Expedient one-step synthesis of nitrogen stilbene analogs by transition metal-free hydroamination of arylacetylenes with pyrroles

A novel family of nitrogen stilbene analogs, 1-styrylpyrroles, has been synthesized in good to excellent yields by a straightforward facile transition metal-free addition of pyrroles to arylacetylenes in the KOH/DMSO system (90–120 °C, 5–13 h). Thermodynamically controlled E/Z-isomer ratio of 1-styrylpyrroles depends on structure of both pyrroles and acetylenes ranging from ca. 100% E-stereoselectivity (for the pair unsubstituted pyrrole—phenylacetylene) to 90, 96% Z-stereoselectivity (for the pairs: 2-phenylpyrrole—phenylacetylene and 2-(2-thienyl)pyrrole—phenylacetylene, respectively).     

Shear wave dispersion and attenuation in periodic systems of alternating solid and viscous fluid layers

The attenuation and dispersion of elastic waves in fluid-saturated rocks due to the viscosity of the pore fluid is investigated using an idealized exactly solvable example of a system of alternating solid and viscous fluid layers. Waves in periodic layered systems at low frequencies are studied using an asymptotic analysis of Rytov’s exact dispersion equations. Since the wavelength of shear waves in fluids (viscous skin depth) is much smaller than the wavelength of shear or compressional waves in solids, the presence of viscous fluid layers necessitates the inclusion of higher terms in the long-wavelength asymptotic expansion. This expansion allows for the derivation of explicit analytical expressions for the attenuation and dispersion of shear waves, with the directions of propagation and of particle motion being in the bedding plane. The attenuation (dispersion) is controlled by the parameter which represents the ratio of Biot’s characteristic frequency to the viscoelastic characteristic frequency. If Biot’s characteristic frequency is small compared with the viscoelastic characteristic frequency, the solution is identical to that derived from an anisotropic version of the Frenkel–Biot theory of poroelasticity. In the opposite case when Biot’s characteristic frequency is greater than the viscoelastic characteristic frequency, the attenuation/dispersion is dominated by the classical viscoelastic absorption due to the shear stiffening effect of the viscous fluid layers. The product of these two characteristic frequencies is equal to the squared resonant frequency of the layered system, times a dimensionless proportionality constant of the order 1. This explains why the visco-elastic and poroelastic mechanisms are usually treated separately in the context of macroscopic (effective medium) theories, as these theories imply that frequency is small compared to the resonant (scattering) frequency of individual pores.     

Slow flow of gas past a strongly heated sphere in the presence of blowing and evaporation from its surface

A solution is obtained to the problem of the simultaneous influence of blowing (evaporation) and large temperature differences on the flow past a sphere and on the force acting on it with allowance for the Burnett thermal stresses in the momentum equation. It is assumed that the Reynolds numbers calculated using the blowing velocity and the velocity of the oncoming flow, respectively, have the order Re_w 1 and Re 1. The temperature difference is determined by the boundary conditions, namely, a constant temperature T_w T on the surface of the sphere (VT/T 1). The problem is solved by the method of matched asymptotic expansions with respect to the small parameter Re. The equations reduce to a system of ordinary differential equations, which are solved numerically by the orthogonal sweep method [1]. It is found that under certain conditions the drag of the sphere can become negative.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 4, pp. 128–134, July–August, 1982.I thank O. G. Fridlender for valuable advice and interest in the work.     

Slow flow of gas around a strongly heated or cooled sphere

Problems similar to those considered in [1, 2] are studied, namely, slow flow over a uniformly heated (or cooled) spherical particle and flow past a weakly nonuniformly heated sphere in the absence of external body forces and with allowance for thermal stresses in the gas. The use of an improved method of numerical solution [3] has made it possible to advance into the region of large temperature differences. A new effect is found: allowance for the thermal stresses in the case of flow around a strongly heated sphere leads to the appearance of a suction force instead of a drag. In the case of flow around a nonuniformly heated sphere the influence of thermal stresses is unimportant. The problems are considered for two temperature dependences of the transport coefficients.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 170–175, October–December, 1981.     

Stability of a hypersonic shock layer on a flat plateStabilité d'une couche de choc hypersonique sur une plaque plane.

