电化学沉积羟基磷灰石过程晶体生长行为

采用恒电流电化学沉积方法从含钙与磷盐水溶液中直接在纯金属钛电极表面沉积纳米羟基磷灰石涂层,运用EDS、SEM、XRD、FTIR等方法对其进行表征. 重点考察了一种典型制备条件下钙磷沉积层的形貌、结构及组分随沉积时间的变化,进而探讨相应条件下电化学沉积羟基磷灰石涂层晶体生长过程的基本规律. 研究表明电化学沉积法可用于在医用金属表面直接涂覆含钙离子缺陷的纳米羟基磷灰石涂层,典型条件下涂层的生长规律为: (1)沉积过程中羟基磷灰石晶粒以c轴方向沿沉积面法线方向择优生长,且这一趋势延续整个沉积过程; (2)内层晶粒的生长受到外层晶粒生长的抑制, 对于同层的晶粒,当晶粒分布密集时,晶粒生长可能发生相互制约; (3)随沉积时间的延长,沉积量增加,而膜层的化学组成基本不发生变化.     

络合剂和添加剂对化学镀铜影响的电化学研究

以CuSO4·5H2O作主盐,乙二胺四乙酸二钠盐(Na2EDTA)作主络合剂,三乙醇胺(TEA)作辅助络合剂,2,2′＿联吡啶(dipyridine)作添加剂,组成化学镀铜液体系,研究络合剂、添加剂对该镀液电化学极化性能的影响,并结合化学沉积速率考察TEA和2,2′＿联吡啶对镀液性能的影响.     

Hybrid Bioceramic Coatings of Calcium Phosphate Prepared by Electrodeposition Technique

The electrodeposition of bioceramic coatings of calcium phosphates on metal substrate is a newly developed method for preparing implanted bio-medical devices^[1-2]. It is proposed to have a remarkable higher bioactivity and excellent bio-capability for the electrodeposited bioceramic coating, because it may produce a pure structure and composition of hydraxiapatite (HAP) during electrodeposition process at room temperature. However, the bonding force of electrodeposition bioceramic coating to the metal substrate is too weak. It has become a major problem in developing electrodeposition technique for preparing bioceramic coatings of calcium phosphates on metal substrate. The present work has been emphasized to develop an approach for preparing HAP bioceramic coatings, which has strong bonding force both in the bulk phase of HAP coating and to the metal substrate.     

Effects of Ultraviolet Illumination and Pre-treatments on Porous Silicon Formation

Although porous silicon is readily formed by anodizing silicon wafers in HF-based solutions, its application in silicon-based optoelectronic devices is greatly limited due to its poor stability and low luminescence yield. It is well recognized that the nature of silicon wafers and the fabrication condition parameters significantly influence uniformity, stability and optical properties of porous silicon. In this work, the ultraviolet illumination and pre-treatments were investigated for porous silicon formation. The surface morphologies and optical properties of the samples were also studied.     

Electrophoretic Deposition of Hydroxyapatite from Non-aqueous Media

Hydroxyapatite Ca₁₀(PO₄)₆(OH)₂ (HA) is an important material for bone and tooth implants, as its chemical composition is similar to that of bone tissue. Owing to the inferior mechanical properties of HA, significant research activity has been associated with the development of HA coatings and composites. The interest in electrophoresis for biomedical applications steins from a variety of reasons such as the possibility of deposition of stoichiometric, high purity material to a degree not easily achievable by other processing techniques and the possibility of forming coatings and bodies of complex shape^[1]. In this work, the experimental results of a study of electrophoretic deposition of HA powders, performed in isopropyl alcohol or ethanol as a suspension medium, are reported.     

Existence of solutions to a Neumann boundary value problem with exponential nonlinearity

