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991.
Elçin Yusufoğlu Cevad Selam 《Numerical Methods for Partial Differential Equations》2010,26(6):1434-1442
In this article, to solve the modified equal width wave (MEW) equation, the homotopy analysis method (HAM) is proposed. The initial approximation can be freely chosen with possible unknown constant, which can be determined by using the boundary and initial conditions. The HAM contains the auxiliary parameter ?, which provides us to adjust and control the convergence region of solution series with a simple way. Three conservative quantities are reported. Numerical results show that this method is a promising and powerful tool to solve the MEW equation. © 2009 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 2010 相似文献
992.
Chizallet C Costentin G Che M Delbecq F Sautet P 《The journal of physical chemistry. B》2006,110(32):15878-15886
Low-coordinated (LC) ions at the MgO surface (noted Mg2+LC and O2-LC with L = 1-5), located on monatomic and diatomic steps, corners, step divacancies, and kinks, have been modeled thanks to periodic density functional theory (DFT) calculations (VASP). Ions of lowest coordination induce the strongest surface geometry relaxation and the highest surface energies. The hydration energies of these sites and thermodynamic stabilities of the resulting surfaces were studied. The factors controlling the interaction strength between water and the surface are the possibility for the hydroxyl group to adopt a bridging geometry between two Mg2+ cations in concave areas of the surface, such as the bottom of the monatomic step, and at second order the surface atomic coordination, and especially the presence of three-coordinated ions. The Lewis basicity and acidity of O2-LC and Mg2+LC, respectively, increase as their coordination number decreases, which implies the same trend for the Br?nsted basicity of the Mg2+-O2- pair toward water. However, this trend can be changed if pairs leading to the formation of bridging OH groups are involved, typically on monatomic steps or in step divacancies where O2C-H and O3C-H are obtained, respectively, instead of the expected O1C-H. Thanks to thermodynamic calculations, the state of the surface as a function of temperature can be determined at a given pressure, unraveling the roles of surface topology and ions coordination. 相似文献
993.
[reaction: see text] To verify if hydrogen-bond donor groups can assist fluoride binding at the boron center of triaryl boranes, o-(dimesitylboryl)trifluoroacetanilide has been synthesized. Reaction of this new borane with [n-Bu(4)N][F] in acetone affords the corresponding fluoroborate complex whose stability constant exceeds that of [Mes(3)BF](-) by at least 2 orders of magnitude. Presumably, the higher fluoride affinity of o-(dimesitylboryl)trifluoroacetanilide results from the cooperativity of the Lewis acidic boron center and the hydrogen-bond donor trifluoroacetamide group. 相似文献
994.
A magnetic tweezers setup is used to control both the stretching force and the relative linking number DeltaLk of a palindromic DNA molecule. We show here, in absence of divalent ions, that twisting negatively the molecule while stretching it at approximately 1 pN induces the formation of a cruciform DNA structure. Furthermore, once the cruciform DNA structure is formed, the extrusion of several kilo-base pairs of palindromic DNA sequence is directly and reversibly controlled by varying DeltaLk. Indeed the branch point behaves as a nanomechanical gear that links rotation with translation, a feature related to the helicity of DNA. We obtain experimentally a very good linear relationship between the extension of the molecule and DeltaLk. We use then this experiment to obtain a precise measurement of the pitch of B-DNA in solution: 3.61 +/- 0.03 nm/turn. 相似文献
995.
We propose a new way to generate an observable geometric phase by means of a completely incoherent phenomenon. We show how to imprint a geometric phase to a system by adiabatically manipulating the environment with which it interacts. As a specific scheme, we analyze a multilevel atom interacting with a broadband squeezed vacuum bosonic bath. As the squeezing parameters are smoothly changed in time along a closed loop, the ground state of the system acquires a geometric phase. We also propose a scheme to measure such a geometric phase by means of a suitable polarization detection. 相似文献
996.
997.
Jorge San Martín Jean-François Scheid Loredana Smaranda 《Comptes Rendus Mathematique》2010,348(15-16):935-939
We propose a new characteristics method for the time discretization of a fluid–rigid system in the case when the densities of the fluid and the solid are different. This method is based on a global weak formulation involving only terms defined on the whole fluid–rigid domain. The main idea is to construct a characteristic function which preserves the rigidity of the solid at the discrete time levels. A convergence result for this semi-discrete scheme is then given. 相似文献
998.
Suzana Mendes-Gonçalves Robert P. Sullivan 《Central European Journal of Mathematics》2010,8(6):1120-1131
Suppose σ is an equivalence on a set X and let E(X, σ) denote the semigroup (under composition) of all α: X → X such that σ ⊆ α ∘ α
−1. Here we characterise Green’s relations and ideals in E(X, σ). This is analogous to recent work by Sullivan on K(V, W), the semigroup (under composition) of all linear transformations β of a vector space V such that W ⊆ ker β, where W is a fixed subspace of V. 相似文献
999.
In a M/M/N+M queue, when there are many customers waiting, it may be preferable to reject a new arrival rather than risk that arrival
later abandoning without receiving service. On the other hand, rejecting new arrivals increases the percentage of time servers
are idle, which also may not be desirable. We address these trade-offs by considering an admission control problem for a M/M/N+M queue when there are costs associated with customer abandonment, server idleness, and turning away customers. First, we formulate
the relevant Markov decision process (MDP), show that the optimal policy is of threshold form, and provide a simple and efficient
iterative algorithm that does not presuppose a bounded state space to compute the minimum infinite horizon expected average
cost and associated threshold level. Under certain conditions we can guarantee that the algorithm provides an exact optimal
solution when it stops; otherwise, the algorithm stops when a provided bound on the optimality gap is reached. Next, we solve
the approximating diffusion control problem (DCP) that arises in the Halfin–Whitt many-server limit regime. This allows us
to establish that the parameter space has a sharp division. Specifically, there is an optimal solution with a finite threshold
level when the cost of an abandonment exceeds the cost of rejecting a customer; otherwise, there is an optimal solution that
exercises no control. This analysis also yields a convenient analytic expression for the infinite horizon expected average
cost as a function of the threshold level. Finally, we propose a policy for the original system that is based on the DCP solution,
and show that this policy is asymptotically optimal. Our extensive numerical study shows that the control that arises from
solving the DCP achieves a very similar cost to the control that arises from solving the MDP, even when the number of servers
is small. 相似文献
1000.
Kotzig asked in 1979 what are necessary and sufficient conditions for a d‐regular simple graph to admit a decomposition into paths of length d for odd d>3. For cubic graphs, the existence of a 1‐factor is both necessary and sufficient. Even more, each 1‐factor is extendable to a decomposition of the graph into paths of length 3 where the middle edges of the paths coincide with the 1‐factor. We conjecture that existence of a 1‐factor is indeed a sufficient condition for Kotzig's problem. For general odd regular graphs, most 1‐factors appear to be extendable and we show that for the family of simple 5‐regular graphs with no cycles of length 4, all 1‐factors are extendable. However, for d>3 we found infinite families of d‐regular simple graphs with non‐extendable 1‐factors. Few authors have studied the decompositions of general regular graphs. We present examples and open problems; in particular, we conjecture that in planar 5‐regular graphs all 1‐factors are extendable. © 2009 Wiley Periodicals, Inc. J Graph Theory 63: 114–128, 2010 相似文献