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排序方式: 共有484条查询结果,搜索用时 980 毫秒
81.
O. Y. Morales T. Martinez P. González M. Navarrete L. Cabrera A. Ramírez 《Journal of Radioanalytical and Nuclear Chemistry》2009,280(2):431-437
The present study in the Metropolitan Zone of Guadalajara (MZG) in the state of Jalisco was carried out along 2007. 222Rn (radon) and 220Rn (thoron) levels were measured in single-family dwellings in normal living conditions (open house condition). Measurements
were accomplished by Electret Passive Environmental Radon Monitors (E-PERM) in different configurations. At the same time
and for the same period, the gamma dose rate was measured by a LiF: Mg, Cu, P+PTFE thermoluminiscent dosimeter. A Quality
Assurance Program was improved. Results show a lognormal distribution of annual concentrations and seasonal variations. Mean
annual concentrations of radon were lower than US EPA and EEC action values. 220Rn levels appear to be higher than the typical value determined by the UNSCEAR Reports (1993 and 2000). Performance of different
E-PERM configurations accomplishes the US EPA guidelines and yield useful results for diverse situations. Gamma rate dose
was higher than that of the Metropolitan Zone of Mexico. 相似文献
82.
Alajarín M Cabrera J Pastor A Sanchez-Andrada P Bautista D 《The Journal of organic chemistry》2006,71(14):5328-5339
The reaction of 2-(phenylamino)- and 2-(dimethylamino)thiazoles with dimethyl acetylenedicarboxylate led unexpectedly to dimethyl 6-(phenylamino)- and 6-(dimethylamino)-3,4-pyridinedicarboxylates. Those compounds reasonably result from a sequence of reactions initiated by a [2 + 2] cycloaddition of the alkyne to the formal C=C of the thiazole ring. These pyridines were obtained in nearly all the cases assayed as the exclusive reaction products under rather mild conditions and in fair to good yields. In contrast, the regioisomeric 2-amino-3,4-pyridinedicarboxylates, which would result from a [4 + 2] cycloaddition followed by sulfur extrusion, were only obtained in one particular case. The two reaction paths leading alternatively to both regioisomers were investigated computationally. The respective [2 + 2] and [4 + 2] cycloadducts were found to be formed stepwise from a common dipolar intermediate. Notably, the step following the [2 + 2] cycloaddition (i.e., the ring opening of the fused cyclobutene intermediate to give an all-cis 1,3-thiazepine) was found to take place in a disrotatory mode. Although geometric constraints and electronic factors may reduce the energy for the disrotation, the implication of the fused five-membered ring in the electronic reorganization leading to the 1,3-thiazepine is determinant. In this sense, this step could be regarded also as a thermally allowed six-electron five-center disrotatory electrocyclic ring opening. The proposed mechanism was experimentally supported by the isolation of several intermediates and other experimental facts. 相似文献
83.
E. Oset D. Cabrera V. K. Magas L. Roca S. Sarkar M. J. Vicente Vacas A. Ramos 《Pramana》2006,66(4):731-752
In these lectures I make an introduction to chiral unitary theory applied to the meson-baryon interaction and show how several well-known resonances are dynamically generated, and others are predicted. Two very recent experiments are analyzed, one of them showing the existence of two Λ(1405) states and the other one providing support for the Λ(1520) resonance as a quasi-bound state of Σ(1385)π. The use of chiral Lagrangians to account for the hadronic interaction at the elementary level introduces a new approach to deal with the modification of meson and baryon properties in a nuclear medium. Examples of it for $\bar K$ andø modification in the nuclear medium are presented 相似文献
84.
The experiment by Collela et al. (1975) [1] evidenced in a striking manner how the gravitational field appears in quantum mechanics. Within the modern framework of gauge theories, one can ascribe such effect as due to gauge fields originated from fundamental symmetries of spacetime: local transformations of the Lorentz-Poincaré group. When this gauge principle is applied to the Dirac equation, we obtain kinematical correlations between the gravitational field and the spin of the particles. The phenomenon is similar to the spin Hall effect found in condensed matter systems, although much smaller in magnitude. Actual measurements may require highly precision interferometric techniques with spin-polarized neutrons. 相似文献
85.
