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21.
On‐line coupling of LC and ICP‐MS has been used for fractionation and detection of species of Cu, Fe, I, Se and Zn in human serum. It has been shown that anion exchange chromatography provided better separation capability (both intra‐ and inter‐element) than size‐exclusion chromatography. The mobile phases for ion exchange chromatography consisted of Tris–HNO3 buffer and ammonium salt (nitrate, acetate or formate). Formate was found to be the best mobile phase counter ion, enabling good chromatographic separation, and is acceptable for mass spectrometry too. The quantitative evaluation of element concentrations adhering to individual fractions was performed by the peak area normalization method. The repeatability of results ranged from 3 to 15% (depending on the element concentration level) and represented the main part of the result uncertainty. The accuracy of Cu and Zn fraction determinations was confirmed by comparison with the isotope dilution technique. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
22.
Summary We study the integration theory for general integral metrics when restricted to upper integrals q, finding improvements in the relation between the classes of the q-integrable and the ql-integrable functions. We give new results and notions which lead to the desirable characterizations of q-integrable functions as ql-integrable f with q(|f|) < ∞, and of ql-integrable functions via the integrability of their upper truncations, under natural conditions which are fulfilled in most
finitely additive integration theories. 相似文献
23.
Bernardo Lafuerza-Guillén Donal O’regan Reza Saadati 《Proceedings Mathematical Sciences》2007,117(1):61-70
We introduce the concept of quotient in PN spaces and give some examples. We prove some theorems with regard to the completeness
of a quotient. 相似文献
24.
J. J. EGOZCUE J. L. DIAZ-BARRERO V. PAWLOWSKY-GLAHN 《数学学报(英文版)》2006,22(4):1175-1182
The set of probability functions is a convex subset of L1 and it does not have a linear space structure when using ordinary sum and multiplication by real constants. Moreover, difficulties arise when dealing with distances between densities. The crucial point is that usual distances are not invariant under relevant transformations of densities. To overcome these limitations, Aitchison's ideas on compositional data analysis are used, generalizing perturbation and power transformation, as well as the Aitchison inner product, to operations on probability density functions with support on a finite interval. With these operations at hand, it is shown that the set of bounded probability density functions on finite intervals is a pre-Hilbert space. A Hilbert space of densities, whose logarithm is square-integrable, is obtained as the natural completion of the pre-Hilbert space. 相似文献
25.
Generally, in homotopy theory a cylinder object (or, its dual, a path object) is used to define homotopy between morphisms,
and a cone object is used to build exact sequences of homotopy groups. Here, an axiomatic theory based on a cone functor is
given. Suspension objects are associated to based objects and cofibrations, obtaining homotopy groups referred to an object
and relative to a cofibration, respectively. Exact sequences of these groups are built. Algebraic and particular examples
are given. We point out that the main results of this paper were already stated in [3], and the purpose of this article is
to give full details of the foregoing. 相似文献
26.
E. Liénard G. Ban J. Blieck D. Durand F. Duval X. Fléchard M. Herbane M. Labalme Y. Lemière F. Mauger A. Méry O. Naviliat-Cuncic D. Rodríguez J. C. Thomas 《Hyperfine Interactions》2006,172(1-3):29-33
We report on the status of the LPCTrap experiment, devoted to measure the β–ν angular correlation in the pure Gamow–Teller
decay of 6He. This measurement is motivated by the search for the presence of tensor type contributions to the weak interaction. The
6He ions are confined in a novel transparent Paul trap. The β particles and the recoil ions are detected in coincidence to
deduce the angular correlation parameter. The commissioning run performed in 2005 has given the proof of principle of this
experiment. Up to 105 coincidences were recorded during a second run in 2006. 相似文献
27.
