全文获取类型
收费全文 | 24261篇 |
免费 | 4983篇 |
国内免费 | 6979篇 |
专业分类
化学 | 17661篇 |
晶体学 | 811篇 |
力学 | 1870篇 |
综合类 | 904篇 |
数学 | 3376篇 |
物理学 | 11601篇 |
出版年
2024年 | 60篇 |
2023年 | 302篇 |
2022年 | 813篇 |
2021年 | 830篇 |
2020年 | 902篇 |
2019年 | 890篇 |
2018年 | 843篇 |
2017年 | 1041篇 |
2016年 | 984篇 |
2015年 | 1307篇 |
2014年 | 1490篇 |
2013年 | 1927篇 |
2012年 | 2088篇 |
2011年 | 2236篇 |
2010年 | 2044篇 |
2009年 | 2124篇 |
2008年 | 2200篇 |
2007年 | 1984篇 |
2006年 | 1956篇 |
2005年 | 1794篇 |
2004年 | 1299篇 |
2003年 | 911篇 |
2002年 | 922篇 |
2001年 | 876篇 |
2000年 | 966篇 |
1999年 | 622篇 |
1998年 | 384篇 |
1997年 | 303篇 |
1996年 | 240篇 |
1995年 | 245篇 |
1994年 | 201篇 |
1993年 | 206篇 |
1992年 | 203篇 |
1991年 | 153篇 |
1990年 | 120篇 |
1989年 | 104篇 |
1988年 | 107篇 |
1987年 | 95篇 |
1986年 | 69篇 |
1985年 | 51篇 |
1984年 | 72篇 |
1983年 | 63篇 |
1982年 | 42篇 |
1981年 | 40篇 |
1980年 | 47篇 |
1979年 | 25篇 |
1978年 | 7篇 |
1977年 | 8篇 |
1971年 | 7篇 |
1959年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
31.
羧甲基壳聚糖/聚乙烯醇/甘油环氧树脂蛇笼型复合螯合膜的制备及对金属离子的吸附性能 总被引:4,自引:0,他引:4
以交联甘油环氧树脂交联的聚乙烯醇(PVA)为笼树脂,羧甲基壳聚糖(CCTS)为蛇树脂制备了具有蛇笼结构的复合螯合膜,研究了其对Cu^2 、Ni^2 、Pb^2 、Fe^3 、Zn^2 ,Hg”^2 、Cd^2 等金属离子的吸附性能,研究表明,该树脂对Cu^2 、Ni^2 、Pb^2 有较好的吸附性能,其中PVA是对Cu^2 的吸附的主要贡献者,而CCTS则是在对Ni^2 的吸附中起主要作用。该树脂可以用于含Cu^2 废水的处理。 相似文献
32.
ZHOU Hai-cheng XU Sheng PENG Qing LI Ya-dong 《高等学校化学研究》2006,22(1):11-13
IntroductionNano-sized semiconductors are of great interestdue to their special optical and electronic proper-ties[1,2].As one of the mostimportantⅡ—Ⅵsemicon-ductors,CdS has importantapplications in many fields,such as the solar cell field,non linear o… 相似文献
33.
Bin XIN Dan PU Shao Xiang XIONG* Guang Hui WANG Beijing Mass Spectrometry Center Center for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2003,14(2)
Recently, capillary electrophoresis/electrospray ionization mass spectrometry (CE/ESI- MS) has been rapidly developed as a powerful analytical tool for charged species ranged from small molecules such as carboxylic acids1, phenolic compounds2, metal species3, tetramines4, herbicides5, drugs and drug metabolites6 to peptides and proteins7, 8. The ESI mode has proven to be sensitive, versatile and relatively easy to use in combination with CE. CE confers rapid analysis and efficient separ… 相似文献
34.
A two-tiered organizing scheme with multiple-length scales for construction of dandelion-like hollow CuO microspheres has been elucidated: (1) mesoscale formation of rhombic building units from smaller nanoribbons via oriented aggregation and (2) macroscopic organization of these units into the CuO microspheres. This self-assembly concept may also be applicable to other metal oxides by creating geometric constraints for constructional units. 相似文献
35.
36.
Shu-Liang Zang Qing-Guo Zhang Ming Huang Bin Wang Jia-Zhen Yang 《Fluid Phase Equilibria》2005,230(1-2):192-196
This paper reports that an ionic liquid (IL) has been prepared by directly mixing InCl3 and 1-methyl-3-ethylimidazolium chloride (EMIC) with molar ratio 1/1 under dry argon atmosphere. The densities, and surface tension of the pure IL were determined at temperature range of 293.15 to 343.15 ± 0.1 K. The volumetric properties and the properties of surface for ionic liquid based on group III were discussed by Glasser's theory and Yang's interstice model. 相似文献
37.
The electrochemical carbon dioxide reduction reaction (CO2RR) offers a promising solution to mitigate carbon emission and at the same time generate valuable carbonaceous chemicals/fuels. Single atom catalysts (SACs) are encouraging to catalyze the electrochemical CO2RR due to the tunable electronic structure of the central metal atoms, which can regulate the adsorption energy of reactants and reaction intermediates. Moreover, SACs form a bridge between homogeneous and heterogeneous catalysts, providing an ideal platform to explore the reaction mechanism of electrochemical reactions. In this review, we first discuss the strategies for promoting the CO2RR performance, including suppression of the hydrogen evolution reaction (HER), generation of C1 products and formation of C2+ products. Then, we summarize the recent developments in regulating the structure of SACs toward the CO2RR based on the above aspects. Finally, several issues regarding the development of SACs for the CO2RR are raised and possible solutions are provided.The electrochemical carbon dioxide reduction reaction (CO2RR) offers a promising solution to mitigate carbon emission and at the same time generate valuable carbonaceous chemicals/fuels. 相似文献
38.
Hexanethiolate monolayer-protected gold nanoclusters (MPCs) were used as redox quenchers at the polarizable water/1,2-dichloroethane (DCE) interface. Photocurrent responses originating from the heterogeneous quenching of photoexcited water soluble porphyrin complexes by MPCs dissolved in the DCE phase were observed. As MPCs can function as both electron acceptors and donors, the photocurrent results from the superposition of two simultaneous processes, which correspond to the oxidation and reduction of MPCs. The magnitude of the net photocurrent is essentially determined by the balance of the kinetics of these two processes, which can be controlled by tuning the Galvani potential difference between the two phases. We show that, within the available potential window, the apparent electron-transfer rate constants follow classical Butler-Volmer dependence on the applied potential difference. 相似文献
39.
为了探寻电流脉冲泄流时,设备的接地是否有效可靠,用FDTD法分析了脉冲泄流时均一土壤、分层土壤及局部改善土壤的电导率对冲击接地阻抗(TGR)的影响。结果表明:大地电导率对冲击接地阻抗的影响很大;对均一土壤,TGR随大地电导率的增大而减小,大地电导率越大,TGR对接地体的埋深越不敏感。对分层土壤,接地体要埋在大地电导率大的土壤层中,且不要靠近交界面;局部改善大地导电性能对降低TGR效果明显,TGR对改善区域的体积非常敏感,而当电导率大于一定值时,大地电导率的再增加,对TGR的影响不明显。 相似文献
40.