全文获取类型
收费全文 | 18954篇 |
免费 | 3541篇 |
国内免费 | 2823篇 |
专业分类
化学 | 14144篇 |
晶体学 | 303篇 |
力学 | 1163篇 |
综合类 | 193篇 |
数学 | 2130篇 |
物理学 | 7385篇 |
出版年
2024年 | 32篇 |
2023年 | 375篇 |
2022年 | 631篇 |
2021年 | 687篇 |
2020年 | 884篇 |
2019年 | 805篇 |
2018年 | 722篇 |
2017年 | 672篇 |
2016年 | 935篇 |
2015年 | 979篇 |
2014年 | 1186篇 |
2013年 | 1478篇 |
2012年 | 1850篇 |
2011年 | 1962篇 |
2010年 | 1355篇 |
2009年 | 1317篇 |
2008年 | 1290篇 |
2007年 | 1191篇 |
2006年 | 1185篇 |
2005年 | 960篇 |
2004年 | 716篇 |
2003年 | 532篇 |
2002年 | 604篇 |
2001年 | 434篇 |
2000年 | 391篇 |
1999年 | 359篇 |
1998年 | 287篇 |
1997年 | 245篇 |
1996年 | 224篇 |
1995年 | 186篇 |
1994年 | 160篇 |
1993年 | 122篇 |
1992年 | 120篇 |
1991年 | 101篇 |
1990年 | 78篇 |
1989年 | 55篇 |
1988年 | 50篇 |
1987年 | 24篇 |
1986年 | 32篇 |
1985年 | 33篇 |
1984年 | 23篇 |
1983年 | 7篇 |
1982年 | 5篇 |
1981年 | 10篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1971年 | 2篇 |
1959年 | 2篇 |
1957年 | 5篇 |
1930年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 187 毫秒
81.
Tian Le LIN Bao Zhen YAN Gao Fei HU Mei WANG 《中国化学快报》2006,17(7):937-940
Complex formation between aluminium and quercetin(Q) in methanol was investigated by means of 27^Al solid-state, 13^C and 1^H NMR and MS(ESI), UV and IR spectra. Formation of the 1:2 complex was favored in methanol relative to all other solvent and the predominant species observed of Al(Ⅲ) has a 1:2 stoichiometry. The fine structure of 1:2 aluminum complex of quercetin was that the aluminum central atom chelated with two quereetin molecules and two methoxyl groups between two five membered rings, its coordination is six, the chelated site was 3-hydroxy-4-carbonyl. 相似文献
82.
Acoustic vector sensor signal processing 总被引:2,自引:0,他引:2
SUN Guiqing LI Qihu ZHANG Bin 《声学学报:英文版》2006,25(1):1-15
Acoustic vector sensor simultaneously, colocately and directly measures orthogonal components of particle velocity as well as pressure at single point in acoustic field so that is possible to improve performance of traditional underwater acoustic measurement devices or detection systems and extends new ideas for solving practical underwater acoustic engineering problems. Although acoustic vector sensor history of appearing in underwater acoustic area is no long, but with huge and potential military demands, acoustic vector sensor has strong development trend in last decade, it is evolving into a one of important underwater acoustic technology. Under this background, we try to review recent progress in study on acoustic vector sensor signal processing, such as signal detection, DOA estimation, beamforming, and so on. 相似文献
83.
The ab initio calculations were performed at the RHF/4-31G level with the reaction pathways of the iso-merization and dehydrogenation of methylnitrene by the intrinsic reaction coordinate method. The results show that the transformation from methylnitrene to methylenimine would be very easy. This accountes for the experimental fact that one couldn' t find the methylnitrene, but only obtained the methylenimine in the pyrolysis of methyl azide. The mode-selective study reveals the reaction coordinates (IRC) of isomerization and dehydrogenation of methylnitrene are associated with the molecular deformation mode of 1191 cm-1 and the methyl group unsymmetrical stretch mode, respectively. The coupling between normal coordinates is favourable to select the reaction channel of isomerization. 相似文献
84.
