全文获取类型
收费全文 | 173014篇 |
免费 | 2097篇 |
国内免费 | 725篇 |
专业分类
化学 | 93460篇 |
晶体学 | 2469篇 |
力学 | 7652篇 |
综合类 | 7篇 |
数学 | 17943篇 |
物理学 | 54305篇 |
出版年
2021年 | 1043篇 |
2020年 | 1193篇 |
2019年 | 1204篇 |
2018年 | 1208篇 |
2017年 | 1196篇 |
2016年 | 2411篇 |
2015年 | 1953篇 |
2014年 | 2542篇 |
2013年 | 7785篇 |
2012年 | 6426篇 |
2011年 | 8141篇 |
2010年 | 4955篇 |
2009年 | 5097篇 |
2008年 | 7430篇 |
2007年 | 7400篇 |
2006年 | 7130篇 |
2005年 | 6602篇 |
2004年 | 5928篇 |
2003年 | 5108篇 |
2002年 | 4998篇 |
2001年 | 6037篇 |
2000年 | 4577篇 |
1999年 | 3484篇 |
1998年 | 2640篇 |
1997年 | 2623篇 |
1996年 | 2584篇 |
1995年 | 2279篇 |
1994年 | 2170篇 |
1993年 | 2047篇 |
1992年 | 2359篇 |
1991年 | 2320篇 |
1990年 | 2035篇 |
1989年 | 2014篇 |
1988年 | 2039篇 |
1987年 | 1972篇 |
1986年 | 1883篇 |
1985年 | 2789篇 |
1984年 | 2763篇 |
1983年 | 2209篇 |
1982年 | 2398篇 |
1981年 | 2278篇 |
1980年 | 2229篇 |
1979年 | 2178篇 |
1978年 | 2247篇 |
1977年 | 2202篇 |
1976年 | 2135篇 |
1975年 | 2127篇 |
1974年 | 2027篇 |
1973年 | 2115篇 |
1972年 | 1201篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
231.
MacLatchy C.S. Smith H.C.L. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1991,19(6):1254-1258
The electron current to a Langmuir probe in a moving high-pressure plasma has been measured and analyzed. The plasma is an atmospheric-pressure propane flame, and the probe's speed relative to the plasma was varied from 10 ms-1 to 30 ms-1. The current is linearly dependent on the speed and appears to be comprised of two components-one driven by diffusion and the other by convection. A model is devised which can be used to measure the electron density. By comparing the density computed from this model to that measured from the ion current, it has been possible to measure the electron mobility in the flame gases. The value obtained by the authors is in good agreement with theoretical calculations found in the literature 相似文献
232.
A Triolo J Bertini C Mannucci A Perico V Pestellini 《Journal of chromatography. A》1991,568(2):281-289
A method for the analysis of platelet-activating factor in platelets employing gas chromatography and selected-ion monitoring mass spectrometry with low-energy electron impact and stable isotope dilution was developed. The procedure involved Bligh and Dyer extraction of the sample followed by thin-layer chromatographic purification. Platelet-activating factor is successively hydrolysed to the corresponding 2-acetyl-1-O-alkylglycerol by digestion with phospholipase C, and the product is allowed to isomerize to the more thermodynamically stable 3-acetyl-1-O-alkylglycerol before column purification and derivatization of the free OH with tert.-butyldimethylchlorosaline-imidazole. This reagent is of common use in platelet-activating factor derivatization, but is made to react with 2-acetyl instead of 3-acetyl isomer. The advantages of using the latter for the final derivatization are discussed and this method is compared with others currently available for gas chromatographic-mass spectrometric analysis of platelet-activating factor. 相似文献
233.
Electron energy distribution functions (eedf) in CO2 laser discharge (He—CO2—N2—CO mixture) have been calculated by solving the Boltzmann equation in the presence of given concentrations of excited (vibrational and electronic) states. The results show a well structured eedf as a result of second kind collisions coming from metastable electronic states of N2 and He as well as a strong dependence of rate coefficients for CO2 dissociation and for the ionization of the different species. 相似文献
234.
H. Postma J. D. Bowman C. D. Bowman J. E. Bush P. P. J. Delheij C. M. Frankle C. R. Gould D. G. Haase J. Knudson G. E. Mitchell S. Penttilä N. R. Roberson S. J. Seestrom J. J. Szymansky S. H. Yoo V. W. Yuan X. Zhu 《Hyperfine Interactions》1992,75(1-4):153-163
Parity violation effects have been studied at 40 neutron p-wave resonances of the even-even nuclei238U and232Th. Of these 11 show parity violation effects larger than 2 standard deviations, making parity violation a rather common phenomenon.
