Electromagnetic waves near perfect conductors. I. Multiple scattering expansions. Distribution of modes

An expansion is established for the Green functions describing electromagnetic waves in the presence of a perfectly conducting boundary. Each term represents a process for which the wave scatters several times on the boundary and propagates freely in between. This multiple scattering expansion reduces to ray optics in the high frequency limit, and thus provides a general framework to study diffraction corrections. It also allows one to evaluate quantities averaged over the spectrum. Some symmetry properties of the expansion are exhibited, in particular, the replacement of magnetic fields by electric fields results in a change of sign at each scattering. Convergence is proven for any smooth boundary in the domain Im k ? | Re k | of complex wavenumbers k. The continuation of the convergence domain around k = 0 is shown to depend upon the topology of the boundary. The multiple scattering expansion method is applied to determine the distribution of electromagnetic eigenmodes in a conducting cavity. The density of modes ?(k) is analyzed in terms of closed classical rays, bouncing off the walls with mirror reflections. Paths of zero length yield the smooth part of ?, expanded as $\text{π}{}^{\mathrm{?2}}\text{[Vk}{}^2\text{-}\text{2}\text{3}\text{∫ dα / R}$ + $\text{O}$(k^?2)] where V is the volume of the cavity, and ∫ dα/R is the integral over the boundary of the mean curvature. Paths of finite length L yield contributions to the density ?(k), of the form Im(a exp ikL) appearing as regular oscillations in the bunching of eigenmodes. For an analytic boundary, inclusion of complex classical rays renders exact the analysis of the eigenmodes in terms of closed paths. As a consequence, the high temperature expansion for the energy of a small blackbody is obtained.     

Superconducting quark matter

In asymptotically dense quark matter, colored glue forces cause an unusual variant of superconductivity. Instead of pairing, the quarks clump in groups of six. We investigate the gap equation in the weak coupling limit, and find the leading behavior of the energy gap and the critical temperature as functions of the renormalized coupling constant.     

Viscosity,refractive index,and surface tension of multicomponent systems: Mathematical representation and estimation from data for binary systems

An equation previously developed for estimation of the excess thermodynamic properties of multicomponent systems from binary mixing data has been applied to other physical properties through extrathermodynamic properties such as the excess Gibbs free energy of activation for viscous flow, molar refractivity, and exess surface free energy. This equation provides reasonably accurate predictions for viscosity, refractive index and surface tension of ternary and quaternary systems, given the properties of the various binary combinations of the components. The equation also serves quite well as a point-of-departure for mathematical representation of experimental data, in that all of the data considered could be represented within experimental uncertainty with the aid of no more than one adjustable parameter for each multicomponent system.     

Photolytic rearrangement of germanium azides. Evidence for transient germa-imines

Photolysis of germanium azides gives rise to transient germa-imines which have been quantitatively trapped by pinacol. Evidence for the formation of diphenylgermylene in the photolysis of hexaphenylcyclodigermazane is also reported.