AC Cabrera J Klett H G Dos Santos A Perona R Gil-Redondo SM Francis EM Priego F Gago A Morreale 《Journal of chemical information and modeling》2012,52(8):2300-2309
An ultrafast docking and virtual screening program, CRDOCK, is presented that contains (1) a search engine that can use a variety of sampling methods and an initial energy evaluation function, (2) several energy minimization algorithms for fine tuning the binding poses, and (3) different scoring functions. This modularity ensures the easy configuration of custom-made protocols that can be optimized depending on the problem in hand. CRDOCK employs a precomputed library of ligand conformations that are initially generated from one-dimensional SMILES strings. Testing CRDOCK on two widely used benchmarks, the ASTEX diverse set and the Directory of Useful Decoys, yielded a success rate of ~75% in pose prediction and an average AUC of 0.66. A typical ligand can be docked, on average, in just ~13 s. Extension to a representative group of pharmacologically relevant G protein-coupled receptors that have been recently cocrystallized with some selective ligands allowed us to demonstrate the utility of this tool and also highlight some current limitations. CRDOCK is now included within VSDMIP, our integrated platform for drug discovery. 相似文献
86.
F. C. Cabrera P. H. B. Aoki R. F. Aroca C. J. L. Constantino D. S. dos Santos A. E. Job 《Journal of Raman spectroscopy : JRS》2012,43(4):474-477
Metallic nanostructures, much smaller than the wavelength of visible light, which support localized surface plasmon resonances, are central to the giant signal enhancement achieved in surface‐enhanced Raman scattering (SERS) and surface‐enhanced resonance Raman scattering (SERRS). Plasmonic driven SERS and SERRS is a powerful analytical tool for ultrasensitive detection down to single molecule detection. For all practical SERS applications a key issue is the development of reproducible and portable SERS‐active substrates, where the most widely used metals for nanostructure fabrication are silver and gold. Here, we report the fabrication of a ‘smart film’, containing gold nanoparticles (AuNPs), produced by in situ reduction of gold chloride III (Au+3) in natural rubber (NR) membranes for SERS and SERRS applications. The composite films (NR/AuNP membranes) show characteristic plasmon absorption of Au nanostructures, which notably do not influence the mechanical properties of the NR membranes. The term ‘smart film’ has to do with the fact that the SERS substrate (smart film) is flexible and standalone, which allows one to take it anywhere and to dip it into solutions containing the analyte to be characterized by SERS or SERRS technique. Besides, the synthesis of the AuNPs at the surface of NR films is much simpler than making an Au colloid and cast it onto a substrate surface or preparing an Au evaporated film. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
87.
V. Bilovol A.M. Mudarra Navarro C.E. Rodríguez Torres A.F. Cabrera 《Physica B: Condensed Matter》2012,407(16):3214-3217
A sample of 10 at% Fe-doped SnO2 powder was prepared by mechanical alloying and then thermally treated at 773 K in vacuum. The fit of the diffraction patterns and X-ray absorption spectroscopy measurements revealed that the as milled sample was pure doped rutile. Fe dissolved into SnO2 was found in Fe2+/Fe3+ ionic valence with mainly paramagnetic behavior. After the thermal treatment all techniques indicate the formation of the ternary Sn0.36Fe2.64O4 spinel phase, which is responsible for the observed ferromagnetism. 相似文献
88.
Abe Y Aberle C Akiri T dos Anjos JC Ardellier F Barbosa AF Baxter A Bergevin M Bernstein A Bezerra TJ Bezrukhov L Blucher E Bongrand M Bowden NS Buck C Busenitz J Cabrera A Caden E Camilleri L Carr R Cerrada M Chang PJ Chimenti P Classen T Collin AP Conover E Conrad JM Cormon S Crespo-Anadón JI Cribier M Crum K Cucoanes A D'Agostino MV Damon E Dawson JV Dazeley S Dierckxsens M Dietrich D Djurcic Z Dracos M Durand V Efremenko Y Elnimr M Endo Y Etenko A Falk E Fallot M Fechner M von Feilitzsch F 《Physical review letters》2012,108(13):131801
The Double Chooz experiment presents an indication of reactor electron antineutrino disappearance consistent with neutrino oscillations. An observed-to-predicted ratio of events of 0.944±0.016(stat)±0.040(syst) was obtained in 101 days of running at the Chooz nuclear power plant in France, with two 4.25 GW(th) reactors. The results were obtained from a single 10 m(3) fiducial volume detector located 1050 m from the two reactor cores. The reactor antineutrino flux prediction used the Bugey4 flux measurement after correction for differences in core composition. The deficit can be interpreted as an indication of a nonzero value of the still unmeasured neutrino mixing parameter sin(2)2θ(13). Analyzing both the rate of the prompt positrons and their energy spectrum, we find sin(2)2θ(13)=0.086±0.041(stat)±0.030(syst), or, at 90% C.L., 0.017相似文献
89.
90.