This paper is concerned with the solutions to the following sinh-Poisson equation with Hénon term$\{\begin{array}{cc}?\mathrm{\Delta }u+u={\epsilon }^2|x?q_1{|}^{2{\alpha }_1}?|x?q_n{|}^{2{\alpha }_n}({\text{e}}^u?{\text{e}}^{?u}),u>0,\hfill & \text{in}\mathrm{\Omega },\hfill \\ \frac{?u}{?\nu }=0,\hfill & \text{on}?\mathrm{\Omega },\hfill \end{array}$ where $\mathrm{\Omega }?{\mathbb{R}}^2$ is a bounded, smooth domain, $\epsilon >0$, ${\alpha }_1,...,{\alpha }_n\in (0,\infty )?\mathbb{N}$, and $q_1,...,q_n\in \mathrm{\Omega }$ are fixed. Given any two non-negative integers $k,l$ with $k+l?1$, it is shown that, for sufficiently small $\epsilon >0$, there exists a solution $u_{\epsilon }$ for which ${\epsilon }^2|x?q_1{|}^{2{\alpha }_1}?|x?q_n{|}^{2{\alpha }_n}({\text{e}}^u?{\text{e}}^{?u})$ asymptotically (i.e. the limit as $\epsilon \to 0$) develops $k+n$ interior Dirac measures and l boundary Dirac measures. The location of blow-up points is characterized explicitly in terms of Green's function of Neumann problem and the function $k(x)=|x?q_1{|}^{2{\alpha }_1}?|x?q_n{|}^{2{\alpha }_n}$.     

溶胶-凝胶法制备改性TiO2纳米薄膜及其防腐蚀性能

应用溶胶-凝胶法和浸渍提拉技术在316L不锈钢表面分别制备TiO2纳米膜和 B-Fe-Ce改性的TiO2纳米膜. 采用场发射扫描电子显微镜(FE-SEM)、原子力显微镜(AFM)、拉曼光谱法和能量分散谱(EDS)对薄膜进行表征,通过电化学阻抗谱(EIS)和动电位阳极极化曲线的测试考察薄膜的耐蚀性及对不锈钢的保护性能. 结果表明:两种纳米薄膜均含锐钛矿型的TiO2纳米颗粒,纯TiO2纳米膜与改性后的纳米膜中颗粒直径分别约为15和10 nm. TiO2/316L不锈钢和 B-Fe-Ce-TiO2/316L不锈钢膜电极浸泡在0.5 mo.lL-1 NaCl溶液后,后者的电化学反应电阻较大,动电位阳极极化曲线的稳定钝化区较宽,击穿电位更高,说明改性的纳米膜的耐蚀性及其保护性能更好.     

Simulation of large-scale fast neutron liquid scintillation detector

Neutron background measurement is always very important for dark matter detection due to almost the same effect for the recoiled nucleus scattered off by the incident neutron and dark matter particle. For deep under-ground experiments, the flux of neutron background is so low that large-scale detection is usually necessary. In this paper, by using Geant4, the relationship between detection efficiency and volume is investigated, meanwhile, two geometrical schemes for this detection including a single large-sized detector and arrayed multi-detector are compared under the condition of the same volume. The geometrical parameters of detectors are filtrated and detection efficiencies obtained under the similar background condition of China Jingping Underground Laboratory (CJPL). The results show that for a large-scale Gd-doped liquid scintillation detector, the detection efficiency increases with the size of detector at the beginning and then trends toward a constant. Under the condition of the same length and cross section, the arrayed multi-detector has almost similar detection performance as the single large-sized detector, while too much detector number could cause degeneration of detection performance. Considering engineering factors, such as testing, assembling and production, the 4 × 4 arrayed detector scheme is flexible and more suitable. Furthermore, the conditions for using fast and slow signal coincidence detection and the detectable lower limit of neutron energy are evaluated by simulating the light process.     

相对论电子束在动态加载等离子体中的自聚焦传输

为了进一步研究相对论电子束-离子通道辐射实验和理论的需要, 研究了相对论电子束入射中性气体以及通过碰撞电离动态加载等离子体实现对高能束流的自聚焦传输过程PIC(particle in cell) 模拟发现, 电子束电离出的离子背景能够实现对电子束的聚焦传输. 但是离子背景横向和纵向的不均匀性对束流的传输特性有显著影响. 在此基础之上, 提出了电子束在横向不均匀离子背景中传输的理论模型, 给出了束流的自聚焦条件.数值计算结果表明, 横向不均匀性会导致电子束的混合相位传输, 使得焦点附近内层电子可能跑到电子束外而被散焦损失, 这与PIC模拟的结果相符. 此外, PIC模拟还发现, 由于电子束的自聚焦, 在焦点处将电离出更多的离子而引起纵向不均匀性, 纵向不均匀性使得碰撞后的低能电子被俘获, 俘获电子效应会大幅降低电子束的传输效率. 但是俘获电子在纵向呈准周期分布, 对传输电子起到静电Wiggler场的作用, 可能实现静电Wiggler场的动态加载. 研究结果对于进一步研究电子束-等离子体系统的实验以及理论模型提出有一定的参考价值.