Ion-solvent interactions and ionic association in ethanol solutions

The electrical conductivities of potassium halides in ethanol have been measured at 25°C. The limiting molar conductances, ionic association constants and the closest approach parameter were calculated (Justice method) and compared with existing literature data. An inversion of the anion size dependence of ionic association constants for these solutions was observed. The results are explained by what has been called localized solvolysis, in which both the cation and the anion of the solvent separated ion pair are connected with different parts of the separating solvent molecule by donor-acceptor bonding. A correlation between K _A and protonic affinity of anions was found. Similar literature data for aqueous and non-aqueous solutions are also examined.     

On tree census and the giant component in sparse random graphs

For each of the two models of a sparse random graph on n vertices, G(n, # of edges = cn/2) and G(n, Prob (edge) = c/n) define t_n(k) as the total number of tree components of size k (1 ≤ k ≤ n). the random sequence {[t_n(k) - nh(k)]n^?1/2} is shown to be Gaussian in the limit n →∞, with h(k) = k^k?2c^k?1e^?kc/k! and covariance function being dependent upon the model. This general result implies, in particular, that, for c> 1, the size of the giant component is asymptotically Gaussian, with mean nθ(c) and variance n(1 ? T)^?2(1 ? 2Tθ)θ(1 ? θ) for the first model and n(1 ? T)^?2θ(1 ? θ) for the second model. Here Te^?T = ce^?c, T<1, and θ = 1 ? T/c. A close technique allows us to prove that, for c < 1, the independence number of G(n, p = c/n) is asymptotically Gaussian with mean nc^?1(β + β²/2) and variance n[c^?1(β + β²/2) ?c^?2(c + 1)β²], where βe^β = c. It is also proven that almost surely the giant component consists of a giant two-connected core of size about n(1 ? T)β and a “mantle” of trees, and possibly few small unicyclic graphs, each sprouting from its own vertex of the core.