Parity mixing up to 10% has been found. The root-mean squared matrix elements for parity violation derived from these resonances
are M=0.58 (+0.50/-0.25) meV for238U, respectively 1.39 (+0.35/-0.38) meV for232Th. 相似文献
235.
Principles and recent developments in ultrasound contrast agents 总被引:6,自引:1,他引:5
The behaviour of gas bubbles and gas encapsulated spheres as echographic contrast agents is reviewed. Compared with rigid spheres, gas bubbles are superior scattering agents and they offer a number of useful properties which can be exploited in a variety of ways. The analysis of their velocity of sound, back-scatter intensity, second harmonic emission and resonant frequency opens up new perspectives in the development of contrast agents for echocardiographic research with potential clinical applications. 相似文献
236.
Liquid crystal televisions have been employed as spatial light modulators in a variety of optical image processing applications. We have used such devices to develop techniques in speckle metrology for the electronic addition of speckle patterns and the display of speckle correlation, and also for the real-time display of object motion. Factors which affect the performance in terms of the useful working range and the accuracy of displacement measurement are discussed. Some modifications to the LCTV which should increase the potential of these devices as spatial light modulators, when used in both amplitude and phase modulation, are considered briefly. 相似文献
237.
G. K. Hubler C. N. Waddell E. P. Donovan J. M. Zavada 《Optical and Quantum Electronics》1991,23(7):S883-S893
Precision reflection measurements were performed on GaAs/AlAs superlattices of the same composition but different layer spacings. Nonlinear-least-squares fits to the data were performed to a single layer. Measurements were extracted for the superlattice thickness, thickness of a disturbed interface layer between the superlattice and substrate, the uniformity in composition and/or spacing and the composition. It was demonstrated that these nondestructive measurements in the infrared region (3000 to 12 000 cm–1) in conjunction with a simple single layer model are capable of accurately yielding the above quantities with high precision. 相似文献
238.
Ferric ferrocyanides synthesized from different sources of ferric cations and ferrocyanide anions and those derived from ferrous ferricyanide, ferrous ferrocyanide and ferric ferricyanide have been studied using Mössbauer and XRD techniques. Structural information of the effect of the provenance on the properties of the final compound is obtained. Significant correlations between isomer shift and quadrupole splitting of inner and outer iron cations have been observed. 相似文献
239.
Techniques of uniformization are used to prove that it is not consistent that the Whitehead groups of cardinality ℵ1 are exactly the strongly ℵ1-free groups. Some consequences of the assumption that every strongly ℵ1-free group of cardinality ℵ1 is Whitehead are derived. Other results about uniformization are also proved.
Research partially supported by NSERC grant #9848.
Research partially supported by the BSF. The authors thank Rutgers University for its support. Publication #441. 相似文献
240.
A 480 L evacuable reaction chamber, equipped with FT-IR spectroscopy on-line and ion chromatography off-line, has been used to study the gas phase reaction between the nitrate radical, NO3, and the reduced organic sulphur compounds CH3CH2SH, (CH3CH2)2S, (CH3CH2)2S2, and CH3CH2SCH3 in air. The products CH3CH2SO3H, SO2, H2SO4, CH3CHO, and CH3CH2ONO2 were identified and quantified in the reactions of the first three compounds, CH3CH2SH, (CH3CH2)2S, and (CH3CH2)2S2. The reaction products were CH3CH2SO3H, CH3SO3H, SO2, H2SO4, CH3CHO, and CH2O in the reaction of CH3CH2SCH3. On the basis of identified reaction products and intermediates observed in the infrared spectra, mechanisms are proposed for the reactions between the NO3 radical and the four reduced organic sulphur compounds. The results of this study, together with those from previous experiments performed in this laboratory on CH3SCH3, CH3SH, and CH3SSCH3 lead to the conclusion that all these species, in the reaction with the NO3 radical, follow a similar degradation mechanism producing SO2, H2SO4, R? SO3H, R? CHO, and R? CH2ONO2, as the main reaction products. The inital step of the reaction of NO3 with R? S? R and R? S? H type (R = CH3, CH2CH3) reduced organic sulphur compounds was found to be H-atom abstraction, probably after the formation of an initial adduct. For the reaction between NO3 and R? S? S? R type compounds, evidence for an addition-decomposition reaction, as the initial steps, was obtained. R? S·, R? S(O)·, and R? S(O)2· appear to be formed as intermediates in all the reactions. © John Wiley & Sons, Inc. 相似文献