Aqueous sol–gel processing of precursor oxides for ZrW<Subscript>2</Subscript>O<Subscript>8</Subscript> synthesis

This paper describes the synthesis of ZrW₂O₈ by the use of an aqueous citrate-gel method in order to prepare a fine, pure and homogeneous oxide mixture suitable for ceramic processing. The thermal expansion coefficient thus obtained for α-ZrW₂O₈ is −10.6 × 10⁻⁶ °C⁻¹ (50–125 °C) whereas for the β-ZrW₂O₈ a value of −3.2 × 10⁻⁶ °C⁻¹ (200–300 °C) is obtained. The advantages of the use of a sol–gel method is expressed in the very homogeneous end-products. The paper describes crystallographic data, morphological structure and the thermal expansion properties of the ZrW₂O₈ material. Moreover, photoluminescence and photochromic properties specific to the precursor gel are described and analyzed. These effects support our views that the precursors show homogeneity up to nanometer level.     

Millimeter-long nanofibers of PMMA spun at super-high speed by ablation with a single pulse of a KrF excimer laser

A new form of matter removal in laser ablation is reported. Polymethylmethacrylate (PMMA) nanofibers are obtained when a PMMA target is irradiated with a single pulse of a KrF excimer laser, whose beam is sharply imaged on a square of side the order of 140 μm, so that a strong intensity gradient is produced. The fluence threshold at which fibers appear, 3 J/cm², is much larger than the ablation threshold, approximately 0.8–1 J/cm². Above this fluence, the melt depth is then large enough and the temperature profile is such that explosive boiling is obtained. The model suggests an expulsion of energetic droplets from the intense pressure of the plume to the exterior of the spot. For the transient melt of a polymeric viscoelastic liquid resulting from UV-laser excitation, such droplets provide the heads of the jets pulled from the melt bath, giving rise, after solidification, to nanofibers. The speed of fiber spinning is extremely high (∼800 m/s) and unusual properties of the laser-produced nanofibers may be expected. Received: 16 April 2002 / Accepted: 17 April 2002 / Published online: 19 July 2002     

A two-class global FCFS discrete-time queueing model with arbitrary-length constant service times

We analyze a discrete-time queueing model where two types of customers, each having their own dedicated server, are accommodated in one single FCFS queue. Service times are deterministically equal to \(s \ge 1\) time slots each. New customers enter the system according to a general independent arrival process, but the types of consecutive customers may be nonindependent. As a result, arriving customers may (or may not) have the tendency to cluster according to their types, which may lead to more (or less) blocking of one type by the opposite type. The paper reveals the impact of this blocking phenomenon on the achievable throughput, the (average) system content, the (average) customer delay and the (average) unfinished work. The paper extends the results of earlier work where either the service times were assumed to be constant and equal to 1 slot each, or the customers all belonged to the same class. Our results show that, in case of Poisson arrivals, for given traffic intensity, the system-content distribution is insensitive to the length (s) of the service times, but the (mean) delay and the (mean) unfinished work in the system are not. In case of bursty arrivals, we find that all the performance measures are affected by the length (s) of the service times, for given traffic intensity.     

Prediction of Thermal Damage upon Ultrafast Laser Ablation of Metals

Ultrafast lasers micromachining results depend on both the processing parameters and the material properties. The obtained thermal effects are negligible if a good combination of processing parameters is chosen. However, optimizing the processing parameters leading to the required surface quality on a given material can be quite complex and time consuming. We developed a semi-empirical model to estimate the heat accumulation on a surface as a function of the laser fluence, scanning speed and repetition rate. The simulation results were correlated with experimental ones on different materials, and compared with the transient temperature distributions calculated using an analytical solution to the heat transfer equation. The predictions of the proposed model allow evaluating the heat distribution on the surface, as well as optimizing the ultrafast laser micromachining strategy, yielding negligible thermal damage.     

On buffers with periodical input traffic

The paper considers an infinite discrete-time buffer system with one single output channel. Unlike most analyses of such a buffer system, the present study uses a ‘dynamic’ model for the arrival process of data units into the system. More specifically, the distribution of the number of arrivals per discrete time-unit is allowed to fluctuate in time, in a periodical fashion, whereas in classical models this distribution remains the same, as time goes by. The probability generating function of the number of data units in the buffer, at various time instants, is derived under such dynamic arrival conditions. An extended illustrating example, comparing ‘static’ and ‘dynamic’ arrival models, concludes the paper.     

Reconstruction of an acoustical image using an ‘acousto-electronic’ lens device

Present acoustic imaging apparatuses give only a virtual image of the insonified object. Several studies have been conducted in order to pick up the information from such an image, such as holography and computer data processing. These techniques are very involved, and so simpler processing systems have been analysed in our laboratory in order to reconstruct a true image. Our first system used optical processing of the acoustic echo. In this paper, a second, acousto-electronic, system is described, which enables like the first the attainment of very high image rates in the B-scan mode.     

Buffers with correlated input and output interruptions

The letter considers a discrete buffered system with one randomly interrupted output channel and stochastic interruptions of the arrival stream which are correlated to the output interruptions. The behaviour of this buffer system is studied, and in particular the influence of the correlation is derived.     

Analyzing a degenerate buffer with general inter-arrival and service times in discrete time

In novel switching approaches such as Optical Burst Switching, the involved buffers can only provide a degenerate waiting room, with delays restricted to multiples of a basic value, the granularity. Although the resulting performance loss was already studied analytically, previous work is either limited by the assumption of independent arrivals, or it involves a matrix with size growing fast with buffer size or arrival process complexity. Overcoming this, we developed a generic and accurate loss performance model for a degenerate GI/G/1 buffer in discrete time, that yields results instantly for any constellation of burst sizes, inter-arrival times, granularity, load and buffer size. This paper presents our model and compares its results to simulations, illustrating the impact of different types of correlation in the arrival process on loss performance. Our basic model is general and accurate, it can thus serve as a basic tool for optical switch design.