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21.
Two-Photon-Induced CO-Releasing Molecules as Molecular Logic Systems in Solution,Polymers, and Cells
Dr. Vadde Ramu Dr. Gandra Upendar Reddy Dr. Jingjing Liu Patrick Hoffmann Dr. Rudrakant Sollapur Dr. Ralf Wyrwa Dr. Stephan Kupfer Prof. Dr. Christian Spielmann Dr. Sylvestre Bonnet Prof. Dr. Ute Neugebauer Dr. Alexander Schiller 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(36):8453-8458
Phototherapeutic applications of carbon monoxide (CO)-releasing molecules are limited because they require harmful UV and blue light for activation. We describe two-photon excitation with NIR light (800 nm)-induced CO-release from two MnI tricarbonyl complexes bearing 1,8-naphthalimide units ( 1 , 2 ). Complex 2 behaves as a logic OR gate in solution, nonwovens, and in HeLa cells. CO release, indicated by fluorescence enhancement, was detected in solution, nonwoven, and HeLa cells by single- (405 nm) and two-photon (800 nm) excitation. The photophysical properties of 1 and 2 have been measured and supported by DFT and TDDFT quantum chemical calculations. Both photoCORMs are stable in the dark in solution and noncytotoxic, leading to promising applications as phototherapeutics with NIR light. 相似文献
22.
A. Ventura T. Chenal M. Bria F. Bonnet P. Zinck Y. Ngono-Ravache E. Balanzat M. Visseaux 《European Polymer Journal》2013
The combination of a neodymium borohydride, Nd(BH4)3(THF)3 (1) or Cp*Nd(BH4)2(THF)x (2), with MgnBuEt (BEM), affords an efficient and highly selective (up to 96.7% 1,4-trans) catalyst for butadiene polymerization. In the presence of excesses of Mg co-catalyst, polymer chain transfer takes place between neodymium and magnesium, and significant amounts of 1,2-units are observed. When considered for butadiene-styrene statistical copolymerization, the catalytic system based on 2 showed a good ability to produce poly[(1,4-trans-butadiene)-co-styrene)], with strong impact of the Mg/Nd ratio on the yield and on the copolymer microstructure, including the percentage of inserted styrene (up to 16.9 mol%). Whatever the co-monomers concentration the polybutadiene backbone remained 1,4-trans. The precise microstructure of the polymers and copolymers was thoroughly analyzed by means of high resolution NMR spectroscopy (900 MHz) and MALDI-ToF spectrometry. 相似文献
23.
Jean Claude Didelot Tomani Olivier Bonnet Alain Nyirimigabo William Deschamps Alembert Tiabou Tchinda Olivia Jansen Allison Ledoux Marie Jeanne Mukazayire Luc Vanhamme Michel Frdrich Raymond Muganga Jacob Souopgui 《Molecules (Basel, Switzerland)》2021,26(9)
Malaria remains one of the leading causes of death in sub-Saharan Africa, ranked in the top three infectious diseases in the world. Plants of the Eriosema genus have been reported to be used for the treatment of this disease, but scientific evidence is still missing for some of them. In the present study, the in vitro antiplasmodial activity of the crude extract and compounds from Eriosema montanum Baker f. roots were tested against the 3D7 strain of Plasmodium falciparum and revealed using the SYBR Green, a DNA intercalating compound. The cytotoxicity effect of the compounds on a human cancer cell line (THP-1) was assessed to determine their selectivity index. It was found that the crude extract of the plant displayed a significant antiplasmodial activity with an IC50 (µg/mL) = 17.68 ± 4.030 and a cytotoxic activity with a CC50 (µg/mL) = 101.5 ± 12.6, corresponding to a selective antiplasmodial activity of 5.7. Bioactivity-guided isolation of the major compounds of the roots’ crude extract afforded seven compounds, including genistein, genistin and eucomic acid. Under our experimental conditions, using Artemisinin as a positive control, eucomic acid showed the best inhibitory activity against the P. falciparum 3D7, a well-known chloroquine-sensitive strain. The present results provide a referential basis to support the traditional use of Eriosema species in the treatment of malaria. 相似文献
24.
25.
Philippe Bonnet 《Transformation Groups》2002,7(1):3-14
In this paper we establish two results concerning algebraic (,+)-actions on
n
. First, let be an algebraic (,+)-action on 3. By a result of Miyanishi, its ring of invariants is isomorphic to [t
1,t
2]. Iff
1,f
2 generate this ring, the quotient map of is the mapF:32,x(f
1(x), f2(x)). By using some topological arguments we prove thatF is always surjective. Secon, we are interested in dominant polynomial mapsF:
n
n-1
whose connected components of their generic fibers are contractible. For such maps, we prove the existence of an algebraic (,+)-action on
n
for whichF is invariant. Moreover we give some conditions so thatF*([t
1,...,t
n-1
]) is the ring of invariants of .Dedicated to all my friends and my family 相似文献
26.
27.
J.-J. Bonnet D. Hubert F. Bonnet M. Bonnefoy A. Fleury L. Avan 《Physics letters. A》1979,70(2):99-102
This note presents the first measurement of the relative intensities of the radiative processes of the L shell of argon. The partial emission cross sections are deduced. Our data show that the radiative transitions within the excited ion are very sensitive to the incident electron energy. 相似文献
28.
Loutelier-Bourhis C Legros H Bonnet JJ Costentin J Lange CM 《Rapid communications in mass spectrometry : RCM》2004,18(5):571-576
The ex vivo identification of dopaminergic metabolites present in rat striata after (L-DOPA + benserazide) treatment is reported. The different metabolites have been identified as the trimethylsilyl derivatives in the striatal extracts by gas chromatography/mass spectrometry. 相似文献
29.
Let b denote the unboundedness number of ωω. That is, b is the smallest cardinality of a subset
such that for everyg∈ωω there isf ∈ F such that {n: g(n) ≤ f(n)}is infinite. A Boolean algebraB is wellgenerated, if it has a well-founded sublatticeL such thatL generatesB. We show that it is consistent with ZFC that
, and there is a Boolean algebraB such thatB is not well-generated, andB is superatomic with cardinal sequence 〈ℵ0, ℵ1, ℵ1, 1〉. This result is motivated by the fact that if the cardinal sequence of a Boolean algebraB is 〈ℵ0, ℵ0, λ, 1〉, andB is not well-generated, then λ≥b. 相似文献
30.
Borohydride complexes of the rare earths have attracted increasing interest during the last decade. This review aims to cover recent results over this period with respect to the preparation, characterization, structure, and applications in organic chemistry of this family of compounds, including inorganic and organometallic complexes. Special emphasis is made on their use for polymerization catalysis. 相似文献