Elena Larraz Carlos Elvira Julio San Romn 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1641-1649
This article explores the synthesis of a novel methacrylic macromonomer with an amphiphilic character derived from poly(ethylene glycol) tert‐octylphenyl ether (MT) and its respective homopolymer. To know their reactivity in radical copolymerization reactions with methyl methacrylate (MMA), a model monomer (MTm) was synthesized to determine the reactivity ratios and compare them with the low molar fractions of copolymers of MT with MMA because they were difficult to isolate. They were rMTm = 0.97 and rMMA = 0.95. The compositional diagrams when representing the weight fraction of MT and MTm in the feed and the copolymer suggested that a clear correlation exists between the experimental points of the model monomer MTm and the macromonomer MT ones, suggesting that the length of the side poly(ethylene oxide) chain does not affect the reactivity of the methacrylic double bond in the prepared monomers for this type of polymerization reaction. The reactivity ratios of the copolymers have a tendency for the formation of random or Bernoullian copolymers. The glass‐transition temperatures (Tg's) of the prepared copolymers were determined by differential scanning calorimetry, deviated from the Fox equation, and discussed on the basis of treatments that consider the influence of the monomeric units along the copolymer chains, determining the Tg of the corresponding alternating dyads. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1641–1649, 2003 相似文献
28.
María G. Armentano Ricardo G. Durn 《Numerical Methods for Partial Differential Equations》2003,19(5):653-664
In this article we analyze the effect of mass‐lumping in the linear triangular finite element approximation of second‐order elliptic eigenvalue problems. We prove that the eigenvalue obtained by using mass‐lumping is always below the one obtained with exact integration. For singular eigenfunctions, as those arising in non convex polygons, we prove that the eigenvalue obtained with mass‐lumping is above the exact eigenvalue when the mesh size is small enough. So, we conclude that the use of mass‐lumping is convenient in the singular case. When the eigenfunction is smooth several numerical experiments suggest that the eigenvalue computed with mass‐lumping is below the exact one if the mesh is not too coarse. © 2003 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 19: 653–664, 2003 相似文献
29.
Gabriela Jeronimo Teresa Krick Juan Sabia Martín Sombra 《Foundations of Computational Mathematics》2004,4(1):41-117
We present a bounded probability algorithm for the computation of the
Chowforms of the equidimensional components of an algebraic variety. In particular,
this gives an alternative procedure for the effective equidimensional decomposition
of the variety, since each equidimensional component is characterized by its Chow
form.
The expected complexity of the algorithm is polynomial in the size and the geometric
degree of the input equation system defining the variety. Hence it improves (or
meets in some special cases) the complexity of all previous algorithms for computing Chow forms. In addition to this, we clarify the probability and uniformity aspects,
which constitutes a further contribution of the paper.
The algorithm is based on elimination theory techniques, in line with the geometric
resolution algorithm due to M. Giusti, J. Heintz, L. M. Pardo, and their collaborators.
In fact, ours can be considered as an extension of their algorithm for zero-dimensional
systems to the case of positive-dimensional varieties. The key element for dealing
with positive-dimensional varieties is a new Poisson-type product formula. This
formula allows us to compute the Chow form of an equidimensional variety from a
suitable zero-dimensional fiber.
As an application, we obtain an algorithm to compute a subclass of sparse resultants,
whose complexity is polynomial in the dimension and the volume of the input
set of exponents. As another application, we derive an algorithm for the computation
of the (unique) solution of a generic overdetermined polynomial equation system. 相似文献
30.
Some previous works show that symmetric fixed- and variable-stepsize linear multistep methods for second-order systems which do not have any parasitic root in their first characteristic polynomial give rise to a slow error growth with time when integrating reversible systems. In this paper, we give a technique to construct variable-stepsize symmetric methods from their fixed-stepsize counterparts, in such a way that the former have the same order as the latter. The order and symmetry of the integrators obtained is proved independently of the order of the underlying fixed-stepsize integrators. As this technique looks for efficiency, we concentrate on explicit linear multistep methods, which just make one function evaluation per step, and we offer some numerical comparisons with other one-step adaptive methods which also show a good long-term behaviour.