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621.
622.
623.
M. Benoit S. Ispas P. Jund R. Jullien 《The European Physical Journal B - Condensed Matter and Complex Systems》2000,13(4):631-636
A Car-Parrinello (CP) molecular dynamics simulation of vitreous silica, combined with classical molecular dynamics, is presented.
The equilibration of the liquid, quench and relaxation of the glass are performed classically using the van Beest, Kramer
and van Santen (BKS) potential [12] and the resulting configuration (coordinates and velocities) is used as input for the
CP simulation. A remarkable stability of the CP dynamics is observed justifying this procedure and validating the BKS potential.
Several structural and electronic properties are calculated and compared with experiments.
Received 23 March 1999 and Received in final form 15 July 1999 相似文献
624.
Guillaume Altmeyer Benoit Panicaud Emmanuelle Rouhaud Mingchuan Wang Arjen Roos Richard Kerner 《Continuum Mechanics and Thermodynamics》2016,28(6):1741-1758
When constructing viscoelastic models, rate-form relations appear naturally to relate strain and stress tensors. One has to ensure that these tensors and their rates are indifferent with respect to the change of observers and to the superposition with rigid body motions. Objective transports are commonly accepted to ensure this invariance. However, the large number of transport operators developed makes the choice often difficult for the user and may lead to physically inconsistent formulation of hypoelasticity. In this paper, a methodology based on the use of the Lie derivative is proposed to model consistent hypoelasticity as an equivalent incremental formulation of hyperelasticity. Both models are shown to be reversible and completely equivalent. Extension to viscoelasticity is then proposed from this consistent model by associating consistent hypoelastic models with viscous behavior. As an illustration, Mooney–Rivlin nonlinear elasticity is coupled with Newton viscosity and a Maxwell-like material is investigated. Numerical solutions are then presented to illustrate a viscoelastic material subjected to finite deformations for a large range of strain rates. 相似文献
625.
Geometric distortion correction for echo planar images using nonrigid registration with spatially varying scale 总被引:1,自引:0,他引:1
One method used to correct geometric and intensity distortions in echo planar images is to register them to undistorted images via nonrigid deformations. However, some areas in the echo planar images are more distorted than others, thus suggesting the use of deformations whose characteristics are adapted spatially. In this article, we incorporate into our previously developed registration algorithm a spatially varying scale mechanism, which adapts the local scale properties of the transformation by means of a scale map. To compute the scale map, a technique is proposed that relies on an estimate of the expected deformation field. This estimate is generated using knowledge of the physical processes that induce distortions in echo planar images. We evaluate the method of spatially varying scale on both simulated and real data. We find that, in comparison with our earlier method using fixed scale, our new method finds deformation fields that are smoother and finds them faster without sacrificing accuracy. 相似文献
626.
We report a simple optical setup to produce both axial and lateral structured illumination through a single objective lens. With a minimum of six full-field images obtained without moving either the sample or the microscope objective, 100 nm diameter fluorescent beads can be localized axially with an accuracy of 50 nm in a 1.76-microm-thick layer. We show that this axial localization improvement can easily be combined with classical lateral structured illumination, so that lateral resolution enhancement by a factor of 2 is maintained. 相似文献
627.
Gloaguen E Mestdagh JM Poisson L Lepetit F Visticot JP Soep B Coroiu M Eppink AT Parker DH 《Journal of the American Chemical Society》2005,127(47):16529-16534
The existence of a mediating state for the ultrafast electronic relaxation in ethylenic-like molecules has been shown by femtosecond electron imaging techniques. This state is of Rydberg character, and its high efficiency is due to its ability to link the electron distributions of the initial and final electronic states. 相似文献
628.
Gauvreau B Bérengier M Blanc-Benon P Depollier C 《The Journal of the Acoustical Society of America》2002,112(6):2680-2687
This study deals with sound propagation in typical traffic noise conditions. The numerical results are obtained through the split-step Padé method and the discrete random Fourier modes technique. These are first evaluated qualitatively, by color contour maps showing noise propagation, diffraction by an impedance discontinuity or a screen edge, and scattering by atmospheric turbulence. Next, our numerical results are quantitatively validated by comparison with analytical models and other parabolic equation models. For all the atmospheric conditions and geometrical configurations available in literature, the agreement between the different methods is very good, except for some cases involving the atmospheric turbulence. However, in those particular cases, the split-step Padé results are shown to be more consistent with physical theory. Finally, our method seems to be very powerful and reliable for traffic noise prediction. 相似文献
629.
Benoit Coasne KeithE. Gubbins RolandJ.‐M. Pellenq 《Particle & Particle Systems Characterization》2004,21(2):149-160
We report a Grand Canonical Monte Carlo simulation study of Ar adsorption at 77 K in silica nanopores having various morphologies/topologies. Both the morphological and topological disorders are shown to significantly affect the capillary condensation phenomenon. In the case of an ellipsoidal pore, we observe that the filling mechanism is similar to that of a cylindrical pore having the same section area but with a lower condensation pressure. We show that the adsorption/desorption hysteresis loop is asymmetrical for the pore with constrictions while it is symmetrical for the regular cylindrical pore. Moreover, the Ar adsorption isotherm for the constricted pore reproduces the main features of that for the fully disordered Vycor‐like porous matrix. The results for the different pore geometries (having no direct interface with the gas reservoir) indicate that the desorption occurs through cavitation at a pressure driven by the smallest void size. We also consider the validity of the BET and BJH methods for the different porous matrices. Except for the Vycor‐like matrix, the BET surface assessed from Ar adsorption isotherm at 77 K always significantly overestimates the intrinsic surface of the pore (even for a planar surface). The disagreement between the BET surface and the geometrical surface is found to increase as the confinement increases (cylindrical pore) and/or the shape of the pore becomes asymmetrical (ellipsoidal pore). Interestingly, the best agreement between the BET and the geometrical surface is found in the case of the pore with a constriction, i.e. a system that exhibits a surface with both negative and positive curvature regions. This idea is supported by the results for the Vycor‐like matrix, which has a distorted surface (many negative curvature regions combined with positive curvature regions): for this disordered porous matrix, the BET surface is found to underestimate the intrinsic surface. Finally, we show that the pore size determined using the BJH method always underestimates the pore size, in agreement with previous experimental and simulation studies. 相似文献
630.
M. Benmouna Z. Benmansour E. W. Fischer H. Benoit T. A. Vilgis 《Journal of Polymer Science.Polymer Physics》1992,30(7):733-745
Dynamical relaxation properties of nonsymmetrical mixtures of homopolymers and of copolymers in solution are examined. In particular, examples of bimodal mixtures in solution, ternary mixtures of two different homopolymers and a solvent, and nonsymmetrical diblock copolymers in solution are examined. The frequencies of the eigenmodes Γ and Γ′, those of the cooperative mode ΓT and the interdiffuse mode ΓI are calculated for these systems. It is found that the variations of TT and TI, with the scattering wave number q are practically identical to those of ΓT and ΓI, respectively. This identity is rigorous only for mixtures or copolymers where the two polymer components are identical except for their contrast factors (i.e., indices of refraction or scattering lengths). Here, it is argued that the identification of the eigenmodes with the cooperative and interdiffuse modes can be extended qualitatively to mixtures of different polymers and to nonsymmetrical copolymers in solution. 相似文献