid method, called the two‐phase SDA, for which the SDA iteration is stopped as soon as it is determined that the stable component is fully converged. Therefore, this two‐phase SDA saves those SDA iterative steps that previously have to have for the rank‐one component to be computed accurately, and thus essentially, it can be regarded as a quadratically convergent method. Numerical results confirm our analysis and demonstrate the efficiency of the new two‐phase SDA. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
7.
8.
Jun Cheng Jie Cang Shi-Jun Liao 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2009,60(3):450-478
A train of periodic deep-water waves propagating on a steady shear current with a vertical distribution of vorticity is investigated
by an analytic method, namely the homotopy analysis method (HAM). The magnitude of the vorticity varies exponentially with
the magnitude of the stream function, while remaining constant on a particular streamline. The so-called Dubreil–Jacotin transformation
is used to transfer the original exponentially nonlinear boundary-value problem in an unknown domain into an algebraically
nonlinear boundary-value problem in a known domain. Convergent series solutions are obtained not only for small amplitude
water waves on a weak current but also for large amplitude waves on a strong current. The nonlinear wave-current interaction
is studied in detail. It is found that an aiding shear current tends to enlarge the wave phase speed, sharpen the wave crest,
but shorten the maximum wave height, while an opposing shear current has the opposite effect. Besides, the amplitude of waves
and fluid velocity decay over the depth more quickly on an aiding shear current but more slowly on an opposing shear current
than that of waves on still water. Furthermore, it is found that Stokes criteria of wave breaking is still valid for waves
on a shear current: a train of propagating waves on a shear current breaks as the fiuid velocity at crest equals the wave
phase speed. Especially, it is found that the highest waves on an opposing shear current are even higher and steeper than
that of waves on still water. Mathematically, this analytic method is rather general in principle and can be employed to solve
many types of nonlinear partial differential equations with variable coefficients in science, finance and engineering. 相似文献
9.
借助于广义算子半群和广义积分算子半群的关系,讨论广义算子半群的Perron型指数稳定性,研究了广义积分算子半群的渐近行为. 相似文献
10.
A linear optical unambiguous discrimination of hyperentangled Bell states is proposed for two‐photon systems entangled in both the polarization and momentum degrees of freedom (DOFs) assisted by time bin. This unambiguous discrimination scheme can completely identify 16 orthogonal hyperentangled Bell states using only linear optical elements, where the function of the auxiliary entangled Bell state is replaced by time bin. Moreover, the possibility of extending this scheme for distinguishing hyperentangled Bell states in n DOFs is discussed, and it shows that hyperentangled Bell states in n ( ) DOFs can be distinguished with k ( ) auxiliary entangled states of additional DOFs by introducing a time delay, which decreases the auxiliary entanglement resource required for unambiguous discrimination of hyperentangled Bell state. Therefore, this scheme provides a new way for distinguishing hyperentangled states with current technology, which will extend the application of discrimination of hyperentangled states via linear optics to other quantum information protocols besides hyperdense coding schemes in the future. 相似文献