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Misha Chertkov Bob Ecke Gregory Eyink Darryl Holm 《Journal of statistical physics》2003,113(5-6):637-642
125.
Bob Coecke 《Foundations of Physics Letters》1995,8(5):437-447
We generalize Aerts' proof concerning the existence of hidden measurements for experiments withn outcomes to general experiments with an infinite set of outcomes. More specific we prove that, if is a set of experiments on an entityS with a set of pure states , and alle are such that the outcomes can be represented as a measurable subset of a finite dimensional real space, on which for every initial state of the entity there exists a probability measure, then there exists a hidden measurement representation for this set of experiments.Research Assistant of the National Fund for Scientific Research.Supported by Flanders' Federale Diensten voor Wetenschappelijke, Technische en Culturele Aangelegenheden in the framework of IUAP-III No 9. 相似文献
126.
David A. Babb Bob R. Ezzell Katherine S. Clement W. Frank Richey Alvin P. Kennedy 《Journal of polymer science. Part A, Polymer chemistry》1993,31(13):3465-3477
Novel polymers containing alternating perfluorocyclobutane and aromatic ether subunits are prepared from aryl poly(trifluorovinyl ether) monomers via the thermal [2π + 2π] dimerization of the trifluorovinyl ether functionality. A model study is described, which probes the nature of the perfluorocyclobutane rings formed during the polymerization reaction. The bifunctional monomer 4,4′-bis(trifluorovinyloxy) biphenyl and the trifunctional monomer 1,1,1-tris(4-trifluorovinyloxyphenyl)ethane are prepared and polymerized to provide thermoplastic and thermoset polymers, respectively. Characterization of the mechanical and dielectric properties of these new polymers is presented. © 1993 John Wiley & Sons, Inc. 相似文献
127.
We present the S1 → S0 fluorescence spectrum, between 740 and 940 nm, of azulene solutions (10?3 M in methanol) excited with a Q-switched ruby laser. The nitrogen-laser excited S2 → S1 fluorescence spectrum, between 700 and 930 nm, is also reported. The transient S1 → Sn spectrum between 500 and 650 nm was studied, using synchronous nitrogen laser and dye laser excitation. The S5 (1B1(3)) state of azulene was found to be located at 45500 cm?1 and the cross section σ25 of the transient absorption S2 → S5 is estimated to be 3 × 10?18 cm2/molecule. 相似文献
128.
In this paper, we review the generalized Forster-Dexter theory to treat photoinduced electronic energy transfer for a system in dense media and for an isolated system (i.e., a system in the collision-free condition). Instead of expressing the rate of energy transfer in terms of spectral overlap, the expression of the energy-transfer rate constant is obtained by evaluating a Fourier integral involved in the energy transfer rate constant using the saddle-point method. In this way, the energy-gap dependence, and the effect of temperature and the isotope effect on the energy transfer can be easily studied. The effect of bridge groups connecting between donor and acceptor chromophores on the intramolecular energy transfer is also studied. 相似文献
129.
Factorial design (FD) was applied in order to develop an optimised method for the detection of chemical warfare (CW) agent simulant compounds on Porapak Q. Application of FD allowed study of the adsorption/desorption mechanism of analytes. Di(propylene glycol) monomethyl ether (DPM) and methyl salicylate (MS) were selected for study as both compounds are employed in agent simulation trials but are currently analysed by different methods. An analytical method for simultaneous determination of both compounds was developed using solvent desorption. The optimised method identified non-polar interactions as the primary adsorption/desorption mechanism. Steel tubes were shown to be more suited for sampling of simulants, due to lower variability in recovery compared to glass tubes. Atmospheric detection limits for both simulants were estimated to be 0.2 mg m(-3) allowing the trace analysis of these compounds by gas chromatography with flame ionisation detection (GC-FID). 相似文献
130.
Dinuclear nickel complexes with bidentate N,O ligands: synthesis, structure, and catalytic oligomerization of ethylene 总被引:2,自引:0,他引:2
The new dicationic dinuclear complexes [Ni(micro-Cl)(2)(N,OH)(2)]Cl(2) (11, N,OH = 2-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)-propan-2-ol; 12, N,OH = 2-pyridin-2-yl-propan-2-ol) were prepared in good yields and evaluated as precatalyts in the oligomerization of ethylene, using MAO or AlEtCl(2) as cocatalyst. These paramagnetic complexes were characterized by single-crystal X-ray diffraction in the solid state and in solution with the help of the Evans method, which revealed agreement between the octahedral coordination spheres found in solution and in the solid state. The N donor atoms of each chelating ligand are in mutual cis position, and the OH donors are mutually trans situated. Selectivities for 1-butene within the C(4) fraction of 61% (11) and 58% (12) were observed in the presence of 200 equiv of MAO, but better turnover frequencies (28 300 (11) and 20 400 (12) mol of C(2)H(4)/(mol of Ni.h)) were obtained when 800 equiv of MAO was used. In the presence of 6 equiv of AlEtCl(2), the activities were considerably increased, up to 174 300 (11) and 97 100 (12) mol of C(2)H(4)/(mol of Ni.h), and the selectivity for C(4) olefins was 70% and 64%, respectively. 相似文献