电化学合成金属醇盐的研究

纳米材料在生物、电子、能源、化工等各个领域的应用日益广泛 ,已成为当前研究的热点 [1,2 ] ,纳米材料的制备有多种方法 ,其中溶胶 -凝胶 ( Sol- gel) [3 ] 、醇盐热解、化学气相淀积 ( CVD)等方法所使用的前驱体主要为金属醇盐 .传统化学方法合成金属醇盐是用 MXn[X为 Hal,R,H,NR2 ,N( Si Me3 ) 2等 ]与醇进行交换反应 ,过程复杂 ,且原材料不易得到 ,产率低 ,纯度达不到要求 ,后续分离繁琐 ,所以人们一直努力寻找合成金属醇盐的新方法 .有机电解合成一般在常温常压下进行 ,可通过调节电极电位控制电极反应的方向和速度 .据报道 [4] …     

CaP/壳聚糖复合膜层的电化学共沉积研究

用电化学共沉积方法在医用钛合金表面成功制备了CaP/壳聚糖复合膜层,并用XRD,SEM,FTIR漫反射光谱和XPS等对复合膜层化学组成及结构进行表征.结果表明,加入壳聚糖可使钙磷沉积层结构发生显著变化,将壳聚糖掺入钙磷沉积层,形成CaP/壳聚糖复合物和杂化物.力学实验表明,在钛基底表面未进行表面预处理条件下,CaP/壳聚糖复合膜层与钛基底的结合力高达2.6MPa,比单一CaP电化学沉积层与基底的结合力提高约4倍.文中还对壳聚糖参与表面电沉积反应机理进行了讨论.     

不锈钢钝化膜耐蚀性与半导体特性的关联研究

通过极化曲线、交流阻抗谱和钝化膜半导体特性等电化学测量，研究了经电化学阳极氧化处理的不锈钢钝化膜在0.5 mol•L^-1 NaCl溶液中耐蚀性能与其半导体特性的关系，进一步探索电化学改性处理不锈钢钝化膜的耐蚀机理. 结果表明，不锈钢钝化膜在负于平带电位范围表现为p型半导体，在高于平带电位范围表现为n型半导体，这主要与组成钝化膜的Fe和Cr氧化物半导体性质有关. 与自然条件下形成的不锈钢钝化膜比较，发现经过电化学阳极氧化后不锈钢钝化膜具有较低的施主与受主浓度，平带电位负移，说明阴离子在钝化膜表面发生吸附. 低的施主与受主浓度及钝化膜表面负电荷的增强，可有效排斥侵蚀性Cl^－在钝化膜表面的特性吸附，有利于提高不锈钢的耐局部腐蚀性能.     

Study of Triaxial Superdeformation in ^162Lu

The triaxially superdeformed states in ^162Lu are investigated using the three-dimensional total routhian surface calculation, and the deformation parameters and the likely configuration are given. The shell and pairing correction energies are considered respectively, and the formation mechanism of triaxial superdeformation is investigated.     

Spectroscopic properties of Ba 6pjnk autoionizing Stark series

With a combination of the isolated core excitation (ICE) technique and a proper polarization configuration of three lasers, both the 6p_1/2nk and 6p_3/2nk autoionizing Stark states excited from the 6snk Stark states with have been measured for the first time. The experimental results are analyzed by fitting them to the Lorentzian profiles, from which the positions and widths are determined at various electric-field strengths. The experimental results indicate that the 6p_1/2nk and 6p_3/2nk autoionizing Stark states have different spectroscopic properties due to the difference of their cores.     

自旋极化核物质的状态方程

在Brueckner-Hartree-Fock理论框架内,研究了自旋极化核物质的状态方程及其自旋依赖性,计算了相关的物理量如朗道参数G₀和G′₀,并着重讨论了三体核力的影响.结果表明:在整个自旋极化度范围内,自旋极化核物质的每核子能量随中子和质子自旋极化度的变化相当精确地满足二次方规律,而且在Brueckner-Hartree-Fock理论框架内,自旋非极化核物质的能量总是比相应的自旋极化核物质的能量低,这表明核物质中不会发生由自旋非极化态向自旋极化态的自发相变.当密度较低时,三体核力对核物质状态方程的自旋依赖性的影响不明显;随着密度的增大,三体核力效应增强,而且三体核力使朗道参数G₀和G′₀增大,从而使核物质对于自旋涨落的稳定性增强     

奇奇核168Lu高自旋态及三轴超形变带的研究

采用TRS方法对¹⁶⁸Lu新发现的4条转动带进行了理论计算,证实了在实验上观测到的一条三轴超形变带,并得到其形变参数值.本工作还对准粒子能量随角频率的变化进行了研究,对实验结果给出了合理解释,说明了为什么实验上很难找到第四条转动带的旋称伙伴带     

On radial Blaschke-Minkowski homomorphisms

In this article we first establish a dual isoperimetric type inequality for mixed radial Blaschke-Minkowski homomorphisms of different orders. Second, we prove a dual Brunn-Minkowski-type and a dual Minkowski-type inequality for mixed radial Blaschke-Minkowski homomorphisms.     

Chaotic response and bifurcation analysis of a flexible rotor supported by porous and non-porous bearings with nonlinear suspension

This study presents numerical work investigating the dynamic responses of a flexible rotor supported by porous journal bearings. Both porous and non-porous bearing types are taken into consideration in this study. The rotating speed ratios and imbalance parameters are also presented and proved to be important control parameters. Many non-periodic responses to chaotic and quasi-periodic motions are found, too. From the bifurcation diagrams in this paper, it is also evidenced that the vibration behaviors would be improved by porous bearings. The modeling result obtained here can be employed to predict the dynamics of bearing–rotor systems, and undesirable behavior of the rotor and bearing orbits can be avoided. Also, this could help engineers and researchers in designing and studying bearing–rotor systems or some turbo-machinery in the future.