采用5d-4f跃迁的稀土Ce3+-冠醚配合物(Ce-二环己基并-18-冠-6,Ce-DC18C6)作为发光掺杂剂,4,4'-二(9-咔唑基)联苯(CBP)为基质,设计制备了紫外发光器件:ITO/CuPc/Ce-DC18C6:CBP/Bu-PBD/LiF/Al,首次观测到峰位于376nm的Ce3+离子的紫外电致发光。通过对比器件的EL谱与Ce3+-冠醚配合物薄膜的PL谱发现,EL光谱中有部分来自Ce3+配合物中的Ce3+离子的。这种5d-4f电子跃迁的掺杂质量分数为3%时,该UV-发光器件的最大辐射功率为13μW/cm2。 相似文献
85.
部分相干光束通过硬边光阑的推广光束传输M2因子 总被引:2,自引:2,他引:0
给出部分相干光通过硬边光阑后的强度二阶矩的计算公式,由此可得到部分相干光通过硬边光阑后的推广光束传输M^2因子。以部分相干高斯-谢尔模型光束为例,推导出相应的M^2因子,并作了数值计算和分析讨论。 相似文献
86.
Differential algebraic equations with after-effect 总被引:4,自引:0,他引:4
C. T. H. Baker C. A. H. Paul H. Tian 《Journal of Computational and Applied Mathematics》2002,140(1-2):63-80
In this paper, we are concerned with the solution of delay differential algebraic equations. These are differential algebraic equations with after-effect, or constrained delay differential equations. The general semi-explicit form of the problem consists of a set of delay differential equations combined with a set of constraints that may involve retarded arguments. Even simply stated problems of this type can give rise to difficult analytical and numerical problems. The more tractable examples can be shown to be equivalent to systems of delay or neutral delay differential equations. Our purpose is to highlight some of the complexities and obstacles that can arise when solving these problems, and to indicate problems that require further research. 相似文献
87.
对用索氏提取法和乙醇浸取法提取红景天红色素进行了比较,并探讨浸取的浓度,浸取温度等因素,指出了最佳生产工艺条件,从红景天中提取的天红色素是一种安全无毒的食用色素,本文还研究了几种食品添加剂对红景天红色素稳定性的影响,并对色素的耐氧化性进行了探讨,旨在为红景天红色素的开发利用提供有实用价值的信息。 相似文献
88.
利用气体放电双探针法研究了等离子体的I-V曲线中的电流I相对于电压V轴交点的不对称性,并提出2种可能的解释:一认为是由于两探针表面积不同引起的;二认为是由于探针所在处等离子体电位不等引起的.本文利用仪器的工艺误差和调换放电管电压的方法,对提出的2种可能原因分别进行验证,并指出第二种解释的合理性,并对其进行了理论分析. 相似文献
89.
Bin Han 《Advances in Computational Mathematics》2006,24(1-4):375-403
In this paper, we present a necessary and sufficient condition for the existence of solutions in a Sobolev space Wpk(ℝs) (1≤p≤∞) to a vector refinement equation with a general dilation matrix. The criterion is constructive and can be implemented.
Rate of convergence of vector cascade algorithms in a Sobolev space Wpk(ℝs) will be investigated. When the dilation matrix is isotropic, a characterization will be given for the Lp (1≤p≤∞) critical smoothness exponent of a refinable function vector without the assumption of stability on the refinable function
vector. As a consequence, we show that if a compactly supported function vector φ∈Lp(ℝs) (φ∈C(ℝs) when p=∞) satisfies a refinement equation with a finitely supported matrix mask, then all the components of φ must belong to a Lipschitz
space Lip(ν,Lp(ℝs)) for some ν>0. This paper generalizes the results in R.Q. Jia, K.S. Lau and D.X. Zhou (J. Fourier Anal. Appl. 7 (2001) 143–167)
in the univariate setting to the multivariate setting.
Dedicated to Professor Charles A. Micchelli on the occasion of his 60th birthday
Mathematics subject classifications (2000) 42C20, 41A25, 39B12.
Research was supported in part by the Natural Sciences and Engineering Research Council of Canada (NSERC Canada) under Grant
G121210654. 相似文献
90.
Yongge Tian 《Journal of Mathematical Analysis and Applications》2002,266(2):333-341
We present an alternative expression for the parallel sum of k Hermitian nonnegative definite matrices by using the Moore-Penrose inverse of a block matrix. 相似文献