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961.
Feng-yan Wang Zhi-chao Chen Yong-wei Zhang Quan Shuai Bo Jiang Dong-xu Dai Xiu-yan Wang Xue-ming Yang 《化学物理学报(中文版)》2009,(2):191-196
Sliced velocity mapping ion imaging technique was employed to investigate the dynamics of the hydroxyl elimination channel in the photodissociaiton of nitric acid in the ultraviolet region. The OH product was detected by (2+1) resonance enhanced multiphoton ionization via the D^2∑^- electronic state. The total kinetic energy spectra of the OH+NO2 channel from the photolysis of HONO2 show that both :NO2(X2A1) and NO2(A2B2) channels are present, suggesting that both 1^1A″ and 2^1A″ excited electronic states of HONO2 are involved in the excitation. The parallel angular distributions suggest that the dissociation of the nitric acid is a fast process in comparison with the rotational period of the HNO3 molecule. The anisotropy parameter β for the hydroxyl elimination channel is found to be dependent on the OH product rotational state as well as the photolysis energy. 相似文献
962.
Jinghua Yu Bo Li Ping Dai Shenguang Ge 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,74(1):277-281
The interaction between 3-(4′-methylphenyl)-5-(4′-methyl-2′-sulfophenylazo) rhodanine (M4MRASP) and bovine serum albumin (BSA) was studied by using spectrofluorimetry. It was shown in fluorescence spectrums that the quenching mechanism of BSA by M4MRASP was a static quenching. Meanwhile, the binding constant and binding site numbers were calculated. The action distance (r = 8.03 nm) and energy transfer efficiency (E = 0.12) between donor (BSA) and acceptor (M4MRASP) were obtained according to the theory of Förster non-radiation energy transfer. The effect of M4MRASP on the conformation of BSA was further analyzed by using synchronous fluorescence spectrometry. A new model of the interaction between small organic molecule and biomacromolecule was established. The results offered a reference for the studies on the biological effects and action mechanism of small molecule with protein. 相似文献
963.
964.
Jing ZHAO Xiu Wei YANG Yu Xin CUI Xue Hui LIU Shu Yan LIU Hong Ying ZHI Ji Yong CHEN Fa Bing ZHU Yun Li XUE and Dian Bo LIU 《中国化学快报》1999,(4)
TheseedsofAesculuschinensisBge.(Hippocastanaceae)havebeenusedasfolkmedicineforthetreatmentofdistensionandpaininchestandabdomenl.Untilnow,thereisnoreportonitschemicalconstituents.Thispaperdescribesstructureelucidationoftwonewcompounds,escinsIVa3andIVb4onthebasisofspectroscopicmethodsandcomparisonwithescinsla1andfo22.Amongthem,EscinlaIwasstudiedbyX-raydistractionanalysis.Compound3,whitepowder,showediRbandsduetocarboxylanda,p-unsaturatedesterat1740,1713and1640cm-'andstrongabsorptionbandsat34… 相似文献
965.
An efficient, economical and easy method for the synthesis of dimethylaminomethylenediphosphonates using bis(trichloromethyl) carbonate and RCONR1R2 has been developed, which proceeded under relatively mild conditions. 相似文献
966.
A novel organic electron acceptor, N,N′-dipyrimidinyl-3,4,9,10-perylene-tetracarboxylic diimide (DMP), was designed and synthesized. The molecular structure was
characterized by FTIR spectrum and elemental analysis. By cyclic voltammetry measurements, DMP was found to possess a lower
LUMO energy level than N,N′-diphenyl-3,4,9,10-perylene-tetracarboxylic diimide due to the stronger electron-withdrawing pyrimidinyl group than the phenyl
group. Fluorescence quenching is observed in a dual-layer film consisting of a DMP layer and a C60 layer and was attributed to the charge transfer at the interface due to the energy level offset between DMP and C60.
Supported by the National Natural Science Foundation of China (Grant Nos. 50433020, 50520150165 & 50403022) 相似文献
967.
Using a general approach which provides sequential optimality conditions for a general convex optimization problem, we derive necessary and sufficient optimality conditions for composed convex optimization problems. Further, we give sequential characterizations for a subgradient of the precomposition of a K-increasing lower semicontinuous convex function with a K-convex and K-epi-closed (continuous) function, where K is a nonempty convex cone. We prove that several results from the literature dealing with sequential characterizations of subgradients are obtained as particular cases of our results. We also improve the above mentioned statements. 相似文献
968.
L. E. Vorobjev D. A. Firsov V. A. Shalygin V. Yu. Panevin A. N. Sofronov A. Yu. Egorov V. M. Ustinov A. G. Gladyshev O. V. Bondarenko A. V. Andrianov A. O. Zakhar’in D. V. Kozlov 《Bulletin of the Russian Academy of Sciences: Physics》2008,72(2):212-214
Emission of terahertz radiation from strained Be-doped GaAsN layers has been revealed at 4.2 K in postbreakdown electric fields. Heavy and light hole subbands are split in strained layers, and, along with localized acceptor states, resonant states arise. The spectrum of terahertz radiation has been obtained, the current-voltage characteristics of the samples were investigated, and the energy spectra of acceptors were calculated. Peaks in the spontaneous emission spectrum correlate well with the results of the energy spectrum calculations. The transitions between the resonant and localized states of the acceptors make the main contribution to the terahertz radiation intensity. 相似文献
969.
针对不同类别样本数差异和不同误分代价的分类问题,提出了一种基于最小二乘加权支持向量机的分类预测方法。在最小二乘加权支持向量机的基础上,考虑不同类别样本数差异和不同误分代价,提出了新的最小二乘加权支持向量机分类模型,构造了新的最优分类函数。将该模型应用于个人信用预测实验,与已有方法的对比实验结果表明,提出的模型在解决不同类别样本数差异和不同误分代价的个人信用预测问题时,有效地降低了总误分代价,提高了个人信用预测精确度。 相似文献
970.
ZHANG Huan ;TIAN Bo ;ZHANG Hai-Qiang ;GENG Tao ;MENG Xiang-Hua ;LIU Wen-Jun ;CAI Ke-Jie 《理论物理通讯》2008,50(11):1169-1176
For describing various complex nonlinear phenomena in the realistic world, the higher-dimensional nonlinear evolution equations appear more attractive in many fields of physical and engineering sciences. In this paper, by virtue of the Hirota bilinear method and Riemann theta functions, the periodic wave solutions for the (2+1)-dimensional Boussinesq equation and (3+1)-dimensional Kadomtsev Petviashvili (KP) equation are obtained. Furthermore, it is shown that the known soliton solutions for the two equations can be reduced from the periodic wave solutions. 相似文献