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61.
在无溶剂绿色化学条件下,将α-萜品烯-马来酸酐加成物(1)与取代苯(硫)脲发生N-酰化反应,合成了4个N-(1-异丙基-2-羧基-4-甲基二环[2.2.2]-5-辛烯-3-羰基)-N′-芳基(硫)脲化合物(3a~3d),并由IR、UV-Vis、MS、1HNMR、13C NMR和元素分析确认了目标产物的结构。生物活性测试表明,其中3个化合物(3a、3b和3c)具有植物激素作用。 相似文献
62.
二氧化碳多相催化加氢的新进展 总被引:4,自引:0,他引:4
就近年来关于CO2活化、几个重要的CO2多相催化加氢反应及廉价氢的供给的研究进展进行综述。参考文献34篇。 相似文献
63.
S. Jovanović F. De Corte A. Simonits L. Moens P. Vukotić J. Hoste 《Journal of Radioanalytical and Nuclear Chemistry》1987,113(1):177-185
In absolute or comparator standardization methods of (n, ) activation analysis with reactor neutrons, the epithermal neutron flux nonideality, if neglected, max lead to significant errors on the analytical result. The concept of the effective resonance energy
, introduced to correct for this effect, is reviewed. 相似文献
64.
The phase analysis of cryolite (Na3AlF6) and sodium metasilicate (Na2SiO3) was performed by thermal analysis. The eutectic system with a region of two immiscible substances at a concentration of Na2SiO3 between 42.8 and 46.3 mol‐% was identified and the eutectic temperature determined to (886±2) °C. Based on the results of mass‐loss measurements, it was assumed that the introduced Na2SiO3 reacts with Na3AlF6 due to the formation of some nonvolatile stable compounds. The stable reaction products were identified by X‐ray diffraction analysis and IR spectroscopy of the spontaneously cooled samples, which established the formation of NaF and stable amorphous aluminosilicate compounds. 相似文献
65.
Summary Kinetics of dehydration of equilibrium swollen poly(acrylic acid) hydrogel was investigated using methods of non-isothermal
thermal analysis. Methods of Kissinger, Coats-Redfern, Van Krevelen and Horowitz-Metzger were applied for determination the
kinetics parameters: activation energy (E), pre-exponent (lnA) as well as the kinetics model ƒ(69) for the process of hydrogel dehydration under different heating rates. An existence
of good agreement between determined values of kinetic parameters (Eand A), which were obtained applying different methods under the same heating rate. Functional relationship between changes of
kinetic parameters of dehydration and changes of heating rate was established. An existence of compensation effect is accepted
and explanation of compensation effect appearance during the hydrogel dehydration is suggested. 相似文献
66.
67.
68.
蒿甲醚在模拟体内酸碱环境中的代谢动力学研究 总被引:2,自引:0,他引:2
利用高效液相法对蒿甲醚进行了模拟体内酸碱环境的代谢动力学研究 ,测定了蒿甲醚及其代谢产物双氢青蒿素、蒿甲醚呋喃酯的代谢曲线。结果表明 ,蒿甲醚在模拟体内肠道和血液的弱碱性环境条件下半衰期为2 87 2min(计算值 ) ;在模拟体内胃液的酸性环境条件下半衰期为 74 6min ;在两种条件下的主要代谢产物均为双氢青蒿素和蒿甲醚呋喃酯。该方法克服了以往文献所报道方法的一些缺点 ,不仅简化了样品制备方法 ,也提高了检测结果的准确性。 相似文献
69.
Sodium hexafluoromanganate(III) has been synthesized by heating equimolecular quantities of Na2MnF5 and NaF in argon atmosphere. The compound is monoclinic witha=5.56 (1) Å,b=5.84 (1) Å,c=8.10 (2) Å, =90.7 (2) andZ=2. It is a high spin complex with
eff
and the deformation of the octahedra is evident from its IR-spectra. Two enantiotropic transitions (at 562 and 653°C) and the melting point at 800°C have been observed.
8. Mitt.: Mh. Chem.106, 483 (1975). 相似文献
8. Mitt.: Mh. Chem.106, 483 (1975). 相似文献
70.
Solutions of 1-hexanol and 1,2-hexanediol in heptane have been investigated tigated by means of dielectric time domain spectroscopy (TDS). The permittivity spectrum of 1-hexanol in heptane is characterized by a model function containing a sum of three elementary Debye dispersions, while 1,2-hexanediol in heptane is best described by a Cole-Davidson model function. It is shown that dilute solutions of 1-hexanol in heptane have a completely different behavior to that of 1,2-hexanediol. For the diol, the relaxation time levels off at a high value indicating an existence of higher hydrogen bonded complexes. It is possible to quantify the relative amount of monomeric 1-alcohol molecules from the dielectric spectrum. The monomerization rate for 1-hexanol upon dilution with heptane is initially low, but increases rapidly for mole fractions of heptane exceeding 0.4. 相似文献