全文获取类型
收费全文 | 666篇 |
免费 | 35篇 |
专业分类
化学 | 454篇 |
晶体学 | 4篇 |
力学 | 40篇 |
数学 | 130篇 |
物理学 | 73篇 |
出版年
2024年 | 2篇 |
2023年 | 8篇 |
2022年 | 3篇 |
2021年 | 14篇 |
2020年 | 16篇 |
2019年 | 8篇 |
2018年 | 15篇 |
2017年 | 9篇 |
2016年 | 22篇 |
2015年 | 25篇 |
2014年 | 28篇 |
2013年 | 50篇 |
2012年 | 56篇 |
2011年 | 64篇 |
2010年 | 29篇 |
2009年 | 23篇 |
2008年 | 62篇 |
2007年 | 44篇 |
2006年 | 51篇 |
2005年 | 39篇 |
2004年 | 35篇 |
2003年 | 16篇 |
2002年 | 18篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1945年 | 1篇 |
1944年 | 1篇 |
1943年 | 1篇 |
1942年 | 3篇 |
1941年 | 2篇 |
排序方式: 共有701条查询结果,搜索用时 265 毫秒
91.
Jack M. Williams M. A. Beno E. H. Appelman J. M. Capriotti F. Wudl E. Aharon-Shalom 《Molecular Crystals and Liquid Crystals》2013,570(1):675-682
Abstract We report the first crystallographic analysis, as a function of temperature, of a TMTSF derivative. Both (TMTSF)2(FSO3) and (TMTSF)2(BrO4) are isostructural (triclinic, with space group PI) with superconducting (TMTSF)2(ClO4). (TMTSF)2(FSO3) undergoes a metal-to-insulator transition at 86-90K as observed by microwave conductivity, D.C. conductivity, and magnetic susceptibility. The crystal structure contains 2-dimensional sheets of short Se-Se contacts in the molecular stacking direction and perpendicular to the stacking direction. The temperature dependent variations in these contact distances appear to be of special importance in determining the conduction properties of these materials, and are observed to change in a surprising manner when (TMTSF)2(FSO3) is cooled (298 → 123K). The homoatomic Se separations within each TMTSF molecule appear to increase slightly, but not significantly. At the same time the entire 2-dimensional sheet of intermolecular (intra- and interstack) Se-Se contacts between TMTSF molecules contract quite anisotropically, which results in an increase in “dimensionality” of the Se-Se network. Hence, an increase in electrical conduction, in the absence of insulating phenomena, over the temperature range 298 → 123K is not surprising. The intermolecular Se-Se contact distances in (TMTSF)2(BrO4) are significantly longer than in (TMTSF)2(FSO3) which suggests that the room temperature electrical conductivity of the (BrO4)? salt may be diminished compared to the (FSO3)? analogue. 相似文献
92.
93.
Denis Veynante Benoît Fiorina Pascale Domingo Luc Vervisch 《Combustion Theory and Modelling》2013,17(6):1055-1088
Detailed chemical mechanisms have to be incorporated in turbulent combustion modelling to predict flame propagation, ignition, extinction or pollutant formation. Unfortunately, hundreds of species and thousands of elementary reactions are involved in hydrocarbon chemical schemes and cannot be handled in practical simulations, because of the related computational costs and the need to model the complexity of their interaction with turbulent motions. Detailed chemistry may be handled using look-up tables, where chemical parameters such as reaction rates and/or species mass fractions are determined from a reduced set of coordinates, progress variables or mixture fractions, as proposed in ILDM, FPI or FGM methods. Nevertheless, these tables may require large computer memory spaces and non-negligible access times. This issue becomes of crucial importance when running on massively parallel computers: to implement these databases in shared memories would induce a large number of data exchanges, reducing the overall code performance; on the other hand duplicating databases in every local processor memory may become impossible either for large databases or small local memories. This work proposes to take advantage of the self-similar behaviour of turbulent premixed flames to reduce the size of these chemical databases, specifically when running on massively parallel machines, under the FPI (Flame Prolongation of ILDM) framework. Several approaches to reduce the database are investigated and discussed both in terms of memory requirements and access times. A very good compromise is obtained for methane–air turbulent premixed flames, where the size of the database is decreased by a factor of 1000, while the access time is reduced by about 60%. 相似文献
94.
