Metal Chemical Vapor Deposition: Design and Synthesis of New Source Reagents for Osmium Thin Films

Treatment of β-diketone ligands, such as hfacH (hexafluoroacetylacetone) or tmhdH (2,2-dimethyl-3,5-heptanedione), with binary metal carbonyls Ru3(CO)12 or Os3(CO)12 in a stainless steel autoclave at elevated temperature afforded the corresponding mononuclear Ru or Os complexes 1, 2 and 3 in good yields. A second type of mononuclear Os CVD source reagent 4 has also been obtained from a reaction of Os3(CO)12 with 3 eq. of iodine under CO atmosphere. These four Ru and Os CVD source complexes are all relatively stable and highly volatile; thus, they can be utilized for depositing the respective metal thin-films with overall quality comparable or better than those deposited using the commercially available source reagents. The surface morphology, the purity and the crystallinity were identified by SEM micrograph, X-ray photoelectron spectroscopy, conductivity measurement and powder XRD, respectively. Possible reaction mechanisms leading to the formation of the metal deposit are presented.     

Experimental Quantum Teleportation of Laser Beams

We experimentally demonstrate quantum teleportation for continuous variables by using squeezed-state entanglement. A fidelity expression for a real experimental system is presented, where all the imperfection factors are considered, including losses and phase fluctuations. The measured fidelity for input coherent states is 0.62 and the prospective result with our measured entanglement and efficiencies is 0.69. We will show the details of the quantum teleportation for continuous variable and discuss the problems for further improvement in this experiment.     

退化的无穷维Hamilton系统的KAM定理

给出了一类较弱的非退化条件,证明了满足该弱非退化条件的退化可积的无穷维Hamilton系统在小扰动下的不变环面存在定理,同时还给出了存在不变环面的参数集合的测度估计.值得一提的是该非退化条件在解析情形下可能是最弱的(受有限维情况的启示).主要运用了KAM技巧证明不变环面的存在性,给出了与上述测度估计有关的小分母条件的测度估计.     

r×t阶Kirkman三连系构造的一种方法

发现了 6n+3的高阶 Kirkman三连系构造方法 .阐明了 r× t阶 Kirkman三连系构造的基本理论 .给出了完全三分图的定义 ,并证明了关于 Kirkman三连系构造的命题 .介绍了 1 3 5阶 Kirkman三连系的构造过程 .     

电子经过介质由于介质被极化影响能量损失的研究

电子经过介质时,将介质极化,本工作的目的是研究较低能量的电子经过不同介质时,由于这种极化效应对于电子能量损耗的影响。利用灌氢气的膨胀式云雾室测量了能量为0.3—1.0Mev的电子经过铍、炭及铝片的平均能耗及最大可几能耗。实验指出:在此能量范围内的电子,经过某些介质,它们的传导电子数与全部电子数的比值f₀以及电阻系数ρ都大,如铍及炭,其能量损耗由于介质被极化而显著减少。电子经过铍的能耗实验结果显著比考虑了介质极化影响的Helpern及Hall与电子能量损耗有显著减少Sterneimer的理论为小;电子经过炭的能耗实验结果是介于此二理论之间。     

Effect of urea on synchronous fluorescence spectra and electrochemical behaviour of cytochrome

The changes of the synchronous fluorescence spectra and the electrochemical behaviour of cytochrome c with the urea concentration are studied. It has been found that with the increase of urea concentration, there occur sequentially the deaggregation of cytochrome c molecules, the increase of exposure extent of the heme group to the solvent, the disruption of Fe-S bond of the heme group and the change in the electrochemical behaviour of cytochrome c. It is suggested that the reason why the electrochemical reaction of cytochrome c is irreversible is that cytochrome c molecules exist in the concentrated solution as oligomers which are electrochemically inactive.     

π+p→Λ+π+K反应共振—近阈效应关联的研究

本文建议作π+p→Λ+π+K反应的实验,其中质心系总能量固定为1900MeV。在末态K介子动能0—90MeV的变化范围内,观察末态Λ-π共振和在∑πk道产生阈附近的近阈效应。通过共振-近阈效应关联和共振的角分布可以确定Y₁^*的自旋和Y₁^*,和∑之间的相对宇称。按照先处理T短阵的么正性,后处理解析性的思想,本文引入了T矩阵在道空间上的对角表象。在此基础上,提出了唯象描述近阈效应、共振现象和末态相互作用,特别是近阈效应和在阈附近共振的关联的一个新方法。并且应用这个方法,处理了所建议实验中的末态共振-近阈效应关联。 关键词：     

低能K-π散射

本文用L.A.P.Balázs处理低能π-π散射问题的方法,计算了低能K-π散射问题。得到了K-π散射I=1/2的P波共振位置(S_R)^1/2=854MeV,半宽度[Г₁^1/2]/2=126MeV和过程π+π→K+K的振幅的唯象常数ξ=0.3μ^-2,共振位置与目前的实验符合较好。     

检验π介子散射过程是否存在p态共振的一个实验方法的建议

An Experiment designed the p-resonance in π-π scattering process is suggested.     

GENERALIZED GAUGE TRANSFORMATION AND CHERN SIMONS COCHAIN

A gauge potential defined on group manifold is defined to qeneralize the gauge transformation.Some symmetry properties and a generalized Chern-Simons cochain are formed.