Stability of a hypersonic shock layer on a flat plate is examined with allowance for disturbances conditions on the shock wave within the framework of the linear stability theory. The characteristics of the main flow are calculated on the basis of the Full Viscous Shock Layer model. Conditions for velocity, pressure, and temperature perturbations are derived from steady Rankine–Hugoniot relation on the shock wave. These conditions are used as boundary conditions on the shock wave for linear stability equations. The growth rates of disturbances and density fluctuations are compared with experimental data obtained at ITAM by the method of electron-beam fluorescence and with theoretical data of other authors. To cite this article: A.A. Maslov et al., C. R. Mecanique 332 (2004).     

Reaction of Vinyl Selenides with Secondary Phosphines and Elemental Selenium: One‐Pot Selective Synthesis of a New Family of Diselenophosphinic Se‐Esters

Alkyl vinyl selenides react with diverse secondary phosphines and elemental selenium in a 1.1:1:2 molar ratio (120–124°C, 20–40 min, 1,4‐dioxane) to afford selectively earlier unknown diselenophosphinic Se‐esters, R₂P(Se)SeCH(Me)SeR´, in 82–99% yield. This three‐component atom‐economic reaction proceeds via intermediate formation of diselenophosphinic acid R₂P(Se)SeH (generated from secondary phosphine and selenium), which adds to the double bond of vinyl selenide in a Markovnikov manner to give the target products.     

Generalized skew‐Hermitian triangular splitting iteration methods for saddle‐point linear systems

A generalized skew‐Hermitian triangular splitting iteration method is presented for solving non‐Hermitian linear systems with strong skew‐Hermitian parts. We study the convergence of the generalized skew‐Hermitian triangular splitting iteration methods for non‐Hermitian positive definite linear systems, as well as spectrum distribution of the preconditioned matrix with respect to the preconditioner induced from the generalized skew‐Hermitian triangular splitting. Then the generalized skew‐Hermitian triangular splitting iteration method is applied to non‐Hermitian positive semidefinite saddle‐point linear systems, and we prove its convergence under suitable restrictions on the iteration parameters. By specially choosing the values of the iteration parameters, we obtain a few of the existing iteration methods in the literature. Numerical results show that the generalized skew‐Hermitian triangular splitting iteration methods are effective for solving non‐Hermitian saddle‐point linear systems with strong skew‐Hermitian parts. Copyright © 2013 John Wiley & Sons, Ltd.     

A mixed integer linear programming approach to minimize the number of late jobs with and without machine availability constraints

This study investigates scheduling problems that occur when the weighted number of late jobs that are subject to deterministic machine availability constraints have to be minimized. These problems can be modeled as a more general job selection problem. Cases with resumable, non-resumable, and semi-resumable jobs as well as cases without availability constraints are investigated. The proposed efficient mixed integer linear programming approach includes possible improvements to the model, notably specialized lifted knapsack cover cuts. The method proves to be competitive compared with existing dedicated methods: numerical experiments on randomly generated instances show that all 350-job instances of the test bed are closed for the well-known problem 1|_ri|∑_wiUi$1|r_i|\sum w_i{U}_i$. For all investigated problem types, 98.4% of 500-job instances can be solved to optimality within 1 hour.     

Convex equipartitions: the spicy chicken theorem

We show that, for any prime power $n$ and any convex body $K$ (i.e., a compact convex set with interior) in $\mathbb{R }^d$ , there exists a partition of $K$ into $n$ convex sets with equal volumes and equal surface areas. Similar results regarding equipartitions with respect to continuous functionals and absolutely continuous measures on convex bodies are also proven. These include a generalization of the ham-sandwich theorem to arbitrary number of convex pieces confirming a conjecture of Kaneko and Kano, a similar generalization of perfect partitions of a cake and its icing, and a generalization of the Gromov–Borsuk–Ulam theorem for convex sets in the model spaces of constant curvature.     

Exponentially closed fields and the conjecture on intersections with tori

We give an axiomatization of the class ECF of exponentially closed fields, which includes the pseudo-exponential fields previously introduced by the second author, and show that it is superstable over its interpretation of arithmetic. Furthermore, ECF is exactly the elementary class of the pseudo-exponential fields if and only if the Diophantine conjecture CIT on atypical intersections of tori with subvarieties is true.