Nonlocal Lotka–Volterra models have the property that solutions concentrate as Dirac masses in the limit of small diffusion. Is it possible to describe the dynamics of the limiting concentration points and of the weights of the Dirac masses? What is the long time asymptotics of these Dirac masses? Can several Dirac masses co-exist? We will explain how these questions relate to the so-called “constrained Hamilton–Jacobi equation” and how a form of canonical equation can be established. This equation has been established assuming smoothness. Here we build a framework where smooth solutions exist and thus the full theory can be developed rigorously. We also show that our form of canonical equation comes with a kind of Lyapunov functional. Numerical simulations show that the trajectories can exhibit unexpected dynamics well explained by this equation. Our motivation comes from population adaptive evolution a branch of mathematical ecology which models Darwinian evolution. 相似文献
95.
Jean Quertinmont Prof. Dr. Tom Leyssens Prof. Dr. Johan Wouters Prof. Dr. Benoît Champagne 《Chemphyschem》2019,20(19):2434-2442
This work aims at better understanding the complex effects of co-crystallization on a single salicylideneaniline molecular switch, (E)-2-methoxy-6-(pyridine-3-yliminomethyl)phenol (PYV3), which can tautomerize between an enol and a keto form. A combination of periodic boundary conditions DFT and molecular wavefunction calculations has been adopted for examining a selection of PYV3 co-crystals, presenting hydrogen bonds (H-bonds) or halogen bonds (X-bonds), for which X-ray diffraction data are available. Three aspects are targeted: i) the energy (H-bond strength, enol to keto relative energy, and geometry relaxation energies), ii) the geometrical structure (PYV3 to co-crystal and enol to keto geometrical variations), and iii) the electron distribution (PYV3 to co-crystal and enol to keto Mulliken charge variations). These allow i) explaining the preference for forming H-bonds with the nitrogen of the pyridine of PYV3 with respect to the oxygens and the importance of the crystal field, ii) distinguishing the peculiar behavior of the SulfonylDiPhenol (SDP) coformer, which stabilizes the keto form of PYV3, iii) describing the relative stabilization of the enol form upon co-crystallization (with the exception of SDP) and therefore iv) substantiating the co-crystallization-induced reduction of thermochromism observed for several PYV3 co-crystals. 相似文献
96.
We present a diagrammatic theory for coherent backscattering from disordered dilute media in the nonlinear regime. We show that the coherent backscattering enhancement factor is strongly affected by the nonlinearity, and we corroborate these results by numerical simulations. Our theory can be applied to several physical scenarios such as scattering of light in a nonlinear Kerr medium or propagation of matter waves in disordered potentials. 相似文献
97.
Synthesis of polyphosphodiesters by ring‐opening polymerization of cyclic phosphates bearing allyl phosphoester protecting groups
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Benoït Clément Daniel G. Molin Christine Jérôme Philippe Lecomte 《Journal of polymer science. Part A, Polymer chemistry》2015,53(22):2642-2648
The allyl phosphoester group is shown to be a protecting group for the synthesis of anionic polyphosphodiesters. Our strategy relies on the synthesis of a cyclic phosphate monomer bearing a pendant allyl phosphoester group, its easy purification by fractional distillation, its organocatalyzed ring‐opening polymerization by 1,8‐diazobicyclo[5.4.0]undec‐7‐ene (DBU) and 1‐[3,5‐bis(trifluoromethyl)phenyl]‐3‐cyclohexyl‐thiourea (TU). Finally, the deprotection of the allyl phosphoester group is carried out by reaction with sodium benzenethiolate in the absence of any detectable degradation. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2642–2648 相似文献
98.
99.
100.
Michele Vascellari Danny Messig Arne Scholtissek Christian Hasse Meng Xia Benoît Fiorina Nasser Darabiha 《Proceedings of the Combustion Institute》2019,37(3):2857-2866
A multi-stream Flamelet Progress Variable (FPV) model, specifically developed for coal combustion, is proposed. The model accounts for the different fuel streams associated with the volatile and char burnout products. The applicability of the new FPV model is investigated in a laminar stagnation pulverized coal flame. The flame considered is a premixed mixture of CH4, O2 and N2, carrying pulverized coal particles, stabilized in an impinging wall. Spontaneous emissions of OH*, CH* and C are measured to identify the flame. The 1D numerical simulations of the experimental conditions are able to reproduce the main features of the flame. The applicability of the multi-stream FPV model to coal combustion is further evaluated with the a posteriori analysis of the FPV results, comparing the results with a reference model, where the species are fully transported and the chemistry directly evaluated. Then, with the budget analysis, the influence of the control variables used to build the look-up table is assessed by examining the conditional contributions to the overall transport terms of scalar quantities (e.g. species, temperature). The results of both analyses show that the proposed multi-stream FPV model can accurately predict the main features of coal combustion, with only minor issues related to the manifold used to build the look-up table. 相似文献